Silica gel supported [1,4-bis(salicylidene amino)-phenylene] vanadium oxo complex catalyst for the oxidation of n-heptane using molecular oxygen

Journal of Molecular Catalysis A: Chemical

Volumn 192, Issue 1-2, 2003, Pages 275-280

  Mishra, G S ^a   Kumar, A ^a  

^a INDIAN INSTITUTE OF TECHNOLOGY KANPUR   (India)

Author keywords

1,4 bis(Salicylidene amino) phenylene vanadium oxo complex; GC MS analysis; N Heptane

Indexed keywords

HEPTANE; ISOMERIZATION; OXIDATION; SILICA GEL; VANADIUM COMPOUNDS;

COVALENTLY BONDED;

CATALYSTS;

[1,4 BIS(SALICYLIDENE AMINO)PHENYLENE]VANADIUM OXO COMPLEX; ACID; HEPTANE; HEPTANOL; LIGAND; NITROGEN; OXYGEN; SILICA GEL; UNCLASSIFIED DRUG; VANADIUM DERIVATIVE;

ARTICLE; CATALYST; CHEMICAL MODIFICATION; COVALENT BOND; GAS CHROMATOGRAPHY; ISOMERISM; LOW TEMPERATURE; MASS SPECTROMETRY; OXIDATION;

EID: 0037415161     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1381-1169(02)00448-X     Document Type: Article

References (30)

1. O. Reiser, Oxidation of weakly active C-H bonds, Angew-Chem. Int. Ed. Engl. 33 (1) (1994) 69-72.
2. G.B. Shulpin, G.V. Nizova, Formation of alkylperoxide in presence in the oxidation of alkanes by H202 catalyzed by transition metal complexes, React. Kinet. Catal. Lett. 48 (1992) 333-336.
3. T. Tagaw, Liquid phase oxidation of benzene to phenol over supported iron salts, J. Catal. 78 (1993) 201-210.
4. S. Murakashi, Y. Oda, T. Naota, N. Komiya, Aerobic oxidants of alkanes and alkenes in the presence of aldehydes catalyzed by copper salts, Chem. Soc., Chem. Commun. 2 (1993) 139-140.
5. A.K.S. Sinha, V. Shanker, Low-temperature catalyst for total oxidation of n-hexane, Ind. Eng. Chem. Res. 32 (6) (1993) 1061-1065.
6. R. Raja, G. Shanker, J.M. Thomas, New catalyst of aerobic selective oxidation of hydrocarbons: Mn(III) and Co(III)containing molecular sieves for the epoxidation of alkanes, Chem. Commun. (1999) 829-830.
7. Z. Wang, E. Martell Arthur, R.J. Motekaitis, Hydroxylation of alkanes by molecular oxygen with dinuclear Fe(II) macro cyclic complexes catalysts, Chem. Commun. (1998) 1523-1524.
8. S. Murahashi, Y. Oda, J. Naota, T Kuwabara, Ruthenium catalyst cytochrame P-450 type oxidation of alkanes with hydrooperoxides, Tetrahedron Lett. 34 (1993) 1202-1299.
9. M. Hartman, S. Ernst, Selective oxidation of linear alkanes with molecular oxygen on molecular sieve catalysts - a breakthrough, Angew-Chem. Int. Ed. 39 (2000) 888-890.
10. P.A. Shapley, N. Zhang, J.L. Allen, D.H. Pool, H.C. Liang, Selective alcohol oxidation with molecular oxygen catalyzed by Os-Cr and Ru-Cr Complexes, J. Am. Soc. 122 (2000) 1079-1091.
11. M.C. Capel-Sanchez, J.M. Compos-Martin, J.L.G. Fierro, M.P. Frutos, A.P. De Polo, Effective alkene epoxidation with dilute hydrogen peroxide on amorphous silica-supported titanium catalysts, Chem. Commun. (2000) 855-856.
12. A. Kumar Jr., S.K. Das, A. Kumar, Formation of benzene catalyzed by polymer-bond vanadyl acetoacetonate, J. Catal. 166 (1997) 108-110.
13. G.A. Olah, A. Molnar, Hydrocarbon Chemistry, 3rd ed., Wiley, New York, 1995, pp. 10-27.
14. J.M. Thomas, R. Raja, G. Shanker, G. Bell Robert, Molecular sieve catalyst for selective oxidation of linear alkanes by molecular oxygen, Nature 398 (1999) 227-230.
15. K.K. Pant, D. Kunzaru, Catalyst pyrolysis of n-heptane: kinetics and modeling, Ind. Eng. Chem. Res. 36 (1997) 2059-2065.
16. 2+ exchanged ferrierite, Appl. Catal. Part A: Gen. 214 (2001) 103-109.
17. K.I. Alhumaizi, V.M. Akhmedov, S.M. Al-Zahrani, S.H. Al-Kuowater, Low temperature hydrocracking of n-heptane over Ni-support catalysts: study of global kinetics, Apl. Catal. Part A: Gen. 219 (2001) 131-140.
18. D. Meloni, D. Martin, M. Guisnet, Acidic and catalytic properties of H-MCM-22 zeolites-2. n-Heptane cracking activity selectivity and deactivation cocking, Appl. Catal. Part A: Gen. 215 (2001) 67-79.
19. Y. Wang, A. Zhang, Q. Xu, R. Chen, Characterization of titanium modified USY zeolites and their catalytic performance on n-heptane cracking, Appl. Catal. Part A: Gen. 214 (2001) 167-177.
20. D. Stokylova Chanv Cher., H.T. Lechert, C.P. Bezouhanova, Oxidation conversion of n-heptane over molecular sieves, Appl. Catal. 203 (2000) 121-126.
21. 2+) catalyst for selective hydroxylation of cyclohexane by molecular oxygen, Catal. Lett. 81 (2002) 113-117.
22. C.A. Root, C.R. Hoeschele Comman, J.W. Kamf, V.L. Pecoraro, Structural and spectroscopic characterization of dioxo vanadium(V) complex with asymmetric schiff base ligands, 32 (1993) 3855-3861.
23. B.E. Leach, A Text Book - Applied Industrial Catalysis, vol. 3, Academic Press, London, 1984.
24. S. Siggia, Quantitative Organic Analysis, vol. 558, 3rd ed., Wiley, New York, 1963.
25. 2+ schiff base catalyst for hydroxylation of benzene, Tetrahedron Lett. 36 (1995) 7909.
26. H. Mimoun, L. Sausaine, E. Daire, M. Postal, J. Fisher, R. Weiss, Vanadium(V) peroxo complexes. New versatile bismimetric reagents for epoxidation of olefins and hydroxylation of alkanes and aromatic hydrocarbons, J. Am. Chem. Soc. 105 (1983) 3101-3110.
27. G.S. Mishra, A. Kumar, Catalytic oxidation of alkanes using molecular oxygen with supported vanadium complex, Chem. Con., India 1 (2000) 41-45.
28. S. Kulkarni, M. Alurker, A. Kumar, Polymer support with schiff functional groups supporting cobaltous palmitate as oxidation catalyst for oxidation, Appl. Catal. Part A: Gen. 142 (1996) 243.
29. B.K. Das, J.H. Clark, A novel immobilized cobalt(III) oxidation catalyst, Chem. Commun. (2000) 605-606.
30. 2, 2 (5) (2000) 77-579.