Zinc-mediated synthesis of α-C-glycosides from 1,2-anhydroglycosides

Synlett

Volumn , Issue 6, 2003, Pages 870-872

  Xue, Song ^a   Han, Kai Zhen ^a   He, Lin ^a   Guo, Qing Xiang ^a  

^a UNIVERSITY OF SCIENCE AND TECHNOLOGY OF CHINA   (China)

Author keywords

Epoxide; Organozinc reagents; Stereo selectivity; Trifluoroacetic acid; C glycosides

Indexed keywords

1,2 ANHYDROGLYCOSIDE DERIVATIVE; GLYCOSIDE; UNCLASSIFIED DRUG; ZINC DERIVATIVE;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; SYNTHESIS;

EID: 0037955984     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2003-38751     Document Type: Article

References (26)

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21. 6b
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25. 11a
26. For comparison, the reaction of n-butylmagnesium chloride with epoxide 2 in THF from -78°C to 0°C gave a 45:55 mixture of α- and β-C-glycoside.