Reverse-flow operation for application of imperfectly immobilized catalysts

AIChE Journal

Volumn 49, Issue 1, 2003, Pages 151-167

  Hung, Kim G W ^a   Papadias, Dennis ^a   Björnbom, Pehr ^a   Anderlund, Magnus ^b   Åkermark, Björn ^b  

^a ROYAL INSTITUTE OF TECHNOLOGY   (Sweden)

^b STOCKHOLM UNIVERSITY   (Sweden)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL REACTORS; DISPERSIONS; LEACHING; REACTION KINETICS;

HOMOGENEOUS CATALYSTS;

CATALYSTS;

CATALYST; LEACHING; PACKED BED; REACTOR; REVERSE FLOW;

ARTICLE; CATALYSIS; CATALYST; DISPERSION; FLOW MEASUREMENT; IMMOBILIZATION; KINETICS; LEACHING; MATHEMATICAL ANALYSIS; MATHEMATICAL MODEL; MEASUREMENT; REACTOR;

EID: 0037207976     PISSN: 00011541     EISSN: None     Source Type: Journal    
DOI: 10.1002/aic.690490114     Document Type: Article

References (29)

1. Agar, D. W., and W. Ruppel, "Multifunktionale Reaktoren für die Heterogene Katalyse," Chem. Ing. Tech., 60, 731 (1988).
2. Blanks, R. F., T. S. Wittrig, and D. A. Peterson, "Bidirectional Adiabatic Synthesis Gas Reactor," Chem. Eng. Sci., 45, 2407 (1990).
3. Björnbom, P., K. G. W. Hung, M. Anderlund, and B. Äkermark, "Reverse Flow Operation for Catalyst Trapping," AIChE Meeting, Reno, NV (2001).
4. Björnbom, P., and B. Åkermark, "A Catalytic Process in a Flow Reversal Reactor," PCT Patent Application WO 01/28674, to KTH Holding AB (April 26, 2001).
5. 3," React. Kinet. Catal. Lett., 37, 267 (1988).
6. Boreskov, G. K., Yu. Sh. Matros, and O. V. Kiselev, "Catalytic Processes Carried out Under Nonstationary Conditions: Thermal Front in a Fixed Bed of Catalyst," Kinet. Catal., 20, 773 (1979).
7. Boreskov, G. K., and Yu. Sh. Matros, "Unsteady-State Performance of Heterogeneous Catalytic Reactions," Catal. Rev.-Sci. Eng., 25, 551 (1983).
8. Cornil, S. B., and E. Kuntz, "Introducing TPPTS and Related Ligands for Industrial Biphasic Processes," J. Organomet. Chem., 502, 177 (1995).
9. Cottrell, F. G., "Purifying Gases and Apparatus Therefore," U.S. Patent No. 2,171,733 (June 21, 1938).
10. Falle, S. A. E. G., J. Kallrath, B. Brockmüller, A. Schreieck, J. R. Giddings, D. W. Agar, and O. Watzenberger, "The Dynamics of Reverse Flow Chromatographic Reactors with Side Stream Feed," Chem. Eng. Commun., 135, 185 (1995).
11. Femlab, User's Guide and Introduction, COMSOL AB, Stockholm (1999).
12. Garland, M., and J. Feng, "Unmodified Homogeneous Rhodium-Catalyzed Hydroformylation of Styrene. The Detailed Kinetics of the Regioselective Synthesis," Organometallics, 18, 417 (1999).
13. Heck, R. F., "Palladium-Catalyzed Vinylation of Organic Halides," Org. React., 27, 345 (1982).
14. Hommeltoft, S. I., O. Ekelund, and J. Zavilla, "Role of Ester Intermediates in Isobutane Alkylation and Its Consequence for the Choice of Catalyst System," Ind. Eng. Chem. Res., 36, 3491 (1997).
15. Hommeltoft, S. I., and H. F. A. Topsoe, "Alkylation Process," European Patent Application EP 0 433 954 A1, to Haldor Topsoe A/S (June 26, 1991).
16. Hung, K. G. W., M. Anderlund, B. Åkermark, and P. Björnbom, "A Reverse Flow Reactor for Homogeneous/Heterogeneous Catalysis," AIChE Meeting, Los Angeles, CA (2000).
17. Kallrath, J., A. Schreieck, B. Brockmüller, D. W. Agar, O. Watzenberger, S. A. E. G. Falle, and J. R. Giddings, "Simulation of Chromatographic Reactors," Comput. Chem. Eng., 18 (Suppl.), 331 (1993).
18. Khinast, J., Y. O. Jeong, and D. Luss, "Dependence of Cooled Reverse-Flow Reactor. Dynamics on Reactor Model," AIChE J., 45, 299 (1999).
19. Levenspiel, O., Chemical Reaction Engineering, 2nd ed., Wiley, New York, p. 282 (1972).
20. Matros, Yu. Sh., and G. A. Bunimovich, "Reverse-Flow Operation in Fixed Bed Catalytic Reactors," Catal. Rev. Sci. Eng., 38, 1 (1996).
21. Matros, Yu. Sh., G. A. Bunimovich, V. O. Strots, and E. A. Mirosh, "Reversed Flow Converter for Emission Control After Automotive Engines," Chem. Eng. Sci., 54, 2889 (1999).
22. Neophytides, S. G., and G. G. Froment, "A Bench Scale Study of Reversed Flow Methanol Synthesis," Ind. Eng. Chem. Res., 31, 1583 (1992).
23. Neophytides, S. G., and A. Tripakis, "The Transient Operation of a Solid Oxide Fuel Cell Monolith Under Forced Periodic Reversal of the Flow," Can. J. Chem. Eng., 74, 719 (1996).
24. Nieken, U., G. Kolios, and G. Eigenberger, "Fixed-Bed Reactors with Periodic Flow Reversal: Experimental Results for Catalytic Combustion," Catal. Today, 20, 355 (1994).
25. Sheldon, R. A., M. Wallau, I. W. C. E. Arends, and U. Schuchardt, "Heterogeneous Catalysis for Liquid-Phase Oxidations: Philosofers' Stones or Trojan Horses?" Acc. Chem. Res., 31, 485 (1998).
26. x-SCR Reactor with Side-Stream Ammonia Addition," Chem. Eng. Sci., 53, 727 (1998).
27. van de Beld, B., Air Purification by Catalytic Oxidation in a Adiabatic Packed-Bed Reactor with Periodic Flow Reactor, PhD Thesis, Univ. of Twente, Enshede, The Netherlands (1995).
28. Wöltinger, J., J. E. Bäckvall, and A. Zsigmond, "Zeolite-Encapsulated Cobalt Salophen Complexes as Efficient Oxygen-Activating Catalysts in Palladium-Catalyzed Aaerobic 1,4-oxidation of 1,3-dienes," Chem. Eur. J., 5, 1460 (1999).
29. Züfle, H., and T. Turek, "Catalytic Combustion in a Reactor with Periodic Flow Reversal: 1. Experimental Results," Chem. Eng. Process., 36, 327 (1997).