Enantiomerically pure phenanthroline or bipyridine containing macrocycles: A new class of ligands for asymmetric catalysis

Tetrahedron Letters

Volumn 44, Issue 14, 2003, Pages 2947-2951

  Puglisi, Alessandra ^a   Benaglia, Maurizio ^a   Annunziata, Rita ^a   Bologna, Alberto ^a  

^a UNIVERSITY OF MILAN   (Italy)

Author keywords

Asymmetric catalysis; Chiral phenanthrolines; Copper(I) complexes; Cyclopropanation; Enantiomerically pure macrocycles

Indexed keywords

ALKENE DERIVATIVE; BIPYRIDINE DERIVATIVE; CIS ACTING ELEMENT; COPPER COMPLEX; LIGAND; MACROCYCLIC COMPOUND; PHENANTHROLINE DERIVATIVE; TRANS ACTING FACTOR;

ARTICLE; ASYMMETRIC CATALYSIS; CHEMICAL MODIFICATION; CHIRALITY; CYCLOPROPANATION; ENANTIOMER; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; STEREOCHEMISTRY; SYNTHESIS;

EID: 0037474678     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(03)00425-8     Document Type: Article

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42. Only a few examples of high cis-stereoselectivity for the cyclopropanation of styrene with ethyldiazoacetate are known, see: (a) Niimi, T.; Uchida, T.; Irie, R.; Katsuki, T. Adv. Synth. Catal. 2001, 343, 79-88 and references cited therein; (b) Bachmann, S.; Furler, M.; Mezzetti, A. Organometallics 2001, 20, 2102-2108; (c) Zheng, Z.; Yao, X.; Li, C.; Chen, H.; Hu, X. Tetrahedron Lett. 2001, 42, 2847-2849; (d) Doyle, P. M.; Davies, S. B.; Hu, W. Chem. Commun. 2000, 867-868 and references cited therein.
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44. Only a few examples of high cis-stereoselectivity for the cyclopropanation of styrene with ethyldiazoacetate are known, see: (a) Niimi, T.; Uchida, T.; Irie, R.; Katsuki, T. Adv. Synth. Catal. 2001, 343, 79-88 and references cited therein; (b) Bachmann, S.; Furler, M.; Mezzetti, A. Organometallics 2001, 20, 2102-2108; (c) Zheng, Z.; Yao, X.; Li, C.; Chen, H.; Hu, X. Tetrahedron Lett. 2001, 42, 2847-2849; (d) Doyle, P. M.; Davies, S. B.; Hu, W. Chem. Commun. 2000, 867-868 and references cited therein.