A delicate balance of energetics. Subtleties associated with α-ketol-based bridge migration to afford 9-keto-10β-p-methoxybenzyloxytaxanes

Journal of Organic Chemistry

Volumn 68, Issue 6, 2003, Pages 2276-2281

  Paquette, Leo A ^a   Lo, Ho Yin ^a   Hofferberth, John E ^a   Gallucci, Judith C ^a  

^a OHIO STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

STERIC ENERGY;

ISOMERIZATION; SYNTHESIS (CHEMICAL); THERMODYNAMICS;

REACTION KINETICS;

9 KETO 10BETA 4 METHOXYBENZYLOXYTAXANE; ALPHA EPOXIDE; ALPHA KETOL; BENZYL DERIVATIVE; CAMPHOR; EPOXIDE; KETOL; PACLITAXEL; UNCLASSIFIED DRUG;

ARTICLE; CALCULATION; CHEMICAL STRUCTURE; ENERGY; ENERGY TRANSFER; ISOMERISM; MOLECULAR MECHANICS; SYNTHESIS; THERMODYNAMICS;

BRIDGED COMPOUNDS; CATALYSIS; COMBINATORIAL CHEMISTRY TECHNIQUES; CRYSTALLOGRAPHY, X-RAY; CYCLIZATION; HYDROXYLATION; INDICATORS AND REAGENTS; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; PACLITAXEL; STEREOISOMERISM; STRUCTURE-ACTIVITY RELATIONSHIP; TAXOIDS; THERMODYNAMICS;

EID: 0037459760     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo020628n     Document Type: Article

References (10)

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