Conditions for facile, controlled RAFT polymerization of acrylamide in water

Macromolecules

Volumn 36, Issue 5, 2003, Pages 1436-1439

  Thomas, David B ^a   Sumerlin, Brent S ^a   Lowe, Andrew B ^b   McCormick, Charles L ^a,b  

^a Virginia Polytechnic Institute and State University   (United States)

^b The University of Southern Mississippi   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BLOCK COPOLYMERS; HYDROLYSIS; MOLECULAR WEIGHT; PH EFFECTS; SYNTHESIS (CHEMICAL);

CHAIN TRANSFER AGENTS (CTA);

POLYMERIZATION;

EID: 0037432359     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma025960f     Document Type: Article

References (33)

1. Darling, T.; David, T.; Fryd, M.; Gridnev, A.; Haddleton, D.; Ittel, S.; Matheson, R.; Moad, G.; Rizzardo, E. J. Polym. Sci., Polym. Chem. 2000, 38, 1706.
2. Kato, M.; Kamigaito, M.; Sawamoto, M.; Higashimuro, T. Macromolecules 1995, 28, 1721.
3. Wang, J. S.; Matyjaszewski, K. J. Am. Chem. Soc. 1995, 117, 5614.
4. Soloman, D. H.; Rizzardo, E. US Patent 4,581,429, 1986.
5. Georges, M. K.; Veregin, R. P. N.; Kazmaier, K. M.; Hamer, G. K. Macromolecules 1993, 26, 2987.
6. Chiefari, J.; Chong, Y. K.; Ercole, F.; Krstina, J.; Jeffrey, J.; Le, T. P. T.; Mayadunne, R. T. A.; Meijs, G. F.; Moad, C. L.; Moad, G.; Rizzardo, E.; Thang, S. H. Macromolecules 1998, 31, 5559.
7. Quinn, J. F.; Rizzardo, E.; Davis, T. P. Chem. Commun. 2001, 1044.
8. Goto, A.; Sato, K.; Tsujii, Y.; Fukuda, T.; Moad, G.; Rizzardo, E.; Thang, S. H. Macromolecules 2001, 34, 402.
9. Mitsukami, Y.; Donavan, M. S.; Lowe, A. B.; McCormick, C. L. Macromolecules 2001, 34, 2248.
10. Shalaby, S. W.; McCormick, C. L.; Butler, G. B. Water-Soluble Polymers: Synthesis, Solution Properties and Applications; ACS Symposium Series 467; American Chemical Society: Washington, DC, 1991.
11. Sumerlin, B. S.; Donovan, M. S.; Mitsukami, Y.; Lowe, A. B.; McCormick, C. L. Macromolecules 2001, 34, 6561.
12. Donovan, M. S.; Sumerlin, B. S.; Lowe, A. B.; McCormick, C. L. Macromolecules 2002, 35, 8663.
13. Donovan, M. S.; Lowe, A. B.; Sumerlin, B. S.; McCormick, C. L. Macromolecules 2002, 35, 4123.
14. Donovan, M. S.; Sanford, T. A.; Lowe, A. B.; Sumerlin, B, S.; Mitsukami, Y.; McCormick, C. L, Macromolecules 2002, 35, 4570.
15. Li, D.; Brittain, W. J. Macromolecules 1998, 31, 3852.
16. Benoit, D.; Chaplinski, V.; Braslau, R.; Hawker, C. J. J. Am. Chem. Soc. 1999, 121, 3904.
17. Huang, X.; Wirth, M. J. Macromolecules 1999, 32, 1694.
18. Teodorescu, M.; Matyjaszewski, K. Macromolecules 1999, 32, 4826.
19. Rademacher, J. T.; Baum, M.; Pallack, M. E.; Brittain, W. J.; Simonsick, W. J. Macromolecules 2000, 33, 284.
20. Senoo, M.; Kotani, Y.; Kamigaito, M.; Sawamoto, M. Macromolecules 1999, 32, 8005.
21. Taton, D.; Wilczewska, A.-Z.; Destarac, M. R. Macromol. Rapid Commun. 2001, 22, 1497.
22. McCormick, C. L.; Donovan, M. S,; Lowe, A. B.; Sumerlin, B. S.; Thomas, D. B. Chain Transfer Agents for RAFT Polymerization in Aqueous Media. US Application No. 10/073,820.
23. Thomas, D. B.; Convertine, A. J.; McCormick, C. L. Polym. Prepr. 2003, 44, in press.
24. Thomas, D. B.; Convertine, A. J.; Hennaux, P.; Sumerlin, B. S.; Lowe, A. B.; McCormick, C. L., manuscript in preparation.
25. Fevola, M. J,; Hester, R. D.; McCormick, C. L. J. Polym. Sci., Polym. Chem. 2003, 41, 560.
26. Rizzardo, E.; Chiefari, J.; Mayadunne, R. T. A.; Moad, G.; Thang, S. H. In Controlled/Living Radical Polymerization. Progress in ATRP, NMP and RAFT; Matyjaszewski, K., Ed.; American Chemical Society: Washington, DC; Vol. 768, pp 278-296.
27. Ladaviere, C.; Dorr, N.; Claverie, J. P. Macromolecules 2001, 34, 5370.
28. Vana, P.; Davis, T. P.; Barner-Kowollik, C. Macromol. Theory Simul. 2002, 11, 823.
29. Coote, M. L.; Radom, L. J. Am. Chem. Soc., Web Release Jan. 16, 2003.
30. Kazakov, S. A.; Shirshin, K. V.; Kazantsev, O. A.; Danov, S. M. RUSS. J. Gen. Chem. 1999, 69, 932.
31. These decomposition products may act as radical traps producing the retardation observed in the uncontrolled acrylamide polymerization at ambient pH. For literature precedence see: Levillain, J.; Masson, S.; Hudson, A.; Alberti, A. J. Am. Chem. Soc. 1993, 115, 8444. Laus, M.; Papa, R.; Sparnacci, K.; Alberti, A.; Benaglia, M,; Macciantelli, D. Macromolecules 2001, 34, 7269.
32. These decomposition products may act as radical traps producing the retardation observed in the uncontrolled acrylamide polymerization at ambient pH. For literature precedence see: Levillain, J.; Masson, S.; Hudson, A.; Alberti, A. J. Am. Chem. Soc. 1993, 115, 8444. Laus, M.; Papa, R.; Sparnacci, K.; Alberti, A.; Benaglia, M,; Macciantelli, D. Macromolecules 2001, 34, 7269.
33. Favier, A.; Charreyre, M.-T.; Chaumont, P.; Pichot, C. Macromolecules 2002, 35, 8271.