On the correlation of the activity coefficients in aqueous electrolyte solutions using the K-MSA model

Industrial and Engineering Chemistry Research

Volumn 42, Issue 6, 2003, Pages 1279-1284

  Ghotbi, C ^a   Azimi, G ^a   Taghikhani, V ^a   Vera, Juan H ^b  

^a SHARIF UNIVERSITY OF TECHNOLOGY   (Iran)

^b MCGILL UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

APPROXIMATION THEORY; CRYSTALLOGRAPHY; ELECTROSTATICS; NEGATIVE IONS; POSITIVE IONS; SOLUTIONS;

IONIC ACTIVITY COEFFICIENTS;

ELECTROLYTES;

ELECTROLYTE;

ANALYTIC METHOD; AQUEOUS SOLUTION; ARTICLE; CALCULATION; CHEMICAL COMPOSITION; CORRELATION COEFFICIENT; CRYSTALLOGRAPHY; HYDRATION; IONIC STRENGTH; MODEL; PHENOMENOLOGY;

EID: 0037454182     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie020790g     Document Type: Article

References (28)

1. Copeman, T. W.; Stein, F. P. An Explicit Non-Equal Diameter MSA Model for Electrolytes. Fluid Phase Equilib. 1986, 30, 237.
2. Corti, H. R. Prediction of Activity Coefficients in Aqueous Electrolyte Mixtures Using the Mean Spherical Approximation. J. Phys. Chem. 1987, 91, 686.
3. Lu, J.-F.; Yu, Y.-X.; Li, Y.-G. Modification and Application of the Mean Spherical Approximation Method. Fluid Phase Equilib. 1993, 85, 81.
4. Simonin, J.-P. Real Ionic Solutions in the Mean Spherical Approximation. 2. Pure Strong Electrolytes up to Very High Concentrations, and Mixtures, in the Primitive Model. J. Phys. Chem. 1997, 101, 4313.
5. Simonin, J.-P.; Bernard, O.; Blum, L. Real Ionic Solutions in the Mean Spherical Approximation. 3. Osmotic and Activity Coefficients for Associating Electrolytes in the Primitive Model. J. Phys. Chem. 1998, 102, 4411.
6. Krienke, H.; Barthel, J. MSA Models of Ion Association in Electrolyte Solutions. Z. Phys. Chem. 1998, 204, 71.
7. n on the Shielding Parameter Λ and the Structure of the Electrolyte Solutions. J. Chem. Phys. 1983, 78, 5270.
8. Simonin, J.-P.; Blum, L.; Turq, P. Real Ionic Solutions in the Mean Spherical Approximation. 1. Simple Salts in the Primitive Model. J. Phys. Chem. 1996, 100, 7704.
9. Taghikhani, V.; Vera, J. H. Correlation of Activity Coefficients in Electrolyte Solutions Using a Kelvin Hard Sphere-Mean Spherical Approximation (K-MSA) Model. Ind. Eng. Chem. Res. 2000, 39, 759.
10. Khoshkbarchi, M. K.; Vera, J. H. A Generalized Mixing Rule for Hard-Sphere Equations of State of Percus-Yevick Type. Fluid Phase Equilib. 1998, 142, 131 and 149, 379.
11. Khoshkbarchi, M. K.; Vera, J. H. A Simplified Hard-Sphere Equation of State Meeting the High- and Low-Density Limits. Fluid Phase Equilib. 1997, 130, 189.
12. Waisman, E.; Lebowitz, J. L. Exact Solution of an Integral Equation for the Structure of a Primitive Model of Electrolytes. J. Phys. Chem. 1970, 52, 4307.
13. Barker, J. A.; Henderson, D. Perturbation Theory and Equation of State for Fluid. II. A Successful Theory of Fluids. J. Chem. Phys. 1967, 47, 4714.
14. Blum, L. Simple Method for the Computation of Thermodynamic Properties of Electrolytes in the Mean Spherical Approximation. J. Phys. Chem. 1988, 92, 2969.
15. Sanchez-Castro, C.; Blum, L. Explicit Approximation for the Unrestricted Mean Spherical Approximation for Ionic Solutions. J. Phys. Chem. 1989, 93, 7478.
16. Sheng, W.; Kalogerakis, N.; Bishnoi, P. R. Explicit Approximation of the Mean Spherical Approximation Model for Electrolyte Solutions. J. Phys. Chem. 1993, 97, 5403.
17. Hinton, J. F.; Amis, E. S. Solvation Numbers of Ions. Chem. Rev. 1971, 71, 627.
18. Samoilov, O Ya. Structure of Aqueous Electrolyte Solutions and the Hydration of Ions; Consultants Bureau Enterprises Inc.: New York, 1965.
19. Chong, S. H.; Hirata, F. Ion Hydration: Thermodynamic and Structural Analysis with an Integral Equation Theory of Liquids. J. Phys. Chem. 1997, 101, 3209.
20. Hamer, W. J.; Wu, Y.-C. Osmotic Coefficients and Mean Activity Coefficients of Uni-univalent Electrolytes in Water at 25 °C. J. Phys. Chem. Ref. Data 1972, 1, 1047.
21. Zemaitis, J. F., Jr.; Clark, D. M.; Rafal, M.; Scrivner, N. C. Handbook of Aqueous Electrolyte Thermodynamics; DIPPER-AIChE Publications: New York, 1986.
22. Robinson, R. A.; Stokes, R. H. Electrolyte Solutions, 2nd ed.; Butterworths: London, 1959.
23. Horvath, A. L. Handbook of Aqueous Electrolyte Solutions, 1st ed.; John Wiley: New York, 1985.
24. Lee, L. L. Molecular Thermodynamics of Non Ideal Fluids; Butterworth Publisher: New York, 1989.
25. Taghikhani, V.; Modarress, H.; Vera, J. H. Measurement and Correlation of the Individual Ionic Activity Coefficients of Aqueous Electrolyte Solutions of KF, NaF and KBr. Can. J. Chem. Eng. 2000, 78, 175.
26. Taghikhani, V.; Modarress, H.; Vera, J. H. Individual Anionic Activity Coefficients in Aqueous Electrolyte Solutions of LiCl and LiBr. Fluid Phase Equilib. 1999, 166, 67.
27. Khoshkbarchi, M. K.; Vera, J. H. Measurement and Correlation of Ion Activity in Aqueous Single Electrolyte Solutions. AIChE J. 1996, 42, 249.
28. Zaytsev, I. D.; Aseyev, G. G. Properties of Aqueous Solutions of Electrolytes, 1st ed.; CRC Press: Boca Raton, FL, 1992.