The determination of phase relations in the CH4-H2O-NaCl system at 1 kbar, 400 to 600°C using synthetic fluid inclusions

Geochimica et Cosmochimica Acta

Volumn 60, Issue 11, 1996, Pages 1885-1897

  Lamb, William M ^a   Popp, Robert K ^a   Boockoff, Leslie A ^a,b  

^a TEXAS A AND M UNIVERSITY   (United States)

^b ARIZONA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EXPERIMENTAL MINERALOGY; FLUID INCLUSION; METHANE; PHASE RELATIONS; SODIUM CHLORIDE; WATER;

EID: 0030442272     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/0016-7037(96)00070-1     Document Type: Article

References (49)

1. Bodnar R. J. and Sterner S. M. (1985) Synthetic fluid inclusions in natural quartz: II. Application to PVT studies. Geochim. Cosmochim. Acta 49, 1855-1859.
2. 2O-NaCl to 1000°C and 1500 bars. Geochim. Cosmochim. Acta 49, 1861-1873.
3. 2-NaCl fluids at high pressures and temperatures. Geochim. Cosmochim. Acta 47, 1247-1275.
4. 2 ± NaCl: New graphical presentations and implications for fluid inclusion studies. Geochim. Cosmochim. Acta 53, 1209-1221.
5. Burnham C. W. (1979) Magmas and Hydrothermal fluids. In Geochemistry of Hydrothermal Ore Deposits, 2nd ed. (ed. H. L. Barnes), pp. 71-136. Wiley.
6. Carmichael I. S. E. and Eugster H. P. (1987) Thermodynamic modeling of geological materials: Minerals, fluids, and melts. Rev. Mineral. 17.
7. 2O system: II. Mixtures from 50 to 1000°C and 0 to 1000 bar. Geochim. Cosmochim. Acta 56, 2619-2631.
8. 2 system: Prediction of phase equilibria and volumetric properties. Geochim. Cosmochim. Acta 59, 2869-2882.
9. Drummond S. E. and Ohmoto H. (1985) Chemical evolution and mineral deposition in boiling hydrothermal systems. Econ. Geol. 80, 126-147.
10. Ernst W. G. (1968) Amphiboles. Springer-Verlag.
11. Etheridge M. A., Wall V. J., and Vernon R. H. (1983) The role of the fluid phase during regional metamorphism and deformation. J. Metam. Geol. 1, 205-226.
12. Ferry J. M. (1980) A case study of the amount and distribution of heat and fluid during metamorphism. Contrib. Mineral. Petrol. 71, 373-385.
13. Ferry J. M. (1982) Characterization of Metamorphism through Mineral Equilibria. Rev. Mineral. 10.
14. Frantz J. D., Zhang Y., Hickmott D. D., and Hoering T. C. (1989) Hydrothermal reactions involving equilibrium between minerals and mixed volatiles: 1. Techniques for experimentally loading and analyzing gases and their application to synthetic fluid inclusions. Chem. Geol. 76, 57-70.
15. 2 as determined using synthetic fluid inclusions in conjunction with mass spectrometry. Chem. Geol. 98, 237-255.
16. French B. M. (1966) Some geological implications of equilibrium between graphite and a C-O-H gas phase at high temperatures and pressures. Rev. Geophys. 4, 223-253.
17. Hanor J. S. (1979) The sedimentary genesis of hydrothermal fluids. In Geochemistry of Hydrothermal Ore Deposits, 2nd ed. (ed. H. L. Barnes), pp. 137-172. Wiley.
18. Heinrich W. (1993) Fluid infiltration through metachert layers at the contact aureole of the Bufa del Diente intrusion, northeast Mexico: Implications for wollastonite formation and fluid immiscibility. Amer. Mineral. 78, 804-818.
19. Henley R. W. and McNabb A. (1978) Magmatic vapor plumes and groundwater interaction in the porphyry copper environment. Econ. Geol. 73, 1-20.
20. Herms P. and Schenk V. (1992) Fluid inclusions in granulite-facies metapelites of the Hercynian ancient lower crust of the Serre, Calabria, Southern Italy. Contrib. Mineral. Petrol. 112, 393-404.
