Stereoselective aldol coupling of α,β-acetylenic ketones promoted by MgI2

Tetrahedron Letters

Volumn 44, Issue 5, 2003, Pages 949-952

  Wei, Han Xun ^a   Hu, Jiali ^a   Purkiss, David W ^a   Paré, Paul W ^a  

^a TEXAS TECH UNIVERSITY   (United States)

Author keywords

, acetylenic ketones; (Z) iodovinyl ketone; Baylis Hillman adducts; Magnesium iodide

Indexed keywords

ALDEHYDE DERIVATIVE; IODINE DERIVATIVE; KETONE DERIVATIVE; LEWIS ACID; MAGNESIUM DERIVATIVE;

ALDOL REACTION; ARTICLE; CATALYSIS; CHEMICAL BOND; CHEMICAL INTERACTION; CHEMICAL REACTION; ISOMER; MICHAEL ADDITION; PROTON NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY; SYNTHESIS;

EID: 0037467815     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(02)02746-6     Document Type: Article

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22. 3): δ 27.4, 77.5, 103.1, 125.1×2, 127.4, 128.4×2, 141.2, 151.1, 196.9.
23. 3): δ 14, 22, 28, 36, 76, 78, 129×2, 130×2, 134, 134, 154, 198.