Luminescent properties of carbon-rich starburst gold(I) acetylide complexes. Crystal structure of [TEE][Au (PCy 3 )] 4 ([TEE]H 4 = tetraethynylethene)

Journal of Organometallic Chemistry

Volumn 670, Issue 1-2, 2003, Pages 11-16

  Lu, Wei ^a   Zhu, Nianyong ^a   Che, Chi Ming ^a  

^a UNIVERSITY OF HONG KONG   (Hong Kong)

Author keywords

Acetylide; Cross conjugation; Fluorescence; Gold; Phosphorescence

Indexed keywords

ACETYLENE DERIVATIVE; ALKYNE DERIVATIVE; CARBON; DICHLOROMETHANE; ETHYLENE; GOLD COMPLEX;

CHEMOLUMINESCENCE; COMPLEX FORMATION; CONTROLLED STUDY; CRYSTAL STRUCTURE; FLUORESCENCE ANALYSIS; LIGHT ABSORPTION; LIQUID; PHOSPHORESCENCE; REVIEW; SOLUTION AND SOLUBILITY; SPECTROSCOPY; SYNTHESIS; ULTRAVIOLET RADIATION;

EID: 0037451013     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(02)02063-6     Document Type: Article

References (34)

1. N.P. Gallagher, J.L. Hendrix, E.B. Milosavljevic, J.H. Nelson, J. Electrochem. Soc. 136 (1989) 2546.
2. H. Schmidbaur (Ed.), Gold: Progress in Chemistry, Biochemistry and Technology, Wiley, Chichester, 1999;
3. J. Manna, K.D. John, M.D. Hopkins, Adv. Organomet. Chem. 38 (1995) 79.
4. T.E. Müller, D.M.P. Mingos, D.J. Williams, J. Chem. Soc. Chem. Commun. (1994) 1787;
5. D.M.P. Mingos, J. Yau, S. Menzer, D.J. Williams, Angew. Chem. Int. Ed. Engl. 34 (1995) 1894;
6. J. Vicente, M.-T. Chicote, M.-D. Abrisqueta, R. Guerrero, P.G. Jones, Angew. Chem. Int. Ed. Engl. 36 (1997) 1203;
7. C.P. McArdle, M.J. Irwin, M.C. Jennings, R.J. Puddephatt, Angew. Chem. Int. Ed. Engl. 38 (1999) 3376;
8. C.P. McArdle, J.J. Vittal, R.J. Puddephatt, Angew. Chem. Int. Ed. Engl. 39 (2000) 3819.
9. Donor-acceptor Au(I) acetylides have been intensely studied by Humphrey and coworkers as NLO materials, for example: I.R. Whittall, M.G. Humphrey, M. Samoc, B. Luther-Davies, Angew. Chem. Int. Ed. Engl. 36 (1997) 370;
10. I.R. Whittall, M.G. Humphrey, M. Samoc, B. Luther-Davies, D.C.R. Hockless, J. Organomet. Chem. 544 (1997) 189.
11. Representative examples: D. Li, C.M. Che, W.C. Lo, S.M. Peng, J. Chem. Soc. Dalton Trans. (1993) 2929;
12. H. Xiao, K.K. Cheung, C.X. Guo, C.M. Che, J. Chem. Soc. Dalton Trans. (1994) 1867;
13. H. Xiao, Y.X. Weng, S.M. Peng, C.M. Che, J. Chem. Soc. Dalton Trans. (1996) 3155;
14. V.W.W. Yam, S.W.K. Choi, J. Chem. Soc. Dalton Trans. (1996) 4227;
15. M.J. Irwin, J.J. Vittal, R.J. Puddephatt, Organometallics 16 (1997) 3541.
16. A. Grohmann, J. Riede, H. Schmidbaur, Nature 345 (1990) 140;
17. H. Schmidbaur, Chem. Soc. Rev. 24 (1995) 391.
18. C.M. Che, H.Y. Chao, V.M. Miskowski, Y. Li, K.K. Cheung, J. Am. Chem. Soc. 123 (2001) 4985;
19. W. Lu, H.F. Xiang, N. Zhu, C.M. Che, Organometallics 21 (2002) 2343.
20. W.F. Fu, K.C. Chan, V.W. Miskowski, C.M. Che, Angew. Chem. Int. Ed. Engl. 38 (1999) 2783;
21. W.F. Fu, K.C. Chan, K.K. Cheung, C.M. Che, Chem. Eur. J. 7 (2001) 7656.
22. H. Schmidbaur, O. Steigelmann, Z. Naturforsch. Teil B 47 (1992) 1721.
23. N.F. Phelan, M. Orchin, J. Chem. Educ. 45 (1968) 633.
24. H.Y. Chao, W. Lu, Y. Li, M.C.W. Chan, C.M. Che, K.K. Cheung, N. Zhu, J. Am. Chem. Soc., in press.
25. I.R. Whittall, M.G. Humphrey, S. Houbrechts, J. Maes, A. Persoons, S. Schmid, D.C.R. Hockless, J. Organomet. Chem. 544 (1997) 277;
26. M.J. Irwin, L. Manojlovic-Muir, K.W. Muir, R.J. Puddephatt, D.S. Yufit, Chem. Commun. (1997) 219.
27. S. Leininger, P.J. Stang, S. Huang, Organometallics 17 (1998) 3981;
28. K. Onitsuka, M. Fujimoto, N. Ohshiro, S. Takahashi, Angew. Chem. Int. Ed. Engl. 38 (1999) 689;
29. V.W.W. Yam, L. Zhang, C.H. Tao, K.M.C. Wong, K.K. Cheung, J. Chem. Soc. Dalton Trans. (2001) 1111.
30. Y. Rubin, C.B. Knobler, F. Diederich, Angew. Chem. Int. Ed. Engl. 30 (1990) 698;
31. J. Anthony, A.M. Boldi, Y. Rubin, M. Hobi, V. Gramlich, C.B. Knobler, P. Seiler, F. Diederich, Helv. Chim. Acta 78 (1995) 13.
32. F. Diederich, R. Faust, V. Gramlich, P. Seiler, J. Chem. Soc. Chem. Commun. (1994) 2045;
33. R. Faust, F. Diederich, V. Gramlich, P. Seiler, Chem. Eur. J. 1 (1995) 111.
34. Y. Zhao, R.R. Tykwinski, J. Am. Chem. Soc. 121 (1999) 458.