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For examples of thiyl radical induced cyclisation reactions, see: (e) Ogawa, A.; Tanaka, H.; Yokoyama, H.; Obayashi, R.; Yokoyama, K.; Sonoda, N. J. Org. Chem. 1992, 57, 111-115;
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For examples of thiyl radical induced cyclisation reactions, see: (i) Oswald, A. A.; Griesbaum K. In The Chemistry of Organic Sulfur Compound; Kharasch, N.; Meyers, C. Y., Eds. Pergamon: Oxford, 1966; Vol. 2, Chapter 9, pp. 233-256.
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0012121711
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note
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AIBN was added hourly from the commencement of each reaction in nine equal portions.
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35
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0012197293
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note
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Solution phase analogues of all the solid supported radical reactions outlined in this paper were conducted using the appropriate dimethyl diallylmalonate derivative. The products derived from both the solid and solution phase experiments gave near identical stereochemical outcomes.
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