Metal island growth and dynamics on molybdenite surfaces

Geochimica et Cosmochimica Acta

Volumn 67, Issue 5, 2003, Pages 923-934

  Becker, Udo ^a   Rosso, Kevin M ^b   Weaver, Robert ^c   Warren, Michele ^d   Hochella Jr , Michael F ^c  

^a UNIVERSITY OF MICHIGAN   (United States)

^b PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

^c VIRGINIA POLYTECHNIC INSTITUTE AND STATE UNIVERSITY   (United States)

^d UNIVERSITY OF MANCHESTER   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; COPPER; GOLD; METAL; MINERAL ALTERATION; MOLYBDENITE; SILVER; SULFIDE; SURFACE STRUCTURE;

EID: 0037371704     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0016-7037(02)01144-4     Document Type: Article

References (34)

1. 2 surface. Surf. Sci. 367, 209-220.
2. Brändle M., Calzaferri G., and Lanz M. (1995) Size quantization and surface states of molybdenum sulphide clusters: a molecular orbital approach. Chem. Phys. 201, 141-150.
3. Becker U. (1995) The electronic structure of galena and hematite surfaces: Applications to the interpretations of STM images, XPS spectra, and heterogeneous surface reactions. Ph. D. Dissertation, Virginia Polytechnic Institute and State University, 189 p.
4. Becker U. and Hochella M. F. Jr. (1996) The calculation of STM images, STS spectra, and XPS peak shifts for galena: New tools for understanding mineral surface chemistry. Geochim. Cosmochim. Acta 60, 2413-2426.
5. Becker U., Vaughan D. J., and Hochella M. F. Jr. (1997) The adsorption of gold to galena surfaces: Calculation of adsorption/reduction energies, reaction mechanisms, XPS spectra, and STM images. Geochim. Cosmochim. Acta 61, 3565-3585.
6. Becker U., Rosso K., and Hochella M. F. Jr. (2001) The proximity effect on semiconducting mineral surfaces: A new aspect of mineral surface reactivity and surface complexation theory? Geochim. Cosmochim. Acta 65, 2641-2649.
7. 2. 1. Band-structure calculations and photoelectron-spectroscopy. Phys. Rev. B. 35, 6195-6202.
8. 2. 2. The nature of the optical band-gaps. Phys. Rev. B. 35, 6203-6206.
9. Coley T. R., Goddard W. A., and Baldeschwieler J. D. (1991) Theoretical interpretation of scanning tunneling microscopy images - Application to the molybdenum-disulfide family of transition-metal dichalcogenides. J. Vac. Sci. Tech. B. 9, 470-474.
10. Cox J. D., Wagman D. D., and Medvedev V. A. (1989) CODATA, Key Values for Thermodynamics. New York, USA: Hemisphere Publishing Corp.
11. Dickinson R. G. and Pauling, L. (1923) The crystal structure of molybdenite. J. Am. Chem. Soc. 45, 1466-1471.
12. Dovesi R., Saunders V. R., and Roetti C. (2000) Crystal98, an ab initio Hartree-Fock LCAO program for periodic systems. University of Turin, Italy.
13. Frisch M. J., Trucks G. W., Schlegel H. B., Scuseria G. E., Robb M. A., Cheeseman J. R., Zakrzewski V. G., Montgomery J. A. Jr., Stratmann R. E., Burant J. C., Dapprich S., Millam J. M., Daniels A. D., Kudin K. N., Strain M. C., Farkas O., Tomasi J., Barone V., Cossi M., Cammi R., Mennucci B., Pomelli C., Adamo C., Clifford S., Ochterski J., Petersson G. A., Ayala P. Y., Cui Q., Morokuma K., Malick D. K., Rabuck A. D., Raghavachari K., Foresman J. B., Cioslowski J., Ortiz J. V., Baboul A. G., Stefanov B. B., Liu G., Liashenko A., Piskorz P., Komaromi I., Gomperts R., Martin R. L., Fox D. J., Keith T., Al-Laham M. A., Peng C. Y., Nanayakkara A., Gonzalez C., Challacombe M., Gill P. M. W., Johnson B., Chen W., Wong M. W., Andres J. L., Gonzalez C., Head-Gordon M., Replogle E. S., and Pople J. A. (1998) Gaussian 98, Revision A.7, Gaussian, Inc., Pittsburgh PA.
