Synthesis of water-soluble polymethacrylates by living anionic polymerization of trialkylsilyl-protected oligo(ethylene glycol) methacrylates

Macromolecules

Volumn 36, Issue 1, 2003, Pages 42-49

  Ishizone, Takashi ^a   Han, Seok ^a   Okuyama, Syunsuke ^a   Nakahama, Seiichi ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

MOLECULAR DESIGN;

ANIONIC POLYMERIZATION; HYDROPHILICITY; MOLECULAR WEIGHT; MONOMERS; OLIGOMERS; SYNTHESIS (CHEMICAL);

BLOCK COPOLYMERS;

EID: 0037435672     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma021257f     Document Type: Article

References (37)

1. (a) Morton, M. Anionic Polymerization: Principles and Practice; Academic Press: New York, 1983.
2. (b) Hsieh, H. L.; Quirk, R. P. Anionic Polymerization; Marcel Dekker: New York, 1996.
3. (a) Nakahama, S.; Hirao, A. Prog. Polym. Sci. 1999, 15, 299.
4. (b) Hirao, A.; Nakahama, S. Trends Polym. Sci. 1994, 2, 267.
5. (c) Hirao, A.; Loykulnant, S.; Ishizone, T. Prog. Polym. Sci. 2002, 27, 1399.
6. Hirao, A.; Kato, H.; Yamaguchi, K.; Nakahama, S. Macromolecules 1986, 19, 1294.
7. Mori, H.; Wakisaka, O.; Hirao, A.; Nakahama, S. Macromol. Chem. Phys. 1994, 195, 3213.
8. (a) Nojiri, C.; Okano, T.; Grainger, D.; Park, K. D.; Nakahama, S.; Suzuki, K.; Kim, S. W. Trans. ASAIO 1987, 33, 596.
9. (b) Nojiri, C.; Okano, T.; Koyanagi, H.; Nakahama, S.; Park, K. D.; Kim, S. W. J. Biomater. Sci., Polym. Ed. 1992, 4, 75.
10. (a) Senshu, K.; Yamashita, S.; Ito, M.; Hirao, A.; Nakahama, S. Langmuir 1995, 11, 2293.
11. (b) Senshu, K.; Yamashita, S.; Mori, H.; Ito, M.; Hirao, A.; Nakahama, S. Langmuir 1999, 15, 1754.
12. (c) Senshu, K.; Kobayashi, M.; Ikawa, N.; Yamashita, S.; Hirao, A.; Nakahama, S. Langmuir 1999, 15, 1763.
13. Mori, H.; Hirao, A.; Nakahama, S. Macromolecules 1994, 27, 35.
14. Zhang, H.; Ruckenstein, E. Macromolecules 2000, 33, 4738.
15. Mori, H.; Hirao, A.; Nakahama, S.; Senshu, K. Macromolecules 1994, 27, 4093.
16. Karlsson, J. O.; Gatenholm, P. Polymer 1996, 37, 4251.
17. Ore, S.; Kulvik, E.; Ohr, W.; Zapffe, J. W. Makromol. Chem. 1971, 148, 211.
18. Green, T. W.; Wuts, P. G. M. Protective Groups in Organic Synthesis, 2nd ed.; Wiley-Interscience: New York, 1991.
19. (a) Fayt, R.; Forte, R.; Jacobs, C.; Jérôme, R.; Ouhadi, T.; Teyssié, Ph.; Varshney, S. K. Macromolecules 1987, 20, 1442.
20. (b) Varshney, S. K.; Hautekeer, J. P.; Fayt, R.; Jérôme, R.; Teyssié, Ph. Macromolecules 1990, 23, 2618.
21. Ozaki, H.; Hirao, A.; Nakahama, S. Macromol. Chem. Phys. 1995, 196, 2099.
22. (a) Ishizone, T.; Yoshimura, K.; Hirao, A.; Nakahama, S. Macromolecules 1998, 31, 8706.
23. (b) Kobayashi, M.; Okuyama, S.; Ishizone, T.; Nakahama, S. Macromolecules 1999, 32, 6466.
24. (a) Kunkel, D.; Müller, A. H. E.; Janata, M.; Lochmann, L. Makromol. Chem., Macromol. Symp. 1992, 60, 315.
25. (b) Yakimansky, A. V.; Müller, A. H. E.; Van Beylen, M. Macromolecules 2000, 33, 5686.
26. (a) Ozaki, H.; Hirao, A.; Nakahama, S. Macromolecules 1992, 25, 1391.
27. (b) Hild, G.; Lamps, J. P.; Rempp, P. Polymer 1993, 34, 2875.
28. (c) Creutz, S.; Teyssié, Ph.; Jérôme, R. Macromolecules 1997, 30, 6.
29. (d) Ishizone, T.; Uehara, G.; Hirao, A.; Nakahama, S.; Tsuda, K. Macromol. Chem. Phys. 1998, 199, 1827.
30. (e) Zhang, H.; Ruckenstein, E. Macromolecules 1998, 31, 746.
31. (f) Ishizone, T.; Sugiyama, K.; Sakano, Y.; Mori, H.; Hirao, A.; Nakahama, S. Polym. J. 1999, 31, 983.
32. (g) Zhang, H.; Ruckenstein, E. Macromolecules 2001, 34, 3587.
33. (h) Ishizone, T.; Tajima, H.; Torimae, H.; Nakahama, S. Macromol. Chem. Phys., in press.
34. Anderson, B. C.; Andrews, G. D.; Arthur, Jr., P.; Jacobson, H. W.; Melby, L. R.; Playtis, A. J.; Sharkey, W. H. Macromolecules 1981, 14, 1599.
35. n value was observed (Table 1, run 7). This is probably due to the trace amount of impurity in the monomer, resulting in the partial loss of initiator at the initial stage of polymerization.
36. Varshney, S. K.; Jacobs, C.; Hautekeer, J. P.; Bayard, P.; Jérôme, R.; Fayt, R.; Teyssié, Ph. Macromolecules 1991, 24, 4997.
37. Hirao, A.; Takenaka, K.; Packrisamy, S.; Yamaguchi, K.; Nakahama, S. Makromol. Chem. 1985, 186, 1157.