Synthesis of a new-type carbonific and its application in intumescent flame-retardant (IFR)/polyurethane coatings

Journal of Fire Sciences

Volumn 21, Issue 4, 2003, Pages 245-266

  Jincheng, Wang ^a   Shenglin, Yang ^a   Guang, Li ^a   Jianming, Jlang ^a  

^a DONGHUA UNIVERSITY   (China)

Author keywords

Carbonific; Characteristic performances; Intumescent flame retardant; Polyurethane coatings; Synthesis

Indexed keywords

CARBONIZATION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROTECTIVE COATINGS; SYNTHESIS (CHEMICAL); THERMODYNAMIC STABILITY;

DRY COATINGS;

POLYURETHANES;

EID: 0038051069     PISSN: 07349041     EISSN: None     Source Type: Journal    
DOI: 10.1177/0734904103021004001     Document Type: Article

References (29)

1. Kuryla, W.C. and Papa, A.J. (1975). Flame Retardancy of Polymeric Materials, Vol. 3, Chapter 1, Marcel Dekker, New York.
2. Duquesne, S., Le Bras, M. and Bourbigot, S. (2001). Mechanism of Fire Retardancy of Polyurethanes Using Ammonium Polyphosphate, Journal of Applied Polymer Science, 82: 3262-3274.
3. Woods, G. (1990). The ICI Polyurethane Book, ICI Polyurethanes and Wiley, Chichester.
4. Hatat, D. (1995). In Techniques de I'ingenieur, Les Techniques de I'ingrnieur, Paris.
5. Kirk, R.E. and Othman, D.F. (1997). Encylopedia of Chemical Technology, Wiley-Interscience, New York.
6. Melchiors, M., Sonntag, M. and Kobusch, C. (2000). Recent Developments in Aqueous Two-component Polyurethane (2K-PUR) Coatings, Progress in Organic Coatings, 40: 99-109.
7. Le Bras, M., Bugajny, M. and Lefebvre, J. (2000). Use of Polyurethanes as Char-forming Agents in Polypropylene Intumescent Formulations, Polymer International, 49: 1115-1124.
8. Bourbigot, S., Le Bras, M. and Bugajny, M. (1998). Intumescence and Polymer Blending: an Approach for Flame Retardancy, NIST Annual Conference, Gaithersburg.
9. Bourbigot, S., Le Bras, M. and Delohel, R.J. (1996). Synergistic Effect of Zeolite in an Intumescence Process: Study of the Carbonaceous Structures Using Solid State NMR, Chem. Soc. Faraday Trans., 92: 149-158.
10. Mamleev, V.Sh. and Gibov, K.M. (1998). In Fire Retardancy of Polymers: The Use of Intumescence, The Royal Chemical Society, Cambridge.
11. Camino, G., Costa, L. and Trossarelli, L. (1984). Study of the Mechanism of Intumescence in Fire Retardant Polymers: Part I - Thermal Degradation of Ammonium Polyphosphate-Pentaerythritol Mixtures, Polymer Degradation and Stability, 6: 243.
12. Chiu, S. and Wu-kou, W. (1998). The Dynamic Flammability and Toxicity of Magnesium Hydroxide Filled Intumescent Fire Retardant Polypropylene, Journal of Applied Polymer Science, 67: 989-995.
13. Le Bras, M., Bourbigot, S. and Delports, S. (1996). New Intumescent Formulations of Fire-retardant Polypropylene - Discussion of the Free Radical Mechanism of the Formation of Carbonaceous Protective Material During the Thermo-oxidative Treatment of the Additives, Fire and Materials, 20: 191.
14. Fontanelli, R., Landoni, G., Legnani, G. and Saronno. (1985). Self-extinguishing Polymeric Compositions, U.S. Pat. 4, 504, 610.
15. Torro-palau, A., Fernadez-Garcia, J. and Orgiles-Barcelo, A. (1997). Characterization of Solvent-based Polyurethane Adhesives Containing Sepiolite as a Filler - Rheplogical, Mechanical, Surface and Adhesion Properties, Journal of Adhesion Science and Technology, 11(2): 247-262.
16. Zongming, W., Xianxiang, H. and Dianqing, S. (1982). Useful Analysis of Infrared Spectrum of Polymers, Petroleum Industry Publication, Beijing.
17. Katritzky, A.R. (1963). Physical Methods in Hetrocyclic Chemistry, Academic Press, New York and London.
18. West, W. (1956). Chemical Applications of Spectroscopy, Rochester Eastman Kodak Company, New York.
19. Yongcheng, N. (2000). Structural Identification of Organic Compounds and Organic Spectroscopy, Science Publication, Beijing.
20. Delobel, R., Le Bras, M., Onasson, N. and Alistiqsa, F. (1990). Thermal Behaviors of Ammonium Polyphosphate-Pentaerythritol Intumescent Additives in Polypropylene Formulations, Journal of Fire Sciences, 8(2): 85.
21. Fengchang, Z. and Yueliang, L. (1988). Functional Coatings, Chemical Industry Publication, Beijing.
22. Chen-Yang, Y.W., Chuang, J.R., Yang, Y.C. and Chiu, Y.S. (1998). New UV-Curable Cydotriphosphazenes as Fire-Retardant Coating Materials for Wood, Journal of Applied Polymer Science, 69: 115-122.
23. Bertelli, G., Camino, G., Marchetti, E., Costa, L. and Locattli, R. (1989). Studies on Chars from Intumescent Systems, Angew Makromol Chem., 169: 137-142.
24. Bertelli, G., Marchetti, E., Camino, G., Costa, L. and Locattli, R. (1990). Intumescent Fire Retardant Systems, Angew Makromol Chem., 172: 156-163.
25. Zhang, J., Horrocks, A.R. and Hall, M.E. (1994). The Flammability of Polyacrylonitrile and Its Copolymers - IV. The Flame Retardant Mechanism of Polyphosphate, Fire and Materials, 18: 307-312.
26. Le Bras, M., Bourbigot, S., Le Tallec, Y. and Laureyns, J. (1997). Synergy in Intumescence - Application to β-cydodextrin Carbonization Agent in Intumescent Additives for Fire Retardant Polyethylene Formulations, Polymer Degradation and Stability, 56: 11-21.
27. Moric, L., Bourbigot, S. and Leroy, J. M. (1997). Heat Transfer Study of Polypropylene-based Intumescent Systems during Combustion, Journal of Fire Sciences, 15: 358-374.
28. Lambonrne, R. (1987). Paint and Surface Coatings: Theory and Practice, Ellis Horwood Limited, Chichester.
29. Hegedus, C.R. and Kamel, I.L. (1993). Polymer-Filler Interaction Effects on Coating Properties, Journal of Coatings Technology, 822(65): 37-43.