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The thiazolium-5-tert-butylaminides 2 are not stabilized by an electron-withdrawing substituent on the exocyclic nitrogen atom. They have been trapped by a dipolarophile in the basic medium.
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note
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Full details of the X-ray structure determinations have been deposited with the Cambridge Cristallographic Data Centre and can be obtained, on request, with quotation of the registry numbers 101259 for 3a and 102044 for 9, the names of the authors and the reference to this article.
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