Chelating P,N versus P,P ligands: Differing reactivity of donor-stabilized pt(η2-PhC≡CPh) complexes toward diphenylacetylene

Organometallics

Volumn 21, Issue 6, 2002, Pages 1118-1123

  Müller, Christian ^a   Lachicotte, Rene J ^a   Jones, William D ^a  

^a UNIVERSITY OF ROCHESTER   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

THERMAL ACTIVATION;

CHELATION; CHEMICAL ACTIVATION; CHEMICAL BONDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PLATINUM COMPOUNDS; SYNTHESIS (CHEMICAL);

ORGANOMETALLICS;

EID: 0037716504     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om010924a     Document Type: Article

References (51)

1. (a) Lautens, M.; Klute, W.; Tam, W. Chem. Rev. 1996, 96, 49.
2. (b) Grotjahn, D. B. In Comprehensive Organometallic Chemistry II; Abel. E. W., Stone, F. G. A., Wilkinson, G., Eds.; Elsevier Science Ltd: Oxford, 1996; Vol. 12, p 741.
3. (c) Schore, N. E. In Comprehensive Organic Synthesis; Trost, B. M., Fleming, I., Eds.; Pergamon Press Ltd: Oxford, 1991; Vol. 5, p 1129.
4. (d) Schore, N. E. Chem. Rev. 1988, 88, 1081.
5. (e) Vollhardt, K. P. C. Angew. Chem., Int. Ed. Engl. 1984, 23, 539.
6. See for example: (a) Eisch, J. J.; Ma, X.; Han, K. I.; Gitua, J. N.; Krüger, C. Eur. J. Inorg. Chem. 2001, 77, and references therein.
7. (b) Cámpora, J.; Palma, P.; Carmona, E. Coord. Chem. Rev. 1999, 193-195, 207, and references therein.
8. (c) Otsuka, S.; Nakamura, A. Adv. Organomet. Chem. 1976, 14, 245, and references therein.
9. (a) Tom Dieck, H.; Fendesak, G.; Munz, C. Polyhedron 1991, 10, 255.
10. (b) Tom Dieck, H.; Munz, C.; Müller, C. J. Organomet. Chem. 1990, 384, 243.
11. (c) Boag, N. M.; Dias, G. H. M.; Green, M.; Spencer, J. L.; Stone, F. G. A.; Vicente, J. J. Chem. Soc., Dalton Trans. 1981, 1981.
12. (a) Hasebe, K.; Kamite, J.; Mori, T.; Katayama, H.; Ozawa, F. Organometallics 2000, 19, 2022.
13. (b) Anderson, G. K.; Lumetta, G. J.; Siria, J. W. J. Organomet. Chem. 1992, 434, 253.
14. (c) Osborn, J. A.; Wilkinson, G.; Mrowca, J. J. Inorg. Synth. 1990, 28, 77.
15. (d) Hackett, M.; Ibers, J. A.; Whitesides, G. M. J. Am. Chem. Soc. 1988, 110, 1436.
16. (e) Hackett, M.; Whitesides, G. M. J. Am. Chem. Soc. 1988, 110, 1449.
17. (f) Ros, R.; Michelin, R. A.; Bataillard, R.; Roulet, R. J. Organomet. Chem. 1978, 161, 75.
18. (g) Smart, L. E.; Browning, J.; Green, M.; Laguna, A.; Spencer, J. L.; Stone, F. G. A. J. Chem. Soc., Dalton Trans. 1977, 1777.
19. (h) Chatt, J.; Rowe, G. A.; Williams, A. A. Proc. Chem. Soc. 1957, 208.
20. (i) Allen, A. D.; Cook, C. D. Can. J. Chem. 1964, 42, 1063.
21. (a) Klein, R. A.; Witte, P.; van Belzen, R.; Fraanje, J.; Goubitz, K.; Numan, M.; Schenk, H.; Ernsting, J. M.; Elsevier, C. J. Eur. J. Inorg. Chem. 1998, 319.
22. (b) De Felice, V.; De Renzi, A.; Ruffo, F.; Tesauro, D. Inorg. Chim. Acta 1994, 219, 169.
