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0012460273
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note
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w = 89 300 g/mol.
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13
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0012389010
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note
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For the synthesis of the poly(acrylamide) ionomers with 30% of ionic amines, 1.00 g (5.93 mmol repeating units) of poly(N- acryloyloxysuccinimide) was dissolved in 72 mL of DMF and heated to 70°C. After that, 1.12 g (4.15 mmol) of octadecylamine was added. The mixture was stirred for 5 h at 70°C and then cooled to 55°C. After that, a solution of 1.17 g (4.46 mmol) of 4-aminobutyltriethylphosphoniumchloride hydrochloride in 24 mL of methanol and 8 mL of triethylamine was added. The mixture was stirred for another 16 h at 55°C. The solvent was evaporated, and the resulting residue was washed three times with 50 mL of methanol. 4-Aminobutyltriethylphosphonium-chloride hydrochloride was synthesized by reaction of N-(4-bromobutyl)phthalimide with triethyl phosphine in toluene for 48 h under reflux. The resulting phosphonium salt was refluxed for 7 days with concentrated hydrochloric acid.
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17
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0030848621
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0034608845
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Stoddart, J.F.7
Zaccheroni, N.8
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