An elongated dihydrogen complex of iridium

Journal of the American Chemical Society

Volumn 125, Issue 28, 2003, Pages 8428-8429

  Pons, Vincent ^a   Heinekey, D Michael ^a  

^a UNIVERSITY OF WASHINGTON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

IRIDIUM; IRIDIUM COMPLEX;

ARTICLE; CIS ISOMER; COMPLEX FORMATION; CORRELATION ANALYSIS; ELECTRON DIFFRACTION; HYDROGEN BOND; ISOTOPE ANALYSIS; QUANTITATIVE ANALYSIS; STRUCTURE ANALYSIS; TEMPERATURE DEPENDENCE; TRANS ISOMER;

EID: 0038037376     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja035555j     Document Type: Article

References (21)

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5. HH: Hush, N. S. J. Am. Chem. Soc. 1997, 119, 1717-1719. An extensive analysis of this relationship including dihydride complexes has been reported: Gründemann, S.; Limbach, H. H.; Buntkowsky, G.; Sabo-Etienne, S.; Chaudret, B. J. Phys. Chem. A 1999, 103, 4752-4754.
6. HH: Hush, N. S. J. Am. Chem. Soc. 1997, 119, 1717-1719. An extensive analysis of this relationship including dihydride complexes has been reported: Gründemann, S.; Limbach, H. H.; Buntkowsky, G.; Sabo-Etienne, S.; Chaudret, B. J. Phys. Chem. A 1999, 103, 4752-4754.
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10. + has been previously reported: Valderrama, M.; Contreras, R. J. Organomet. Chem. 1996, 513, 7-15.
11. + has been previously reported: Valderrama, M.; Contreras, R. J. Organomet. Chem. 1996, 513, 7-15.
12. 2O: C, 31.58; H, 5.83. Found: C, 31.65; H, 5.89.
13. + by X-ray diffraction. The structure is unremarkable, with an Ir-Cl bond distance of 2.38 Å. This is significantly shorter than the Ru - Cl distance of 2.44 Å previously reported in the neutral Ru analogue Cp*Ru(dmpm)Cl: Smith Jr., D. C.; Haar, C. M.; Luo, L.; Li, C.; Cucullu, M. E.; Mahler, C. H.; Notan, S. P.; Marshall, W. J.; Jones, N. L.; Fagan, P. J. Organometallics 1999, 18, 2357-2361.
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16. -1.
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