The intrinsic 3[dσ*pσ] emission of binuclear gold(I) complexes with two bridging diphosphane ligands lies in the near UV; emissions in the visible region are due to exciplexes

Angewandte Chemie - International Edition

Volumn 38, Issue 18, 1999, Pages 2783-2785

  Fu, Wen Fu ^a   Chan, Kwok Chu ^a   Miskowski, Vincent M ^a   Che, Chi Ming ^a  

^a UNIVERSITY OF HONG KONG   (Hong Kong)

Author keywords

Binuclear complexes; Exciplexes; Gold; Luminescence; UV Vis spectroscopy

Indexed keywords

GOLD COMPLEX; LIGAND; PHOSPHANE COMPLEX; PHOSPHONIC ACID DERIVATIVE; SOLVENT; UNCLASSIFIED DRUG;

ARTICLE; COMPLEX FORMATION; CRYSTAL STRUCTURE; LUMINESCENCE; TEMPERATURE; ULTRAVIOLET SPECTROSCOPY; X RAY CRYSTALLOGRAPHY;

EID: 0033578796     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19990917)38:18<2783::AID-ANIE2783>3.0.CO;2-I     Document Type: Article

References (43)

1. a) C. King, J. C. Wang, M. N. I. Khan, J. P. Fackler, Jr., Inorg. Chem. 1989, 28, 2145-2149;
2. b) M. N. I. Khan, C. King, D. D. Heinrich, J. P. Fackler, Jr., L. C. Porter, Inorg. Chem. 1989, 28, 2150-2154.
3. a) C. M. Che, H. L. Kwong, V. W. W. Yam, K. C. Cho, J. Chem. Soc. Chem. Commun. 1989, 885-886;
4. b) D. Li, C. M. Che, H. L. Kwong, V. W. W. Yam, J. Chem. Soc. Dalton Trans. 1992, 3325-3329.
5. L. H. Gade, Angew. Chem. 1997, 109, 1219-1221; Angew. Chem. Int. Ed. Engl. 1997, 36, 1171-1173.
6. L. H. Gade, Angew. Chem. 1997, 109, 1219-1221; Angew. Chem. Int. Ed. Engl. 1997, 36, 1171-1173.
7. a) S. J. Shieh, X. Hong, S. M. Peng, C. M. Che, J. Chem. Soc. Dalton Trans. 1994, 3067-3068;
8. b) B. C. Tzeng, C. M. Che, S. M. Peng, J. Chem. Soc. Dalton Trans. 1996, 1769-1770;
9. c) B. C. Tzeng, W. C. Lo, C. M. Che, S. M. Peng, Chem. Commun. 1996, 181-182;
10. d) H. Xiao, K. K. Cheung, C. M. Che, J. Chem. Soc. Dalton Trans. 1996, 3699-3703;
11. e) H. Xiao, Y. X. Weng, W. T. Wong, T. C. W. Mak, C. M. Che, J. Chem. Soc. Dalton Trans. 1997, 221-226;
12. f) B. C. Tzeng, C. K. Chan, K. K. Cheung, C. M. Che, S. M. Peng, Chem. Commun. 1997, 135-136;
13. g) B. C. Tzeng, C. M. Che, S. M. Peng, Chem. Commun. 1997, 1171-1172.
14. a) J. C. Vickery, M. M. Olmstead, E. Y. Fung, A. L. Balch, Angew. Chem. 1997, 109, 1227-1229; Angew. Chem. Int. Ed. Engl. 1997, 36, 1179-1181;
15. a) J. C. Vickery, M. M. Olmstead, E. Y. Fung, A. L. Balch, Angew. Chem. 1997, 109, 1227-1229; Angew. Chem. Int. Ed. Engl. 1997, 36, 1179-1181;
16. b) R. J. Lachicotte, M. A. Mansour, W. B. Connick, H. J. Gysling, R. Eisenberg, J. Am. Chem. Soc. 1998, 120, 1329-1330.
17. a) C. King, M. N. I. Khan, R. J. Staples, J. P. Fackler, Jr., Inorg. Chem. 1992, 31, 3236-3238;
