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Volumn 22, Issue 6, 2003, Pages 1183-1195

Indenyl rhenium alkyne complexes: CO substitution via alkyne-assisted ring slippage and CO-catalyzed phosphine substitution

Author keywords

[No Author keywords available]

Indexed keywords

ALKYNE ASSISTED RING SLIPPAGE; ALKYNE LIGAND; INDENYL RHENIUM ALKYNE COMPLEXES; PHOSPHINE;

EID: 0037451088     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om020884q     Document Type: Article
Times cited : (15)

References (26)
  • 11
    • 0012477451 scopus 로고
    • Cargill, R. W., Ed.; Pergamon Press: Oxford, U.K.
    • The concentration of CO in solution was calculated using the Ostwald coefficient: (a) Solubility Data Series: Carbon Monoxide; Cargill, R. W., Ed.; Pergamon Press: Oxford, U.K. 1990; Vol. 43, p 113.
    • (1990) Solubility Data Series: Carbon Monoxide , vol.43 , pp. 113
  • 14
    • 0012462150 scopus 로고    scopus 로고
    • note
    • As a test for maintenance of the CO concentration in solution, the rates of reaction of 3 at 40 atm CO were run at 1.7 and 4.9 mM concentrations of 3. If the reactions were CO starved, then the effect of CO starvation should have been more pronounced at the higher concentrations of 3 where CO depletion would be accentuated. However, similar rates were observed.
  • 15
    • 0012429808 scopus 로고    scopus 로고
    • note
    • A 30 mL PARR stainless steel pressure vessel equipped with a SiComp probe of a ASI ReactIR infrared spectrometer. SiComp probe is an attenuated total reflectance (ATR) device with silicon as the ATR surface.
  • 16
    • 11644324798 scopus 로고
    • note
    • Chemical shift and the proton resonance pattern are distinctive for the three different modes of coordination. O'Connor, J. M.; Casey, C. P. Chem. Rev. 1987, 87, 307.
    • (1987) Chem. Rev. , vol.87 , pp. 307
    • O'Connor, J.M.1    Casey, C.P.2
  • 20
    • 0012429310 scopus 로고    scopus 로고
    • note
    • Addition of excess CNt-Bu to 3 in an effort to obtain complete conversion led to formation of uncharacterized decomposition products.
  • 21
    • 0012479483 scopus 로고    scopus 로고
    • note
    • 2.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.