Improvement in ductility of chitosan through blending and copolymerization with PEG: FTIR investigation of molecular interactions

Biomacromolecules

Volumn 4, Issue 1, 2003, Pages 173-180

  Kolhe, Parag ^a   Kannan, Rangaramanujam M ^a  

^a Wayne State University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

MOLECULAR INETRACTIONS;

COPOLYMERIZATION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; MEDICAL APPLICATIONS; POLYETHYLENE GLYCOLS; POLYMER BLENDS; X RAY DIFFRACTION ANALYSIS;

BIOMATERIALS;

BIOMATERIAL; CHITOSAN; COPOLYMER; MACROGOL;

ARTICLE; CHEMICAL COMPOSITION; CHEMICAL PROCEDURES; CHEMICAL STRUCTURE; CONTROLLED STUDY; CRYSTALLIZATION; FILM; INFRARED SPECTROSCOPY; MOLECULAR INTERACTION; POLYMERIZATION; PRIORITY JOURNAL; X RAY DIFFRACTION; YOUNG MODULUS;

BINDING SITES; CALORIMETRY, DIFFERENTIAL SCANNING; CARBOHYDRATE CONFORMATION; CHITIN; CHITOSAN; MOLECULAR CONFORMATION; POLYETHYLENE GLYCOLS; SPECTROSCOPY, FOURIER TRANSFORM INFRARED; THERMODYNAMICS; X-RAY DIFFRACTION;

EID: 0037687576     PISSN: 15257797     EISSN: None     Source Type: Journal    
DOI: 10.1021/bm025689+     Document Type: Article

References (24)

1. Muzzarelli, R. A. A.; Jeuniaux, C.; Gooday, G. W. Chitin in nature and technology; Plenum: New York, 1986.
2. Madihally, S. V.; Matthew, H. W. T. Porous chitosan scaffolds for tissue engineering. Biomaterials 1999, 20 (12), 1133-1142.
3. Ratto, J. A.; Chen, C. C.; Blumstein, R. Phase behavior study of chitosan/polyamide blends. J. Appl. Polym. Sci. 1996, 59, 1451-1461.
4. Dufresne, A.; Cavaillé, J.-Y.; Dupeyre, D.; Garcia-Ramirez, M.; Romero, J. Morphology, phase continuity and mechanical behavior of polyamide 6/chitosan blends. Polymer 1999, 40 (7), 1657-1666.
5. Mucha, M.; Piekielna J.; Wieczorek, A. Characterization and morphology of biodegradable chitosan/synthetic polymer blends. Macromol. Symp. 1999, 144, 391-412.
6. Alekseev, V. L.; Kel'berg, E. A.; Bronnikov, S. V.; Evmenenko, G. A. Structure and mechanical properties of chitosan-poly(ethylene oxide) blend films. Polym. Sci., Ser. B 2001, 43, 281-284.
7. Alexeev, V. L.; Kelberg, E. A.; Evmenenko, G. A.; Bronnikov, S. V. Improvement of the mechanical properties of chitosan films by the addition of poly (ethylene oxide). Polym. Eng. Sci. 2000, 40, 1211-1215.
8. Wang, W.; Roberts, G. A. F. Effect of acetyl group content on the miscibility of blends of chitosan with poly(ethylene oxide). Adv. Chitin Sci. 1997, 2, 561-566.
9. Zhao, W.; Yu, L.; Zhong, X.; Zhang, Y.; Sun, J. The compatibility and morphology of chitosan-poly (ethylene oxide) blends. J. Macromol. Sci. Phys. 1995, B34 (3), 231.
10. Harris, J. M., Zalipsky, S., Eds. Poly(ethylene glycol): Chemistry and Biological Applications; ACS Symposium Series 680; American Chemical Society: Washington, DC, 1997.
11. Domszy, J. G.; Roberts, G. A. F. Evaluation of Infrared Spectroscopic techniques for analyzing Chitosan. Makromol. Chem. 1985, 186 (8), 1671-1677.
12. Rathke, T. D.; Hudson, S. M. Determination Of The Degree Of N-Deacetylation In Chitin And Chitosan As Well As Their Monomer Sugar Ratios By Near-Infrared Spectroscopy. J. Polym. Sci., Part A: Polym. Chem. 1993, 31 (3), 749-753.
13. Shigemasa, Y.; Matsuura, H.; Sashiwa, H.; Saimoto, H. Evaluation of different absorbance ratios from infrared spectroscopy for analyzing the degree of deacetylation in chitin. Int. J. Biol. Macromol. 1996, 18 (3), 237-242.
14. Zhang, M.; Li, X. H.; Gong, Y. D.; Zhao, N. M.; Zhang, X. F. Properties and biocompatibility of chitosan films modified by blending with PEG. Biomaterials 2002, 23, 2641-2648.
15. Bentley, M. D.; Roberts, M. J.; Harris, M. Reductive amination using poly (ethylene glycol) acetaldehyde hydrate generated in situ: applications to chitosan and lysozyme. J. Pharm. Sci. 1998, 87 (11), 1446-1449.
16. Zhong, J.; Matthew, H. W. T. Crystallinity of dry materials of PEG-modified chitosan, manuscript in preparation.
17. Sakurai, K.; Maegawa, T.; Takahashi, T. Glass transition temperature of chitosan and miscibility of chitosan/poly(N-vinyl pyrrolidone) blends. Polymer 2000, 41, 7051-7056.
18. Harish Prashanth, K. V.; Kittur, F. S.; Tharanathan, R. N. Solid-state structure of chitosan prepared under different N-deacetylating conditions. Carbohydr. Polym. 2002, 50 (1), 27-33.
19. Corrigan, D. O.; Healy, A. M.; Corrigan, O. I. The effect of spray drying solutions of poly(ethylene glycol) (PEG) and lactose/PEG on their physicochemical properties. Int. J. Pharm. 2002, 235 (1-2), 193-205.
20. Socrates, G. Infrared Characteristic Group Frequencies, Tables and charts, 2nd ed.; John Wiley and sons: Chichester, U.K., 1994.
21. Painter, P.; Coleman, M. M. Fundamentals of polymer science, 2nd ed.; Technomic Publishing Co.: Lancaster, PA, 1997.
22. Coleman, M. M.; Graf, J. F.; Painter, P. C. Specific interactions and the miscibility of polymer blends; Technomic Publishing: Lancaster, PA, 1991.
23. Moss, D.; Nabedryk, E.; Breton, J.; Mantele, W. Redox-linked Conformational Changes in Proteins Detected by a Combination of IR Spectroscopy and Protein Electrochemistry. Evaluation of the Technique with Cytochrome c. Eur. J. Biochem. 1990, 187, 565-572.
24. Jiang, W. H.; Han, S. J. Study of interaction between poly(ethylene glycol) and chitosan by viscosity method. J. Polym. Sci., Part B: Polym. Phys. 1998, 36, 1275-1281.