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note
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We tried to prepare ligand 2 with a dedicated organic synthesis, by reacting quinolinealdehyde with an excess of R,R-trans-1,2-diaminocyclohexane. However, due to the comparable solubility in organic solvents of trans-1,2-diaminocyclohexane and 2, we were not able to separate them. Metal-mediated hydrolysis should thus be considered the synthesis of choice for 2.
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note
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2+ molecular cation is also strongly supported by molecular dynamics force field MM + Calculations (Hyperchem 3 for Windows package).
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32
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0012360055
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note
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Identical spectra were found on variation of temperature in the - 25 < T < 20°C range.
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