Organic syntheses via transition metal complexes. 116. Carbocyclic four-, five-, and six-membered rings by condensation of (alkyl,ethoxy)carbene complexes (M = W, Cr) with α,β-unsaturated tertiary acid amides

Organometallics

Volumn 21, Issue 8, 2002, Pages 1637-1645

  Aumann, Rudolf ^a   Vogt, Dominik ^a   Fu, Xiaolin ^a   Fröhlich, Roland ^a   Schwab, Pia ^b  

^a UNIVERSITY OF MÜNSTER   (Germany)

^b DRESDEN UNIVERSITY OF TECHNOLOGY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ACIDS; ADDITION REACTIONS; COMPLEXATION; HYDROCARBONS; SYNTHESIS (CHEMICAL); TRANSITION METALS; TUNGSTEN;

ORGANIC SYNTHESES;

ORGANOMETALLICS;

EID: 0037812659     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0108604     Document Type: Article

References (55)

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48. Data sets were collected with Nonius MACH3 and KappaCCD diffractometers, equipped with a Nonius FR591 rotating anode generator. Programs used: data collection EXPRESS (Nonius B.V., 1994) and COLLECT (Nonius B.V., 1998), data reduction MolEN (Fair, K. Enraf-Nonius E.V., 1990) and Denzo-SMN (Otwinowski, Z., Minor, W. Methods Enzymol. 1997, 276, 307-326), absorption correction for CCD data SORTAV (Blessing, R. H. Acta Crystallogr. 1995, A51, 33-37. Blessing, R. H. J. Appl. Crystallogr. 1997, 30, 421-426), structure solution SHELXS-86 and SHELXS-97 (Sheldrick, G. M. Acta Crystallogr. 1990, A46, 467-473), structure refinement SHELXL-93 and SHELXL-97 (Sheldrick, G. M. Universität Göttingen, 1997), graphics DIAMOND (Brandenburg, K. Universität Bonn, 1997).
49. Data sets were collected with Nonius MACH3 and KappaCCD diffractometers, equipped with a Nonius FR591 rotating anode generator. Programs used: data collection EXPRESS (Nonius B.V., 1994) and COLLECT (Nonius B.V., 1998), data reduction MolEN (Fair, K. Enraf-Nonius E.V., 1990) and Denzo-SMN (Otwinowski, Z., Minor, W. Methods Enzymol. 1997, 276, 307-326), absorption correction for CCD data SORTAV (Blessing, R. H. Acta Crystallogr. 1995, A51, 33-37. Blessing, R. H. J. Appl. Crystallogr. 1997, 30, 421-426), structure solution SHELXS-86 and SHELXS-97 (Sheldrick, G. M. Acta Crystallogr. 1990, A46, 467-473), structure refinement SHELXL-93 and SHELXL-97 (Sheldrick, G. M. Universität Göttingen, 1997), graphics DIAMOND (Brandenburg, K. Universität Bonn, 1997).
50. Data sets were collected with Nonius MACH3 and KappaCCD diffractometers, equipped with a Nonius FR591 rotating anode generator. Programs used: data collection EXPRESS (Nonius B.V., 1994) and COLLECT (Nonius B.V., 1998), data reduction MolEN (Fair, K. Enraf-Nonius E.V., 1990) and Denzo-SMN (Otwinowski, Z., Minor, W. Methods Enzymol. 1997, 276, 307-326), absorption correction for CCD data SORTAV (Blessing, R. H. Acta Crystallogr. 1995, A51, 33-37. Blessing, R. H. J. Appl. Crystallogr. 1997, 30, 421-426), structure solution SHELXS-86 and SHELXS-97 (Sheldrick, G. M. Acta Crystallogr. 1990, A46, 467-473), structure refinement SHELXL-93 and SHELXL-97 (Sheldrick, G. M. Universität Göttingen, 1997), graphics DIAMOND (Brandenburg, K. Universität Bonn, 1997).
51. Data sets were collected with Nonius MACH3 and KappaCCD diffractometers, equipped with a Nonius FR591 rotating anode generator. Programs used: data collection EXPRESS (Nonius B.V., 1994) and COLLECT (Nonius B.V., 1998), data reduction MolEN (Fair, K. Enraf-Nonius E.V., 1990) and Denzo-SMN (Otwinowski, Z., Minor, W. Methods Enzymol. 1997, 276, 307-326), absorption correction for CCD data SORTAV (Blessing, R. H. Acta Crystallogr. 1995, A51, 33-37. Blessing, R. H. J. Appl. Crystallogr. 1997, 30, 421-426), structure solution SHELXS-86 and SHELXS-97 (Sheldrick, G. M. Acta Crystallogr. 1990, A46, 467-473), structure refinement SHELXL-93 and SHELXL-97 (Sheldrick, G. M. Universität Göttingen, 1997), graphics DIAMOND (Brandenburg, K. Universität Bonn, 1997).
52. Signal not observed due to dynamic line-broadening.
53. One signal missing probably due to overlap with signals of the major isomer.
54. 2,3J(C,H) correlation experiments.
55. 3J(3′H,4′-H) = 4.9 Hz.