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note
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20 Compound (7) was prepared from cis-dicyclopropane-1,2-dimethanol, vinyl butyrate and porcine pancreatic lipase (G. D. Coxon, S. Knobl, E. Roberts, M. S. Baird, J. R. Al Dulayymi, G. S. Besra, P. J. Brennan and D. E. Minnikin, Tetrahedron Lett., 1999, 6689; we regret that this was incorrectly reported in that paper. The enantiomer of (7) was in fact converted into natural lactobacillic acid, whereas (7) gave its enantiomer).
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Prepared from -aspartic acid based on J. A. Frick, J. B. Klassen, A. Bathe, J. M. Abramson and H. Rappoport, Synthesis, 1992, 621.
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0012747693
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note
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3). Thanks are due to the EPSRC MS Service in Swansea for obtaining the molecular mass of 4.
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34
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35
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0012729353
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note
-
We thank Professor D.E. Minnikin for supplying a sample of the material originally extracted for ref. 2.
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