Metal insertion into the open face of an isonido-metallathiaborane cluster: Formation and characterization of [2-PPh3- 2,3-Cl2-2,3-(μ-Cl)-3,7-(μ-dppm)-closo-2,3,1-Rh2 SB9H8] from [1-PPh3-{1,3-(μ-dppm)}-isonido-1,2-RhSB9H8]

Organometallics

Volumn 22, Issue 13, 2003, Pages 2548-2550

  Volkov, Oleg ^a,b   Rath, Nigam P ^a   Barton, Lawrence ^a  

^a UNIVERSITY OF MISSOURI ST LOUIS   (United States)

^b NIKOLAEV INSTITUTE OF INORGANIC CHEMISTRY   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC COMPOUNDS; BORON COMPOUNDS; DIAMONDS; MOLECULAR STRUCTURE; REACTION KINETICS;

DIAMOND SQUARE DIAMOND; ISONIDO METHALLATHIABORANE CLUSTER; LIGAND EXCHANGE; METAL INSERTION;

ORGANOMETALLICS;

EID: 0037861834     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0301177     Document Type: Article

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21. 12 (6 mg, 0.005 mmol; 39%).
22. 11B} NMR (500 MHz): δ 4.36 (1H, BH), 3.67 (1H, BH), 3.55 (2H, BH), 3.28 (1H, BH), 2.41 (2H, BH), 2.15 (1H, BH).
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