21. Holloway J. R. (1981) Compositions and volumes of supercritical fluids. In The Earth's Crust (ed. L. S. Hollister and M. L. Crawford); Mineral Assoc. Canada Short Course Handbook 6, pp. 13-38.
22. 4. Geochim. Cosmochim. Acta 45, 607-614.
23. Kelley D. S. (1996) Methane-bearing fluids in the oceanic crust: Gabbro-hosted fluid inclusions from the southwest Indian Ridge. J. Geophys. Res. 101 (in press).
24. 2 mixtures at elevated pressures and temperatures. Amer. J. Sci. 81, 735-767.
25. 4-rich inclusions from quartz veins in the Valley-and Ridge province and the anthracite fields of the Pennsylvania Appalachains. Amer. Mineral. 76, 320-240.
26. 4-NaCl bis 250 MPa und 800 K. Ph.D. dissert., Univ. Karlsruhe.
27. 2 fluids during formation of the Dome de l'Agout, France. Geochim. Cosmochim. Acta 46, 193-203.
28. Larsen R. B., Brooks C. K., and Bird D. K. (1992) Methane-bearing, aqueous, saline solutions in the Skaergaard intrusion, east Greenland. Contrib. Mineral. Petrol. 112, 428-437.
29. Lamb W. M. (1987) Metamorphic fluids and granulite genesis. Ph.D. diss., Univ. Wisc.
30. 2 vapour free environment. Nature 312, 56-58.
31. 2-rich fluid inclusions in granulites. Contrib. Mineral. Petrol. 96, 485-495.
32. Linke W. F. (1958) Solubilities of Organic and Metal-Organic Compounds, 1, 4th ed. Van Norstrand.
33. Linke W. F. (1965) Solubilities of Organic and Metal-Organic Compounds, 2, 4th ed. Amer. Chem. Soc.
34. Mullis J., Dubessy J., Poty B., and O'Neil, J. (1994) Fluid regimes during late stages of a continental collision: Physical, chemical, and stable isotope measurements of fluid inclusions in fissure quartz from a geotraverse through the Central Alps, Switzerland. Geochim. Cosmochim. Acta 58, 2239-2267.
35. Ohmoto H. and Kerrick D. M. (1977) Devolatilization equilibria in graphitic systems. Amer. J. Sci. 277, 1013-1044.
36. Popp R. K., Nagy K. L., and Hajsh A. (1984) Semiquantitative control of hydrogen fugacity in rapid-quench hydrothermal vessels. Amer. Mineral. 69, 557-562.
37. Roedder E. (1979) Fluid inclusions as samples of ore fluids. In Geochemistry of Hydrothermal Ore Deposits (ed. H. Barnes), pp. 684-737. Holt, Rinehart, and Winston.
38. Roedder E. (1984) Fluid inclusions. Rev. Mineral. 12.
39. Ryzhenko B. N. and Volkov V. P. (1971) Fugacity coefficients of some gases in a broad range of temperatures and pressures. Geochim. Intl. 8, 468-481.
40. Shelton K. L. and Orville P. M. (1980) Formation of synthetic fluid inclusions in natural quartz. Amer. Mineral. 65, 1233-1236.
41. 2 or NaCl at high P and T. Geochem. Intl. 30, 53-71.
42. 2O system to 6 kb and 700°C. Amer. J. Sci. 291, 1-54.
43. 2O under vapor saturated conditions. Geochim. Cosmochim. Acta 52, 989-1006.
44. Touret J. L. R. (1987) Fluid inclusions and pressure-temperature estimates in deep-seated rocks. In Chemical Transport in Metasomatic Processes (ed. H. C. Helgeson), 91-121. Reidel.
45. Van Den Kerkhof A. M., Touret J. L. R., Maijer C., and Jansen, J.B. H. (1991) Retrograde methane-dominated fluid inclusions from high-temperature granulites of Rogaland, southwestern Norway. Geochim. Cosmochim. Acta 55, 2533-2544.
46. Welsch H. (1973) Die Systeme Xenon-Wasser und Methan-Wasser bei hohen Drucken und Temperaturen. Ph.D. thesis, Institute for Physical Chemistry, Karlsruhe.
47. Yardley B. W. D., Shepard T. J., and Barber J. P. (1983) Fluid inclusion studies of high-grade rocks from Connemara, Ireland. In Migmatites, Melting and Metamorphism (ed. M. P. Therton and C. D. Gribble), pp. 110-126. Shiva.
48. 2O) using synthetic fluid inclusions. Chem. Geol. 64, 335-350.
49. 2O system using synthetic fluid inclusions. Chem. Geol. 100, 51-72.