18. b) Z. Assefa, B. G. McBurnett, R. J. Staples, J. P. Fackler, Jr., Inorg. Chem. 1995, 34, 4965-4972.
19. a) N. Nagasundaram, G. Roper, J. Biscoe, J. W. Chai, H. H. Patterson, N. Blom, A. Ludi, Inorg. Chem. 1986, 25, 2947-2951;
20. b) Z. Assefa, F. DeStefano, M. A. Garepapaghi, J. H. LaCasce, Jr., S. Ouellete, M. R. Corson, J. K. Nagle, H. H. Patterson, Inorg. Chem. 1991, 30, 2868-2876.
21. a) V. W. W. Yam, T. F. Lai, C. M. Che, J. Chem. Soc. Dalton Trans. 1990, 3747-3752;
22. b) V. W. W. Yam, S. W. K. Choi, J. Chem. Soc. Dalton Trans. 1996, 4227-4232;
23. c) V. W. W. Yam, C. K. Li, C. L. Chan, Angew. Chem. 1998, 110, 3041-3044; Angew. Chem. Int. 1998, 37, 2857-2859.
24. c) V. W. W. Yam, C. K. Li, C. L. Chan, Angew. Chem. 1998, 110, 3041-3044; Angew. Chem. Int. 1998, 37, 2857-2859.
25. a) S. D. Hanna, J. I. Zink, Inorg. Chem. 1996, 35, 297-302;
26. b) S. D. Hanna, S. I. Khan, J. I. Zink, Inorg. Chem. 1996, 35, 5813-5819.
27. a) A. Vogler, H. Kunkely, Chem. Phys. Lett. 1988, 150, 135-137;
28. b) H. K. Yip, A. Schier, J. Riede, H. Schmidbaur, J. Chem. Soc. Dalton Trans. 1994, 2333-2334.
29. D. F. Feng, S. S. Tang, C. W. Liu, I. J. B. Lin, Y. S. Wen, L. K. Liu, Organometallics 1997, 16, 901-909.
30. a) V. M. Miskowski, S. F. Rice, H. B. Gray, S. J. Milder, J. Phys. Chem. 1993, 97, 4277-4283;
31. b) S. F. Rice, H. B. Gray, Inorg. Chem. 1988, 27, 4704-4708;
32. c) S. F. Rice, H. B. Gray, J. Am. Chem. Soc. 1983, 105, 4571-4575;
33. d) D. M. Roundhill, H. B. Gray, C. M. Che, Acc. Chem. Res. 1989, 22, 55-61;
34. e) A. E. Stiegman, S. F. Rice, H. B. Gray, V. M. Miskowski, Inorg. Chem. 1987, 26, 1112-1116.
35. H. X. Zhang, C. M. Che, Chem. Eur. J., in press.
36. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-116329-116331. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: (+44)1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
37. H. R. C. Jaw, M. M. Savas, R. D. Rogers, W. R. Mason, Inorg. Chem. 1989, 28, 1028-1037.
38. a) P. Pyykkö, Y. Zhao, Angew. Chem. 1991, 103, 622-623; Angew. Chem. Int. Ed. Engl. 1991, 30, 604-605;
39. a) P. Pyykkö, Y. Zhao, Angew. Chem. 1991, 103, 622-623; Angew. Chem. Int. Ed. Engl. 1991, 30, 604-605;
40. b) J. Kozelka, H. R. Oswald, E. Dubler, Acta Crystallogr. Sect. C 1986, 42, 1007-1009;
41. c) D. Perrault, M. Drouin, A. Michel, V. M. Miskowski, W. P. Schaefer, P. D. Harvey, Inorg. Chem. 1992, 31, 695-702.
42. K. H. Leung, D. L. Phillips, M. C. Tse, C. M. Che, V. M. Miskowski, J. Am. Chem. Soc. 1999, 121, 4799-4803.
43. T. M. McCleskey, H. B. Gray, Inorg. Chem. 1992, 31, 1733-1734.