Asymmetric [2+2+1] cyclopentannulation of olefins. Ring expansion of 2-N-methyl-N-tosyl-cyclobutanone

Tetrahedron

Volumn 58, Issue 35, 2002, Pages 6991-7000

  Mahuteau Betzer, Florence ^a   Ghosez, Léon ^a,b  

^a UNIVERSITÉ CATHOLIQUE DE LOUVAIN   (Belgium)

^b INSTITUT EUROPÉEN DE CHIMIE ET BIOLOGIE   (France)

Author keywords

Cyclobutanone; Cyclopentannulation; Cyclopentenone; Rearrangement

Indexed keywords

1 METHYL 7 (METHYLTOSYLAMINO)SPIRO[BICYCLO[3.2.0]HEPTAN 6,2' OXIRANE]; 10 (METHYLTOSYLAMINO)SPIRO[BICYCLO[6.2.0]DECAN 9,2' OXIRANE]; 2 (METHYLTOSYLAMINO) 3 PHENYLSPIRO[CYCLOBUTAN 1,2' OXIRANE]; 3 BUTYL 2 (METHYLTOSYLAMINO)SPIRO[CYCLOBUTAN 1,2' OXIRANE]; 5 METHYLBICYCLO[3.3.0]OCT 3 EN 2 ONE; 7 (METHYLTOSYLAMINO)SPIRO[BICYLO[3.2.0]HEPTAN 6,2' OXIRANE]; 8 (METHYLTOSYLAMINO)SPIRO[BICYCLO[4.2.0]OCT 3 EN 7,2' OXIRANE]; 8 (METHYLTOSYLAMINO)SPIRO[BICYCLO[4.2.0]OCTAN 7,2' OXIRANE]; 9 (METHYLTOSYLAMINO)SPIRO[BICYCLO[5.2.0]NONAN 8,2' OXIRANE]; ALKENE DERIVATIVE; BICYCLO COMPOUND; BICYCLO[6.3.0]DEC 9 EN 8 ONE; CYCLOBUTANONE DERIVATIVE; CYCLOPENTENONE DERIVATIVE; DIMETHYLSULFONIUM METHYLID; ETHYLENE OXIDE DERIVATIVE; KETENE DERIVATIVE; LITHIUM DERIVATIVE; LITHIUM IODIDE; SULFONIUM DERIVATIVE; TETRAHYDROFURAN; TOLUENESULFONAMIDE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; ASYMMETRIC SYNTHESIS; CHEMICAL REACTION; CHIRALITY; CYCLOPENTANNULATION; ENANTIOMER; PRIORITY JOURNAL; REACTION ANALYSIS; STEREOCHEMISTRY; STOICHIOMETRY;

EID: 0037178952     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(02)00694-4     Document Type: Article

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