Kinetics of biomass pyrolysis: A reformulated three-parallel-reactions model

Industrial and Engineering Chemistry Research

Volumn 42, Issue 3, 2003, Pages 434-441

  Manyà, Joan J ^a   Velo, Enrique ^a   Puigjaner, Luis ^a  

^a UNIVERSITAT POLITÈCNICA DE CATALUNYA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

BAGASSE; CELLULOSE; PYROLYSIS; SUGAR CANE; THERMOGRAVIMETRIC ANALYSIS;

HEMICELLULOSE;

BIOMASS;

CELLULOSE; HEMICELLULOSE; LIGNIN;

PYROLYSIS;

ARTICLE; BIOMASS; CHEMICAL REACTION; KINETICS; MODEL; PYROLYSIS; SUGARCANE;

BAGASSE; BIOMASS; CELLULOSE; GRAVIMETRY; PYROLYSIS; SUGAR CANE; THERMAL ANALYSIS;

EID: 0037419636     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie020218p     Document Type: Article

References (23)

1. Antal, M. J.; Allen, S. G.; Dai, X.; Shimizu, B.; Tam, M. S.; Gronli, M. Attainment of the Teoretical Yield of Carbon from Biomass. Ind. Eng. Chem. Res. 2000, 39, 4024.
2. Antal, M. J.; Várhegyi, G. Cellulose Pyrolysis Kinetics: The Current State of Knowledge. Ind. Eng. Chem. Res. 1995, 34, 703.
3. Milosavljevic, I.; Suuberg, E. M. Cellulose Thermal Decomposition Kinetics: Global Mass Loss Kinetics. Ind. Eng. Chem. Res. 1995, 34, 1081.
4. Antal, M. J.; Várhegyi, G.; Jakab, E. Cellulose Pyrolysis Kinetics: Revisited. Ind. Eng. Chem. Res. 1998, 37, 1267.
5. Chornet, E.; Roy, C. Compensation Effect in the Thermal Decomposition of Cellulosic Materials. Thermochim. Acta 1980, 35, 389.
6. Gronli, M.; Antal, M. J.; Várhegyi, G. A Round-Robin Study of Cellulose Pyrolysis Kinetics by Thermogravimetry. Ind. Eng. Chem. Res. 1999, 38, 2238.
7. Miller, R. S.; Bellan, J. A Generalized Biomass Pyrolysis Model Based on Superimposed Cellulose, Hemicellulose and Lignin Kinetics. Combust. Sci. Technol. 1997, 126, 97.
8. Orfao, J. J. M.; Antunes, F. J. A.; Figueiredo, J. L. Pyrolysis Kinetics of Lignocellulosic Materials-Three Independent Reactions Model. Fuel 1999, 78, 349.
9. Koufopanos, C. A.; Maschio, G.; Lucchesi, A. Kinetic Modeling of the Pyrolysis of Biomass and Biomass Components. Can. J. Chem. Eng. 1989, 67, 75.
10. Teng, H.; Wei, Y.-C. Thermogravimetric Studies on the Kinetics of Rice Hull Pyrolysis and the Influence of Water Treatment. Ind. Eng. Chem. Res. 1998, 37, 3806.
11. Bilbao, R.; Mastral, J. F.; Aldea M. E.; Ceamanos, J. The Influence of the Percentage of Oxygen in the Atmosphere on the Thermal Decomposition of Lignocellulosic Materials. J. Anal. Appl. Pyrolysis 1997, 42, 189.
12. Várhegyi, G.; Antal, M. J.; Jakab, E.; Szabo, P. Kinetic Modeling of Biomass Pyrolysis. J. Anal. Appl. Pyrolysis 1997, 42, 73.
13. Ouensanga, A.; Picard, C. Thermal Degradation of Sugar Cane Bagasse. Thermochim. Acta 1988, 125, 89.
14. Roque-Diaz, P.; Shemet, V.; Lavreko, V.; Khristich, V. Studies on Thermal Decomposition and Combustion Mechanism of Bagasse under non-Isothermal Conditions. Thermochirn. Acta 1985, 93, 349.
15. Várhegyi, G.; Antal, M. J.; Szekely, T.; Szabo, P. Kinetics of the Thermal Decomposition of Cellulose, Hemicellulose, and Sugar Cane Bagasse. Energy Fuels 1989, 3, 329.
16. Caballero, J. A.; Font, R.; Marcilla, A.; Conesa, J. A. New Kinetic Model for Thermal Decomposition of Heterogeneous Materials. Ind. Eng. Chem. Res. 1995, 34, 806.
17. Stubington, J. F.; Aiman, S. Pyrolysis Kinetics of Bagasse at High Heating Rates. Energy Fuels 1994, 8, 194.
18. Drummond, A.-R. F.; Drummond, I. W. Pyrolysis of Sugar Cane Bagasse in a Wire-Mesh Reactor. Ind. Eng. Chem. Res. 1996, 35, 1263.
19. Reina, J. Estudio Cinético e Hidrodinámico de la Pirólisis de Maderas Residuales para su Gasificación en Reactor de Lecho Fluidizado. Ph.D. Thesis, Universitat Politècnica de Catalunya, Barcelona, Spain, 1999.
20. Sherrod, P. H. NLREG Reference Manual, 1995 (available online at http://www.nlreg.com; verified July 3, 2002).
21. Conesa, J. A.; Marcilla, A.; Caballero, J. A.; Font, R. Comments on the Validity and Utility of the Different Methods for Kinetic Analysis of Thermogravimetric Data. J. Anal. Appl. Pyrolysis 2001, 58-59, 617.
22. Sesták, J. Thermophysical Properties of Solids. Their Measurements and Theoretical Thermal Analysis; Academia Praha: Prague, Czech Republic, 1984.
23. Várhegyi, G.; Szabo, P.; Jakab, E.; Till, F. Least Squares Criteria for the Kinetic Evaluation of Thermoanalytical Experiments. Examples from a Char Reactivity Study. J. Anal. Appl. Pyrolysis 2001, 57, 203.