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As a test for maintenance of the CO concentration in solution, the rates of reaction of 3 at 40 atm CO were run at 1.7 and 4.9 mM concentrations of 3. If the reactions were CO starved, then the effect of CO starvation should have been more pronounced at the higher concentrations of 3 where CO depletion would be accentuated. However, similar rates were observed.
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15
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0012429808
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note
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A 30 mL PARR stainless steel pressure vessel equipped with a SiComp probe of a ASI ReactIR infrared spectrometer. SiComp probe is an attenuated total reflectance (ATR) device with silicon as the ATR surface.
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16
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11644324798
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Chemical shift and the proton resonance pattern are distinctive for the three different modes of coordination. O'Connor, J. M.; Casey, C. P. Chem. Rev. 1987, 87, 307.
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0012429310
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Addition of excess CNt-Bu to 3 in an effort to obtain complete conversion led to formation of uncharacterized decomposition products.
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21
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0012479483
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2.
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