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Volumn 35, Issue 22, 2002, Pages 8271-8280

Study of the RAFT polymerization of a water-soluble bisubstituted acrylamide derivative. 1. Influence of the dithioester structure

Author keywords

[No Author keywords available]

Indexed keywords

REVERSIBLE ADDITION-FRAGMENTATION CHAIN TRANSFER (RAFT);

EID: 0037159301     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma020550c     Document Type: Article
Times cited : (113)

References (63)
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    • In particular, because termination reactions occur, the RAFT techniqne cannot be considered as a living polymerization according to Szwarc's criteria (Nature (London) 1956, 178, 1168) or IUPAC recommendations (Pure Appl. Chem. 1996, 68, 2287). However, recent discussions tend to introduce moderation to this definition (Darling, T.R.; Davis, T.P.; Fryd, M.; Gridnev, A.A.; Haddleton, D.M.; Ittel, S.D.; Matheson, Jr., R.R.; Mead, G.; Rizzardo, E. J. Polym. Sci., Part A: Polym. Chem. 2000, 38, 1706).
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    • In particular, because termination reactions occur, the RAFT techniqne cannot be considered as a living polymerization according to Szwarc's criteria (Nature (London) 1956, 178, 1168) or IUPAC recommendations (Pure Appl. Chem. 1996, 68, 2287). However, recent discussions tend to introduce moderation to this definition (Darling, T.R.; Davis, T.P.; Fryd, M.; Gridnev, A.A.; Haddleton, D.M.; Ittel, S.D.; Matheson, Jr., R.R.; Mead, G.; Rizzardo, E. J. Polym. Sci., Part A: Polym. Chem. 2000, 38, 1706).
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    • note
    • The more efficient the dithioester, the faster the fragmentation reaction and the less probable the side reactions on intermediate radicals II and III. Moreover, considering the macrodithioesters, the more stable the propagating radical, the faster the fragmentation reaction and the less probable the side reactions on intermediate radicals IV.
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    • Bamford, C.H.; Tipper, C.F.H. Free Radical Polymerization; Comprehensive Chemical Kinetics; Elsevier Scientific Publishing Co.: Amsterdam, 1976; p 169.
    • (1976) Free Radical Polymerization , pp. 169
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.