Sitting-atop complex formation of 2,3,7,8,12,13,17,18-octaethylporphyrin with copper(II) ion in acetonitrile

Inorganica Chimica Acta

Volumn 340, Issue , 2002, Pages 87-96

  Inamo, Masahiko ^a   Kohagura, Tomoko ^a   Kaljurand, Ivari ^b   Leito, Ivo ^b  

^a AICHI UNIVERSITY OF EDUCATION   (Japan)

^b UNIVERSITY OF TARTU   (Estonia)

Author keywords

Copper(II) complexes; pKa of porphyrin in acetonitrile; Porphyrin metallation; Reaction intermediate; Sitting atop complexes

Indexed keywords

ACETONITRILE; INORGANIC COMPOUNDS; METAL IONS; METALS; MOLAR RATIO; MOLECULES; NITROGEN; PORPHYRINS; RATE CONSTANTS; REACTION INTERMEDIATES; SPECTROPHOTOMETRY;

COMPLEX FORMATION REACTIONS; COPPER COMPLEXES; METALLATION; OUTER-SPHERE COMPLEXES; SECOND-ORDER CONDITIONS; SECOND-ORDER RATE CONSTANTS; SITTING-ATOP COMPLEXES; SPECTROPHOTOMETRIC TITRATIONS;

COPPER COMPOUNDS;

ACETONITRILE; COPPER COMPLEX; NITROGEN; PORPHYRIN DERIVATIVE; PYRROLE DERIVATIVE;

ALKALINITY; ARTICLE; CHEMICAL BINDING; CHEMICAL COMPOSITION; CHEMICAL REACTION; COMPLEX FORMATION; MOLECULAR DYNAMICS; REACTION TIME; SPECTROPHOTOMETRY; TITRIMETRY;

EID: 0037175536     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(02)01044-7     Document Type: Article

References (51)

