Stereospecific anionic polymerization of N,N-dialkylacrylamides

Macromolecules

Volumn 32, Issue 20, 1999, Pages 6466-6477

  Kobayashi, Motoyasu ^a   Okuyama, Shunsuke ^a   Ishizone, Takashi ^a   Nakahama, Seiichi ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITIVES; ANIONIC POLYMERIZATION; COMPOSITION EFFECTS; ETHERS; MOLECULAR WEIGHT DISTRIBUTION;

POLYDIALKYLACRYLAMIDE; STEREOSPECIFICITY; TETRAHYDROFURAN;

POLYAMIDES;

EID: 0032595954     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma990812j     Document Type: Article

References (43)

1. Butler, K.; Thomas, P. R.; Tyler, G. J. J. Polym. Sci. 1960, 48, 357-366.
2. (a) Gia, H.; McGrath, J. E. Polym. Prepr. 1980, 21 (1), 74-76.
3. (b) Gia, H.; McGrath, J. E. Polym. Bull. 1980, 2, 837-840.
4. (c) Mohajer, Y.; Wilkers, G. L.; McGrath, J. E. J. Appl. Polym. Sci. 1981, 26, 2827-2839.
5. (d) Huang, S. S.; McGrath, J. E. Polym. Prepr. 1983, 24 (2), 138-140.
6. Sogah, D. Y.; Hertler, W. R.; Webster, O. W.; Cohen, G. M. Macromolecules 1987, 20, 1473-1488.
7. Hertler, W. R.; Sogah, D. Y.; Farnham, W. B.; RajanBabu, T. V. J. Am. Chem. Soc. 1983, 105, 5706-6708.
8. (a) Eggert, M.; Freitag, R. J. Polym. Sci., Part A: Polym. Chem. 1994, 32, 803-813.
9. (b) Freitag, R.; Baltes, T.; Eggert, M. J. Polym. Sci., Part A: Polym. Chem. 1994, 32, 3019-3030.
10. (a) Xie, X.; Hogen-Esch, T. E. Polym. Prepr. 1992, 33 (1), 241-242.
11. (b) Xie, X.; Hogen-Esch, T. E. Polym. Prepr. 1993, 34 (1), 118-119.
12. (c) Xie, X.; Hogen-Esch, T. E. Macromolecules 1998, 29, 1746-1752.
13. (a) Varshney, S. K.; Hautekeer, J. P.; Fayt, R.; Jérôme, R.; Teyssié, Ph. Macromolecules 1990, 23, 2618-2622.
14. (b) Fayt, R.; Forte, R.; Jacobs, C.; Jérôme, R.; Ouhadi, T.; Teyssié, Ph.; Varshney, S. K. Macromolecules 1987, 20, 1442-1444.
15. (a) Wang, J. S.; Jérôme, R.; Teyssié, Ph. Macromolecules 1994, 27, 4896-4901.
16. (b) Nugay, N.; Nugay, T.; Jérôme, R.; Teyssié, Ph. J. Polym. Sci., Polym. Chem. 1997, 35, 361-369.
17. Vlcek, P.; Lochmann, L.; Otoupalova, J. Makromol. Chem., Rapid Commun. 1992, 13, 163-167.
18. Kitayama, T.; Shinozaki, T.; Sakamoto, T.; Yamamoto, M.; Hatada, K. Makromol. Chem., Suppl. 1989, 15, 167-185.
19. (a) Kitayama, T.; Zhang, Y.; Hatada, K. Polym. Bull. 1994, 32, 439-446.
20. (b) Kitayama, T.; Zhang, Y.; Hatada, K. Polym. J. 1994, 26, 868-872.
21. (c) Kitayama, T.; Hirano, T.; Hatada, K. Polym. J. 1996, 28, 61-67.
22. (d) Kitayama, T.; Hirano, T.; Zhang, Y.; Hatada, K. Macromol. Symp. 1996, 107, 297.
23. (e) Hirano, T.; Yamaguchi, H.; Kitayama, T.; Hatada, K. Polym. J. 1998, 30, 767-769.
24. L'Abbe, G.; Smets, G. J. Polym. Sci., Part A-1 1967, 5, 1359-1381.
25. Hsieh, H. L. J. Polym. Sci., Polym. Chem. 1976, 14, 379-386.
26. Tsvetanov, C. H.; Petrova, D. T.; Li, P. H.; Panayotov, I. M. Eur. Polym. J. 1978, 14, 25-28.
27. Ozaki, H.; Hirao, A.; Nakahama, S. Macromol. Chem. Phys. 1995, 196, 2099-2111.
28. Ishizone, T.; Yoshimura, K.; Hirao, A.; Nakahama, S. Macromolecules 1998, 31, 8706-8712.
29. Nakahama, S.; Kobayashi, M.; Ishizone, T.; Hirao, A.; Kobayashi, M. J. Macromol. Sci. Pure Appl. Chem. 1997, A34, 1845-1855.
30. Ishizone, T.; Hirao, A.; Nakahama, S. Macromolecules 1991, 24, 625-626.
31. Hirao, A.; Takenaka, K.; Packirisamy, S.; Yamaguchi, K.; Nakahama, S. Makromol. Chem. 1985, 186, 1157-1166.
32. (a) Tsuruta, T.; Fujio, R.; Furukawa, J. Makromol. Chem. 1964, 80, 172-184.
33. (b) Fujio, R.; Tsuruta, T.; Furukawa, J. J. Chem. Soc. Jpn., Ind. Chem. Sect. (Kogyo Kagaku Zasshi) 1963, 66, 365-369.
34. - was not detected, although the spectrum was not shown in this article.
35. 6c in water. However, the poly(DMA)s obtained in our experiment were soluble in water regardless of the tacticity.
36. Sakaguchi, Y.; Hamada, T.; Tamao, K.; Nishino, J. Kobunshi Kagaku 1972, 29(328), 562-566.
37. (a) Hatada, K.; Ute, K.; Tanaka, K.; Imanari, M.; Fujii, N. Polym. J. 1987, 19, 425-436.
38. (b) Hatada, K.; Ute, K.; Tanaka, K.; Kitayama, T. Polym. J. 1987, 19, 1325-1328.
39. 3 at 50°C, tacticity could not be determined from those signals in this study.
40. 3.
41. (a) Ito, S. Kobunshi Ronbunshu 1989, 46, 437-443.
42. (b) Bae, Y. H.; Okano, T.; Kim, S. W. J. Polym. Sci., Part B: Polym. Phys. 1990, 28, 923-936.
43. The carbonyl carbon of EMA monomer also exhibits two signals (see Experimental Section), probably due to the restricted rotation around the amide bond.