Graphoepitaxy control of the deposition of cationic polymer micelles on SiO2 surfaces

Langmuir

Volumn 19, Issue 8, 2003, Pages 3098-3102

  Hahn, Jungseok ^a   Webber, S E ^a  

^a UNIVERSITY OF TEXAS AT AUSTIN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

GRAPHOEPITAXY CONTROL;

ADSORPTION; BLOCK COPOLYMERS; DEPOSITION; EPITAXIAL GROWTH; POLYSTYRENES; SILICA; SURFACE TREATMENT;

MICELLES;

EID: 0037447001     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la0268911     Document Type: Article

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20. 2)), where q is the scattering vector.
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22. Typical average values obtained under higher magnification are 36-40 nm with a standard deviation of ±3 nm.
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24. (a) Gerstenberg, M. C.; Pedersen, J. S. Phys. Rev. E 1998, 58, 8028-8031. In this case, the observed ordering is at a solid-liquid interface. (b,c) Zhu, J.; Eisenberg, A.; Lennox, R. B. Macromolecules 1992, 25, (b) 6547-6565, (c) 6556-6562. In this case, the diblock polymer was dissolved in a solvent that is not miscible with water and spread on the water-air interface. After the solvent evaporates, surface micelles are formed and TEM images of these "surface micelles" look qualitatively like our images. However, in this technique no polymer micelles are present in the bulk solution, so the physical system is a little different than ours.
25. (a) Gerstenberg, M. C.; Pedersen, J. S. Phys. Rev. E 1998, 58, 8028-8031. In this case, the observed ordering is at a solid-liquid interface. (b,c) Zhu, J.; Eisenberg, A.; Lennox, R. B. Macromolecules 1992, 25, (b) 6547-6565, (c) 6556-6562. In this case, the diblock polymer was dissolved in a solvent that is not miscible with water and spread on the water-air interface. After the solvent evaporates, surface micelles are formed and TEM images of these "surface micelles" look qualitatively like our images. However, in this technique no polymer micelles are present in the bulk solution, so the physical system is a little different than ours.
26. (a) Gerstenberg, M. C.; Pedersen, J. S. Phys. Rev. E 1998, 58, 8028-8031. In this case, the observed ordering is at a solid-liquid interface. (b,c) Zhu, J.; Eisenberg, A.; Lennox, R. B. Macromolecules 1992, 25, (b) 6547-6565, (c) 6556-6562. In this case, the diblock polymer was dissolved in a solvent that is not miscible with water and spread on the water-air interface. After the solvent evaporates, surface micelles are formed and TEM images of these "surface micelles" look qualitatively like our images. However, in this technique no polymer micelles are present in the bulk solution, so the physical system is a little different than ours.