A [2+2+1] strategy for the conversion of olefins into cyclopentenones. Ring expansion of 2-N-methyl-N-tosylcyclobutanones

Tetrahedron Letters

Volumn 40, Issue 28, 1999, Pages 5183-5186

  Mahuteau Betzer, Florence ^a   Ghosez, Léon ^a  

^a UNIVERSITÉ CATHOLIQUE DE LOUVAIN   (Belgium)

Author keywords

Cyclobutanones; Cyclopentannulation; Cyclopentenones; Epoxides; Rearrangement; Ring expansion

Indexed keywords

ALKENE DERIVATIVE; CYCLOBUTANONE DERIVATIVE; CYCLOPENTENONE DERIVATIVE; EPOXIDE; IMINE; IODINE DERIVATIVE; SULFONIUM DERIVATIVE;

ARTICLE; CHEMICAL MODIFICATION; ENANTIOMER; REACTION ANALYSIS; STEREOCHEMISTRY; STEREOSPECIFICITY; X RAY DIFFRACTION;

EID: 0033538656     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(99)00948-X     Document Type: Article

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27. 3S C%: 63.52; H%: 7.21; N%: 4.36; S%: 9.97; Found: C%: 63.46; H%: 7.25; N%: 4.29; S%: 10.35.
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29. 3S C%: 63.52; H%: 7.21; N%: 4.36; S%: 9.97; Found: C%: 63.27; H%: 7.16; N%: 4.22; S%: 10.14. Compound 6a: identical with an authentic sample: RN=81255-91-6.