Efficient asymmetry generation in the synthesis of oxo-rhenium(v) complex cis-[ReOCl2{OCMe2CMe2OP (OCMe2CMe2O)}py]

Angewandte Chemie - International Edition

Volumn 42, Issue 15, 2003, Pages 1725-1727

  Rybak, Witold K ^a   Skarzyńska, Anna ^a   Głowiak, Tadeusz ^a  

^a UNIVERSITY OF WROC AW   (Poland)

Author keywords

Asymmetric amplification; Autocatalysis; Chiral resolution; Configuration determination; Rhenium

Indexed keywords

CATALYSTS; CRYSTALLIZATION; SPECTROSCOPIC ANALYSIS; SYNTHESIS (CHEMICAL);

ENANTIOMERS;

RHENIUM COMPOUNDS;

PYRIDINE; RHENIUM COMPLEX;

ARTICLE; ASYMMETRIC CATALYSIS; CHELATION; CHIRALITY; CIS TRANS ISOMERISM; CRYSTALLIZATION; ENANTIOMER; ISOMERISM; NUCLEAR MAGNETIC RESONANCE; SYNTHESIS; X RAY DIFFRACTION;

EID: 0037879283     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200219501     Document Type: Article

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40. The cis complex, C or rac, stirred and boiled in toluene for 5 h, affords the trans complex in 10.5 % or 17.5% yields, respectively, and the corresponding cis complex with ee + 99% or ee 0% (rac). After another 15 h reaction time, no further conversion was observed within the experimental error (Supporting Information).