1. Dailey H.A., Dailey T.A., Wu C.K., Medlock A.E., Wang K.F., Rose J.P., Wang B.C. Cell. Mol. Life Sci. 57:2000;1909.
2. Ferreira G.C. Int. J. Biochem. Cell Biol. 31:1999;995.
3. Taketani S. Fujita H., Regulation of Heme Protein Synthesis. 1994;Med Press, Ohio.
4. Lavallee D.K. Mol. Struct. Energ. 9:1988;279.
5. Dailey H.A. Biosynthesis of Heme and Chlorophylls. 1990;McGraw-Hill, New York.
6. Lavallee D.K. The Chemistry and Biochemistry of N-Substituted Porphyrins. 1987;VCH, New York.
7. Fleischer E.B., Wang J.H. J. Am. Chem. Soc. 82:1960;3498.
8. Marcquet J.P., Theophahanides T. Can. J. Chem. 51:1973;219.
9. Letts K., Mackay R.A. Inorg. Chem. 14:1975;2993.
10. Fleischer E.B., Dixon F. Bioinorg. Chem. 7:1977;129.
11. Inada Y., Sugimoto Y., Nakano Y., Itoh Y., Funahashi S. Inorg. Chem. 37:1998;5519.
12. Izutsu K. Acid-Base Dissociation Constants in Dipolar Aprotic Solvents. 1990;Blackwell Scientific Publications, London.
13. Lias S.G., Liepman J.F., Levin R.D. J. Phys. Chem. Ref. Data. 13:1984;695.
14. Inada Y., Nakano Y., Inamo M., Nomura M., Funahashi S. Inorg. Chem. 39:2000;4793.
15. Inamo M., Kamiya N., Inada Y., Nomura M., Funahashi S. Inorg. Chem. 40:2001;5636.
16. Gutmann V. The Donnor-Acceptor Approach to Molecular Interactions. 1978;Plenum Press, New York.
17. Kaljurand I., Rodima T., Leito I., Koppel I.A., Schwesinger R. J. Org. Chem. 65:2000;6202.
18. Leito I., Rodima T., Koppel I.A., Schwesinger R., Vlasov V.M. J. Org. Chem. 62:1997;8479.
19. Leito I., Kaljurand I., Koppel I.A., Yagupolskii L.M., Vlasov V.M. J. Org. Chem. 63:1998;7868.
20. Coetzee J.F. Prog. Phys. Org. Chem. 4:1967;45.
21. Coetzee J.F., Padmanabhan G.R. J. Am. Chem. Soc. 87:1965;5005.
22. Funahashi S., Inada Y. Trends Inorg. Chem. 5:1998;15.
23. Buchler J.W. Smith K.M., Porphyrins and Metalloporphyrins. 1975;Elsevier, Amsterdam.
24. Longo F.R., Brown E.M., Rau W.G., Adler A.D. Dolphin D., The Porphyrins. V:1978;459 Academic Press, New York.
25. Lavallee D.K. Coord. Chem. Rev. 61:1985;55.
26. Hambright P. Kadish K.M., Smith K.M., Guilard R., The Porphyrin Handbook. 3:2000;129 Academic Press, New York.
27. Funahashi S., Yamaguchi Y., Tanaka M. Bull. Chem. Soc. Jpn. 57:1984;204.
28. Funahashi S., Yamaguchi Y., Tanaka M. Inorg. Chem. 23:1984;2249.
29. S. Funahashi, Y. Yamaguchi, K. Ishihara, M. Tanaka, J. Chem. Soc., Chem. Commun. (1982) 187.
30. R. Khosropour, P. Hambright, J. Chem. Soc., Chem. Commun. (1972) 13.
31. Funahashi S., Saito K., Tanaka M. Bull. Chem. Soc. Jpn. 54:1981;2695.
32. Robinson L.R., Hambright P. Inorg. Chim. Acta. 185:1991;17.
33. Golubchikov O.A., Lomova T.N., Kuvshinova E.M., Korovina S.G., Klyueva M.E., Zhilina Z.M., Berezin B.D. Russ. J. Phys. Chem. 63:1989;188.
34. Fuoss R.M. J. Am. Chem. Soc. 80:1958;5059.
35. Eigen M. Z. Phys. Chem. 1:1954;176.
36. Sokol L.S.W.L., Fink T.D., Rorabacher D.B. Inorg. Chem. 19:1980;1263.
37. Powell D.H., Helm L., Merbach A.E. J. Chem. Phys. 95:1991;9258.
38. Powell D.H., Furrer P., Pittet P.-A., Merbach A.E. J. Phys. Chem. 99:1995;16622.
39. Poupko R., Luz Z. J. Chem. Phys. 57:1972;3311.
40. Helm L., Lincoln S.F., Merbach A.E., Zbinden D. Inorg. Chem. 25:1986;2550.
41. Sheldrick W.S. J. Chem. Soc., Perkin Trans. 2:1976;453.
42. Stone A., Fleischer E.B. J. Am. Chem. Soc. 90:1968;2735.
43. E. Cetinkaya, A.W. Johnson, M.F. Lappert, G.M. McLaughlin, K.W. Muir, J. Chem. Soc., Dalton Trans. (1974) 1236.
44. Senge M.O., Forsyth T.P., Nguyen L.T., Smith K.M. Angew. Chem., Int. Ed. Engl. 33:1994;2485.
45. Navaza A., De Rango C., Charpin P. Acta Crystallogr., C. 39:1983;1625.
46. Nguyen L.T., Senge M.O., Smith K.M. Tetrahedron Lett. 35:1994;7581.
47. Barkigia K.M., Fajer J., Berber M.D., Smith K.M. Acta Crystallogr., C. 51:1995;511.
48. Cheng B., Munro O.Q., Marques H.M., Scheidt W.R. J. Am. Chem. Soc. 119:1997;10732.
49. Shamim A., Hambright P., Williams R.F.X. Indian J. Chem. 21A:1982;763.
50. Suttler T.P.G., Hambright P. J. Coord. Chem. 30:1993;317.
51. Worthington P., Hambright P., Williams R.F.X., Reid J., Burnham C., Shamim A., Turay J., Bell D.M., Kirkland R., Little R.G., Datta-Gupta N., Eisner U. J. Inorg. Biochem. 12:1980;281.