Hydrogen atom abstraction by a chromium(IV) oxo complex derived from O2

Journal of the American Chemical Society

Volumn 124, Issue 47, 2002, Pages 14008-14009

  Qin, Kun ^a   Incarvito, Christopher D ^a   Rheingold, Arnold L ^a   Theopold, Klaus H ^a  

^a UNIVERSITY OF DELAWARE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHROMIUM DERIVATIVE; HYDROGEN; OXYGEN;

ARTICLE; ATOM; CATALYSIS; CATALYST; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; MAGNETISM; MOLECULAR STABILITY; OXIDATION; PROTON NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT; REACTION ANALYSIS; SYNTHESIS;

EID: 0037184450     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja028382r     Document Type: Article

References (23)

1. (a) Lippard, S. J.; Berg, J. M. Principles of Bioinorganic Chemistry; University Science Books: Mill Valley, CA, 1994.
2. (b) Sheldon, R. A.; Kochi, J. K. Metal-Catalyzed Oxidations of Organic Compounds; Academic Press: New York, 1981.
3. (c) Mayer, J. M. Acc. Chem. Res. 1998, 31, 441.
4. (d) Bakac, A. J. Am. Chem. Soc. 2002, 124, 9136.
5. (a) Egan, J. W., Jr.; Haggerty, B. S.; Rheingold, A. L.; Sendlinger, S. C.; Theopold, K. H. J. Am. Chem. Soc. 1990, 112, 2445.
6. (b) Reinaud, O. M.; Theopold, K. H. J. Am. Chem. Soc. 1994, 116, 6979.
7. (c) Theopold, K. H.; Reinaud, O. M.; Doren, D.; Konecny, R. In 3rd World Congress on Oxidation Catalysis; Grasselli, R. K., Oyama, S. T., Gaffney, A. M., Lyons, J. E., Eds.; Elsevier: Amsterdam, 1997; p 1081.
8. (d) Thyagarajan, S.; Incarvito, C. D.; Rheingold, A. L.; Theopold, K. H. Chem. Commun. 2001, 2198.
9. (e) Hikichi, S.; Komatsuzaki, H.; Akita, M.; Moro-Oka, Y. J. Am. Chem. Soc. 1998, 120, 4699.
10. (f) Hikichi, S.; Yoshizawa, M.; Sasakura, Y.; Akita, M.; Moro-Oka, Y. J. Am. Chem. Soc. 1998, 120, 10567.
11. Qin, K.; Incarvito, C. D.; Rheingold, A. L.; Theopold, K. H. Angew. Chem., Int. Ed. 2002, 41, 2333.
12. (a) Mayer, J. M. Comments Inorg. Chem. 1988, 8, 125.
13. (b) Bakac, A.; Espenson, J. H. Acc. Chem. Res. 1993, 26, 519.
14. 1 = 0.0609 [I > 2σ], GOF = 1.033.
15. Orpen, A. G.; Brammer, L.; Allen, F. H.; Kennard, O.; Watson, D. G. J. Chem. Soc., Dalton Trans. 1989, S1.
16. Hess, A.; Hörz, M. R.; Liable-Sands, L. M.; Lindner, D. C.; Rheingold, A. L.; Theopold, K. H. Angew. Chem., Int. Ed. 1999, 38, 166.
17. 4. The byproduct of the oxygen atom transfer, i.e., iodobenzene, has only aromatic C-H bonds (similar in strength to those of benzene). The reaction is carried out on a vacuum line to prevent contamination with solvents from the drybox atmosphere.
18. 1 = 0.0777 [I > 2σ], GOF = 1.083 1,083.
19. Nugent, W. A.; Mayer, J. M. Metal-Ligand Multiple Bonds; Wiley: New York, 1988; p 163.
20. (a) Shirin, Z.; Hammes, B. S.; Young, V. G., Jr.; Borovik, A. S. J. Am. Chem. Soc. 2000, 122, 1836.
21. (b) Macbeth, C. E.; Hammes, B. S.; Young, V. G.; Borovik, A. S. Inorg. Chem. 2001, 40, 4733.
22. Wells, A. F. Structural Inorganic Chemistry; Clarendon: Oxford, 1984; p 357.
23. All bond dissociation energies from CRC Handbook of Chemistry and Physics, 72nd Ed.; Lide, D. R., Ed.; CRC Press: Boca Raton 1991; p 9-115.