Allenes as carbon nucleophiles in palladium-catalyzed reactions: Observation of anti attack of allenes on (π-allyl)palladium complexes

Journal of the American Chemical Society

Volumn 124, Issue 38, 2002, Pages 11246-11247

  Franzén, Johan ^a   Löfstedt, Joakim ^a   Dorange, Ismet ^a   Bäckvall, Jan E ^a  

^a STOCKHOLM UNIVERSITY   (Sweden)

Author keywords

[No Author keywords available]

Indexed keywords

ALLENE DERIVATIVE; PALLADIUM COMPLEX;

ARTICLE; CATALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; ELECTRON TRANSPORT; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0037174418     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja026150m     Document Type: Article

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52. One reviewer suggested that Pd(0) is assisting in the nucleophilic attack by coordinating to the allene. This is a possible pathway that we cannot exclude.