14. Gervilla F., Papunen H., Kojonen K., and Johanson B. (1998) Platinum-, palladium- and gold-rich arsenide ores from the Kylmakoski Ni-Cu deposit (Vammala Nickel Belt, SW Finland). Min. Petrol. 64, 163-185.
15. Grenne T., Ihlen P. M., and Vokes, F. M. (1999) Scandinavian Caledonide Metallogeny in a plate tectonic perspective. Min. Dep. 34, 422-471.
16. Kertesz M. and Hoffmann R. (1984) Octahedral vs trigonal-prismatic coordination and clustering in transition-metal dichalcogenides. J. Am. Chem. Soc. 106, 3453-3460.
17. Li S. Y., Rodriguez J. A., Hrbek J., Huang H. H., and Xu, G. Q. (1998) Chemical and electronic properties of silver atoms supported on sulfur and molybdenum sulfide surfaces. Surf. Sci. 395, 216-228.
18. Lexa J., Stohl J., and Konecny V. (1999) The Banska Stiavnica ore district: relationship between metallogenetic processes and the geological evolution of a stratovolcano. Min. Dep. 34, 639-654.
19. Magonov S. N. and Whangbo M. H. (1994) Interpreting STM and AFM images. Adv Mat. 6, 355-371.
20. Maloof T. L., Baker T., and Thomson J. F. H. (2001) The Dublin. Gulch intrusion-hosted gold deposit, Tombstone plutonic suite, Yukon Territory, Canada. Min. Dep. 36, 583-593.
21. 2 thin films prepared by an intercalation-exfoliation method. J. Vac. Sci. Tech. B. 12, 2111-2114.
22. Milman V., Winkler B., White J. A., Pickard C. J., Payne M. C., Akhmatskaya E. V., and Nobes R. H. (2000) Electronic structure, properties, and phase stabilities of inorganic crystals: a pseudopotential plane-wave study. Int. J. Quant. Chem. 77, 895-910.
23. Miyake K., Aiso Y., Komiyama M., Harada A., Kamachi M., and Shigekawa H. (1994) Lattice matching of α-cyclodextrin commensurate with molybdenum disulfide studied by scanning tunneling microscopy. Jpn. J. Appl. Phys. 33, 3720-3722.
24. MSI (1998) Castep User Guide, Molecular Simulations Inc., San Diego.
25. Perdew J. P., Chevary J. A., Vosko S. H., Jackson K. A., Pederson M. R. Singh D. J., and Fiolhais C. (1992) Atoms, molecules, solids, and surfaces - Applications of the generalized gradient approximation for exchange and correlation. Phys. Rev. B. 46, 6671-6687.
26. Pisani C. (1996) Quantum-mechanical ab-initio calculation of the properties of crystalline materials, Lecture Notes in Chemistry. Vol. 67, 327 p., Berlin: Springer Verlag.
27. Pisani C., Dovesi R., and Roetti C. (1988) Hartree-Fock ab initio treatment of crystalline systems. Lecture Notes in Chemistry. Vol. 48, 190 p. Berlin: Springer Verlag.
28. Rappe A. K. and Goddard W. A. (1991) Charge equilibration for molecular dynamics dimulations. J. Phys. Chem. 95, 3358-3363.
29. Sanchez-Portal D., Artacho E., and Soler J. M. (1995) Projection of plane-wave calculations into atomic orbitals. Solid State Comm. 95, 685-690.
30. Schumm R. H., Wagman D. D., Bailey S., Evans W. H., and Parker V. B. (1973) In National Bureau of Standards. (USA) Technical Notes 270-1-270-8
31. Sotnikov V. I., Berzina A. N., Economou-Eliopoulos M., and Eliopoulos D. G. (2001) Palladium, platinum and gold distribution in porphyry Cu +/-. Mo deposits of Russia and Mongolia. Ore. Geol. Rev. 18, 95-111.
32. Wareham C. D., Rice C. M., Boyce A. J., and Rogers G. (1998) S, C, Sr, and Pb sources in the Pliocene Silver Creek porphyry Mo system, Rico, Colorado. Econ. Geol. Bull. Soc. Econ. Geol. 93, 32-46.
33. Watanabe M., Nishido H., Hoshino K., Hayasaka Y., and Imoto N. (1998) Metallogenic epochs in the Inner Zone of southwest Japan. Ore. Geol. Rev. 12, 267-288.
34. White J. A. and Bird, D. M. (1994) Implementation of gradient-corrected exchange-correlation potentials in Car-Parrinello total-energy calculations. Phys. Rev. B. 50, 4954-4957.