Synthesis and structural characterization of a new molecule-based complex constructed from dodecamolybdophosphoric acid and imidazole

Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

Volumn 33, Issue 4, 2003, Pages 533-546

  Han, Zheng Bo ^a   Wang, Xiu Li ^a   Wang, En Bo ^a   Luan, Guo You ^a   Hu, Chang Wen ^a   Hu, Ning Hai ^b   Jia, Heng Qing ^b  

^a NORTHEAST NORMAL UNIVERSITY   (China)

^b CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY   (China)

Author keywords

Crystal structure; Molecule based complex; Polyoxometalate; Synthesis

Indexed keywords

ANION; IMIDAZOLE DERIVATIVE; METAL DERIVATIVE; N,N DIMETHYLFORMAMIDE; PHOSPHORIC ACID DERIVATIVE;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; COMPARATIVE STUDY; COMPLEX FORMATION; CRYSTAL; CRYSTAL STRUCTURE; CRYSTALLIZATION; ELECTRICITY; ELECTRON SPIN RESONANCE; HYDROGEN BOND; INFRARED RADIATION; INFRARED SPECTROSCOPY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STRUCTURE ANALYSIS; SYNTHESIS; ULTRAVIOLET SPECTROSCOPY; X RAY CRYSTALLOGRAPHY;

EID: 0037864542     PISSN: 00945714     EISSN: None     Source Type: Journal    
DOI: 10.1081/SIM-120020322     Document Type: Article

References (30)

1. Coronado, E.; Gómez-García, C.J. Polyoxometalate-based molecular materials. Chem. Rev. 1998, 98, 273-296.
2. Wang, E.B.; Hu, C.W.; Xu, L. Concise Polyoxometalates; Chemical Industry Press. Beijing, 1997; 110-176.
3. Lehn, J.M. Supramolecular chemistry-scope and perspectives molecules, supermolecules, and molecular devices. Angew. Chem., Int. Ed. Engl. 1988, 27, 89-112.
4. Deborah, G.S.; Judd, D.; Hill, C.L. Synthesis, characterization, and biological activity of a new potent class of anti-HIV agents, the peroxoniobium-substituted heteropolytungstates. J. Med. Chem. 1994, 37, 816-820.
5. Pope, M.T. Heteropoly and Isopoly Oxometalates; Springer. New York, 1983; 58-98.
6. 2O. J. Mol. Struct. 2000, 525, 71-77.
7. 2O. Inorg. Chem. 1994, 33, 5586-5590.
8. 2O. J. Chem. Soc., Dalton Trans. 1990, 3221-3228.
9. Peng, J.; Wang, E.B.; Zhou, Y.S. Synthesis, electric properties and crystal structure of a new radical-ion salt based on TTF and a keggin heteropolymolybdate. J. Chem. Soc., Dalton Trans. 1998, 3865-3872.
10. 40}]. Inorg. Chem. 2001, 21, 5468-5471.
11. 2O. J. Mol. Struct. 2001, 595, 7-13.
12. Sugiura, K.; Sakata, Y.; Tanaka, T.; Sawada, M. Anion controlled donor alignment: electrosynthesis and crystal structure of a novel cation radical salt constructed from porphyrin and hexatungstate. Chem. Lett. 1997, 26, 281-282.
13. Han, Z.B.; Wang, E.B.; Luan, G.Y. Synthesis and crystal structure of a novel compound constructed from tris(2,2′-bipyridine)ruthenium(II) and decatungstate. Inorg. Chem. Commun. 2001, 4, 427-429.
14. Wu, H. Synthesis of dodecamolybdophosphoric acid. J. Biol. Chem. 1920, 43, 4, 189-190.
15. Siemens. SHELXTL Version 5.0; Siemens Industrial Automation, Analytical Instrumentation. Madison, WI, 1995.
16. 2 (BEST = Bis(ethylenediseleno) tetrathiafulvalene). Inorg. Chem. 1998, 37, 2183-2188.
17. Rocchiccioli-Deltcheeft, L.; Fournier, M.; Franck, R. Vibrational investigations of polyoxometalates. 2. Evidence for anion-anion interactions in molybdenum(VI) compounds related to the Keggin structure. Inorg. Chem. 1983, 22, 207-216.
18. Bi, L.H.; Wang, E.B.; Xu, L.; Huang, R.D. Synthesis, properties and crystal structure of some polyoxometalates containing the tris(hydroxymethyl)aminomethane cation. Inorg. Chem. Acta 2000, 305, 163-171.
19. Szymanski, H.A.; Yelin, R.E. NMR Hand Handbook; Plenum York-Washington, 1968; 172.
20. Strickland, D.H. The preparation and properties of silicomolybdic acid. I. The properties of alpha silicomolybdic acid. J. Am. Chem. Soc. 1952, 74, 862-867.
21. Niu, J.Y.; Wang, J.P.; You, X.Z. Transition metal disubstituted ternary heteropolyoxometallate: synthesis, characterization, crystal structure and magetic properties. Polyhedron 1996, 15, 3963-3969.
22. Liu, J.; Wang, E.B.; Peng, J. Synthesis properties and preventing plant virus activity of rare earth molybdophosphoric heteropoly blues. J. Chin. Rare Earth Soc. 1999, 1, 65-70.
23. Fruchaart, J.M.; Herevé, G.; Launay, J.P.; Massart, R. Electronic spectra of mixed valence reduced heteropolyanions. Inorg. Nucl. Chem. 1976, 38, 1627-1634.
24. 2O. J. Mater. Chem. 2002, 4, 1169-1173.
25. Fuchs, J.; Tiele, A.; Palm, R. The norbornyl cation prototype of a 1,3-bridged carbocation. Angew. Chem., Int. Ed. Engl. 1982, 23, 87-88.
26. Evans, H.T.; Pope, M.T. Reinterpretation of five recent crystal structures of heteropoly and isopoly complexes: divanadodecamdybdophosphate, trivanadoenneamolybdophosate 'γ-dodecatungstophosphate', the dodecamolybdate blue complex and dihydrogen decavanadate. Inorg. Chem. 1984, 23, 501-504.
27. n. Inorg. Chem. 1994, 33, 5180-5187.
28. 6 = 18-crown-6). J. Mol. Struct. 2000, 524, 133-139.
29. 2O (DMA=N,N-dimethylacetamide). Inorg. Chem. 1987, 26, 1436-1441.
30. 3CN). Inorg. Chem. 1995, 34, 4139-4146.