The first structural characterization of an azoaromatic radical anion stabilized by dicopper(I) coordination

Angewandte Chemie - International Edition

Volumn 37, Issue 17, 1998, Pages 2403-2404

  Doslik, Nataša ^a   Sixt, Torsten ^a   Kaim, Wolfgang ^a  

^a UNIVERSITY OF STUTTGART   (Germany)

Author keywords

Azo compounds; Bond order; Copper; EPR; Radical ions; Spectroscopy

Indexed keywords

EID: 0032544381     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19980918)37:17<2403::AID-ANIE2403>3.0.CO;2-J     Document Type: Article

References (23)

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15. Kα radiation (0.71073 A°). The structure was solved by direct methods (Siemens SHELXS-86) and refined with full-matrix least-square methods (SHELXL-93). Two solvent molecules had to be included, one of which was disordered. Anisotropic thermal parameters were refined for all non-hydrogen atoms. Hydrogen atoms were introduced at calculated positions and refined freely (riding model). Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-101074. Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road. Cambridge CB2 1EZ, UK (fax: (-44)1223-336-033: e-mail: deposit@ccdc.cam.ac.uk).
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23. Note added in proof (July 24, 1998): The molecular structure of Ru complexes of azoaromatic radical anions will be reported by A. Chakravorty et al.