23. Park, S.; Hedden, D.; Rheingold, A. L.; Roundhill, D. M. Organometallics 1986, 5, 1305.
24. (a) Green, M.; Grove, D. M.; Howard, J. A. K.; Spencer, J. L.; Stone, F. G. A. J. Chem. Soc., Chem. Commun. 1978, 759.
25. (b) Boag, N. M.; Green, M.; Grove, D. M.; Howard, J. A. K.; Spencer, J. L.; Stone, F. G. A. J. Chem. Soc., Dalton Trans. 1980, 2170.
26. (c) Boag, N. M.; Green, M.; Howard, J. A. K.; Spencer, J. L.; Stansfield, R. F. D.; Thomas, M. D. O.; Stone, F. G. A.; Woodward, P. J. Chem. Soc., Dalton Trans. 1980, 2182.
27. Schager, F.; Haack, K.-J.; Mynott, R.; Rufiñska, A.; Pörschke, K.-R. Organometallics 1998, 17, 807.
28. Müller, C.; Iverson, C. N.; Lachicotte, R. J.; Jones, W. D. J. Am. Chem. Soc. 2001, 123, 9718.
29. For the concept of hemilability see for example: (a) Jeffrey, J. C.; Rauchfuss, T. B. Inorg. Chem. 1979, 18, 2658.
30. (b) Braunstein, P.; Naud, F. Angew. Chem., Int. Ed. 2001, 40, 680.
31. (b) Müller, C.; Vos, D.; Jutzi, P. J. Organomet. Chem. 2000, 600, 127.
32. (c) Slone, C. S.; Weinberger,.D. A.; Mirkin, C. A. Prog. Inorg. Chem. 1999, 48 233.
33. (d) Okuda, J. Comments Inorg. Chem. 1994, 16 185.
34. Pearson, R. G.; Scott, A. In Survey of Progress in Chemistry; Academic Press: New York, 1969; Chapter 1.
35. Werner, H.; Hampp, A.; Peters, K.; Peters, E. M.; Walz, L.; von Schnering, H. G. Z. Naturforsch. 1990, 45b, 1548.
36. (a) Fryzuk, M. D.; Jones, T.; Einstein, F. W. B. Organometallics 1984, 3, 185.
37. (b) Burg, R. J.; Chatt, J.; Hussain, W.; Leigh, G. J. J. Organomet. Chem. 1979, 182, 203.
38. The C≡C bond length in free diphenylacetylene is 1.198(4) Å: Mavriris, A.; Moustakali-Mavridis, I. Acta Crystallogr. 1977, B33, 3612.
39. (a) Bartik, T.; Happ, B.; Iglewsky, M.; Bandmann, H.; Boese, R.; Heimbach, P.; Hoffmann, T.; Wensohuh, E. Organometallics 1992, 11, 1235.
40. (b) Rosenthal, U., Schulz, W. J. Organomet. Chem. 1987, 321, 103.
41. (c) Tatsumi, K.; Hoffmann, R.; Templeton, J. L. Inorg. Chem. 1982, 21, 466.
42. (d) Hey, E.; Weller, F.; Dehnicke, K. Z. Anorg. Allg. Chem. 1984, 514, 18.
43. (e) Dewar, M. J. S.; Ford, G. P. J. Am. Chem. Soc. 1979, 101, 783.
44. (f) Hartley, F. R. Angew. Chem. 1972, 84, 667.
45. (g) Nelson, J. H.; Wheelock, K. S.; Cusachs, L. C.; Jonassen, H. B. J. Am. Chem. Soc. 1969, 91, 7005.
46. (h) Greaves, E. O.; Lock, C. J. L.; Maitlis, P. M. Can. J. Chem. 1968, 46, 3879.
47. (i) Dewar, M. J. S. Bull. Soc. Chim. Fr. 1951, 18, C79.
48. (j) Chatt, J.; Duncanson, L. A. J. Chem. Soc. 1983, 2939.
49. Glanville, J. O.; Stewart, J. M.; Grim, S. O. J. Organomet. Chem. 1967, 7, P9.
50. Gastinger, R. G.; Rausch, M. D., Sullivan, D. A.; Palenik, G. J. J. Am. Chem. Soc. 1976, 98, 719.
51. Pörschke, K.-R. Angew. Chem., Int. Ed. Engl. 1987, 26, 1288.