Stereoselectivity of the carbopalladation-functionalization of allenic compounds: A mechanistic study

Tetrahedron

Volumn 54, Issue 49, 1998, Pages 14835-14844

  Gamez, Patrick ^a   Ariente, Cécile ^a   Goré, Jacques ^a   Cazes, Bernard ^a  

^a UNIVERSITÉ LYON 1   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ACETIC ACID; ALKADIENE; ALLENE DERIVATIVE; ANION; HYDROCARBON; MALONIC ACID; PALLADIUM;

ARTICLE; CHEMICAL REACTION; CONJUGATION; PRIORITY JOURNAL; REACTION ANALYSIS; STEREOCHEMISTRY; STEREOISOMERISM; STRUCTURE ANALYSIS; TEMPERATURE;

EID: 0032480997     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(98)00945-4     Document Type: Article

References (22)

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15. 8. This anti-relationship is commonly encountered with allenic compounds. For example, the nucleophilic substitutions of the acetates or phosphates of 4-alkylbuta-2,3-diene-1-ols by Grignard or organocopper reagents lead to 1,3-dienes with a total anti-stereoselectivity corresponding to an anti incoming of the organometallic reagent referred to the 4-alkyl substituent: Djahanbini, D.; Cazes, B.; Goré, J. Tetrahedron, 1984, 40, 3465-3475.
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