Facile oxidative addition of O-H bonds of methanol and water to IR(I) complexes having peraryldiphosphane ligands

Angewandte Chemie - International Edition

Volumn 37, Issue 24, 1999, Pages 3381-3383

  Tani, Kazuhide ^a   Iseki, Aika ^a   Yamagata, Tsuneaki ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

Iridium; Methanol; Oxidative additions; P ligands; Water

Indexed keywords

ALKANE DERIVATIVE; IRIDIUM COMPLEX; LIGAND; METHANOL; PHOSPHORUS DERIVATIVE; WATER;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; HYDROGEN BOND; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION; X RAY ANALYSIS;

EID: 0033521566     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19981231)37:24<3381::AID-ANIE3381>3.0.CO;2-O     Document Type: Article

References (34)

1. a) H. E. Bryndza, W. Tam, Chem. Rev. 1988, 88, 1163-1188;
2. b) T. Yoshida, Y. Ueda, S. Otsuka, J. Am. Chem. Soc. 1978, 100, 3941-3942;
3. c) T. Yoshida, T. Okano, Y. Ueda, S. Otsuka, J. Am. Chem. Soc. 1981, 103, 3411-3422;
4. d) T. Yoshida, T. Kitani, S. Otsuka, J Am. Chem. Soc. 1979, 101, 2027-2038;
5. e) T. Yoshida, T. Okano, T. Saito, S. Otsuka, Inorg. Chim. Acta 1980, 44, L135-L135.
6. R. A. W. Johnstone, A. H. Wilbi, I. D. Entwisth, Chem. Rev. 1985, 85, 129-170.
7. K. Tani, E. Tanigawa, Y. Tatsuno, S. Otsuka, J. Organomet. Chem. 1985, 279, 87-101.
8. a) D. Milstein, J. C. Calabrese, I. D. Williams, J. Am. Chem. Soc. 1986, 108, 6387-6389;
9. b) D. Milstein, J. Am. Chem. Soc. 1986, 108, 3525-3526;
10. c) A. L. Casalnuovo, J. C. Calabrese, D. Milstein, Inorg. Chem. 1987, 26, 971-973;
11. d) O. Blum, D. Milstein, Angew. Chem. 1995, 107, 210-212; Angew. Chem. Int. Ed. Engl. 1995, 34, 229-231;
12. d) O. Blum, D. Milstein, Angew. Chem. 1995, 107, 210-212; Angew. Chem. Int. Ed. Engl. 1995, 34, 229-231;
13. e) O. Blum, D. Milstein, J. Am. Chem. Soc. 1995, 117, 4582-4594.
14. a) R. S. Paonessa, A. L. Prignano, W. C. Trogler, Organometallics 1985, 4, 647-656;
15. b) J. Fornies, M. Green, J. L. Spencer, F. G. A. Stone, J. Chem. Soc. Dalton Trans. 1977, 1006-1009;
16. c) D. Braga, P. Sabatino, C. Di Buugno, P. Leoni, M. Pasquali, J. Organomet. Chem. 1987, 334, C46-C48;
17. d) F. L. Ladipo, M. Kooti, J. S. Merola, Inorg. Chem. 1993, 32, 1681-1688;
18. e) L. J. Newman, R. G. Bergman, J. Am. Chem. Soc. 1985, 107, 5314-5315;
19. f) D. S. Glueck, L. J. N. Winslow, R. G. Bergman, Organometallics 1991, 10, 1462-1479;
20. g) A. L. Seligson, R. L. Cowan, W. C. Trogler, Inorg. Chem. 1991, 30, 3371-3381;
21. h) N. S. Akl, H. A. Tayim, J. Organomet. Chem. 1985, 297, 371-374;
22. i) H. Werner, A. Michenfelder, M. Schulz, Angew. Chem. 1991, 103, 617; Angew. Chem. Int. Ed. Engl. 1991, 30, 596-598.
23. i) H. Werner, A. Michenfelder, M. Schulz, Angew. Chem. 1991, 103, 617; Angew. Chem. Int. Ed. Engl. 1991, 30, 596-598.
24. T. Yamagata, A. Iseki, K. Tani, Chem. Lett. 1997, 1215-1216.
25. R. Dorta, P. Egli, F. Zücher, A. Togni, J. Am. Chem. Soc. 1997, 119, 10857-10858.
26. R. Uson, L. A. Oro, J. A. Cabeza, Inorg. Synth. 1985, 23, 126-129.
27. The NMR signal of a monomeric ROH proton appears at about δ = 0.5; R. M. Silverstein, G. C. Bassler, T. C. Morrill, Spectrometric Identification of Organic Compounds, 4th ed., Wiley, New York, 1981, Chap. 4.
28. -3. For more details refer to the supporting information. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Center as supplementary publication no. CCDC-101027. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: (+44)1223-336-033; e-mail: deposit@ccdc.cam.ac.uk). All calculations were carried out on Silicon Graphics SGI Power Challenge workstation at the Research Center for Protein Engineering, Institute for Protein Research, Osaka University.
29. G. M. Sheldrick, SHELXS-86, Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1985.
30. J. Karle, J. Acta Crystallogr. Sect. B 1968, 24, 182-186. The DIRDIF program system. Technical Report of the Crystallography Laboratory, University of Nijmegen, The Netherlands. teXsan: Single Crystal Structure Analysis Software, Version 1.6f, Molecular Structure Corporation, The Woodlands, TX 77381, USA, 1993.
31. G. M. Sheldrick, SHELXL-93 in Crystallographic Computing 6 (Eds.: P. Flack, P. Parknyi, K. Simon), University Press, Oxford, 1993.
32. R. Noyori, H. Takaya, Acc. Chem. Res. 1990, 23, 345-350, and references therein.
33. A. G. Orpen, L. Brammer, F. G. Allen, O. Kennard, D. G. Watson, R. Taylar, J. Chem. Soc. Dalton Trans. 1989, S1-S83.
34. 1 complexes to give neutal hydrodido(hydroxo) complexes was reported: R. Dorta, A. Togni, Organometallics 1998, 17, 3423-3428.