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Volumn 22, Issue 7, 2003, Pages 1358-1360

The first coordination of an (α-diazo)phosphine to a transition-metal center

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; COMPLEXATION; PHOSPHORUS; X RAY DIFFRACTION;

EID: 0037474877     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0210558     Document Type: Article
Times cited : (4)

References (49)
  • 19
    • 0037008597 scopus 로고    scopus 로고
    • (b) Despagnet, E.; Gornitzka, H.; Eozhenko, A. B.: Schoeller, W. W.; Bourissou, D.; Bertrand, G. Angew. Chem. 2002, 114, 2959; Angew. Chem., Int. Ed. 2002,41, 2835.
    • (2002) Angew. Chem., Int. Ed. , vol.41 , pp. 2835
  • 30
    • 0013002491 scopus 로고    scopus 로고
    • note
    • 15 An excess of rhodium complex allows the coordination equilibration to be displaced and, thus, to complete the conversion of 1.
  • 32
    • 0012909918 scopus 로고    scopus 로고
    • note
    • 31P NMR spectroscopy). Orange crystals of 2 (38 mg, 52%) were obtained by cooling the ether solution to -80 °C. Mp: 75 °C dec.
  • 33
    • 0013002082 scopus 로고    scopus 로고
    • note
    • 2; 0.12 mmol) at room temperature. After the mixture was stirred for 30 min at this temperature, 1 mL of pentane was added and yellow crystals of 3 (60 mg, 64%) were obtained by cooling the solution to -20 °C. Mp: 63 °C dec.
  • 34
    • 0013017967 scopus 로고    scopus 로고
    • note
    • PRh = 224 Hz).
  • 35
    • 0012963352 scopus 로고    scopus 로고
    • note
    • 27 All non-hydrogen atoms were treated anisotropically. The hydrogen atoms were geometrically idealized and refined using a riding model. Crystallographic data (excluding structure factors) have been deposited with the Cambridge Crystallographic Data Centre as Supplementary Publication Nos. CCDC-203087 (2), 203088 (3), and 203089 (3′). Copies of the data can be obtained free of charge on application to the CCDC, 12 Union Road, Cambridge CB2 1 EZ, U.K. (fax, (+44)1223-336-033; email, deposit@ccdc.cam.ac.uk).
  • 40
    • 0002087304 scopus 로고
    • 3D search and research using the Cambridge structural database
    • (b) Allen, F. H.; Kennard, O. 3D Search and Research Using the Cambridge Structural Database. Chem. Design Automation News 1993, 8(1), 1, 31-37.
    • (1993) Chem. Design Automation News , vol.8 , Issue.1 , pp. 1
    • Allen, F.H.1    Kennard, O.2
  • 42
    • 0012908134 scopus 로고    scopus 로고
    • note
    • An investigation of the molecular structure of the mesityl analogue of 3 has been undertaken, and all relevant crystallographic data are reported in the Supporting Information. An geometry identical with that observed for 3 was determined. It should be noted that the mesityl derivative 3′ was considerably more reactive than 3, making its characterization much more difficult.
  • 47
    • 0012911372 scopus 로고
    • VCH: Weinheim, Germany
    • Diazo compounds react with transition-metal fragments either by the carbon or by the terminal nitrogen atoms, with or without nitrogen elimination: Diazo Chemistry; Zollinger, H., Ed.; VCH: Weinheim, Germany, 1995; Vol. 2, pp 439-454.
    • (1995) Diazo Chemistry , vol.2 , pp. 439-454
    • Zollinger, H.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.