Total synthesis of (+)-dactylolide

Organic Letters

Volumn 4, Issue 4, 2002, Pages 635-637

  Smith III, Amos B ^a   Safonov, Igor G ^a  

^a UNIVERSITY OF PENNSYLVANIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANTINEOPLASTIC AGENT; DACTYLOLIDE; DYES, REAGENTS, INDICATORS, MARKERS AND BUFFERS; FUSED HETEROCYCLIC RINGS; LACTONE; MACROLIDE; ZAMPANOLIDE;

ANIMAL; ARTICLE; CHEMISTRY; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SPONGE (PORIFERA); SYNTHESIS;

ANIMALS; ANTINEOPLASTIC AGENTS; BICYCLO COMPOUNDS, HETEROCYCLIC; INDICATORS AND REAGENTS; LACTONES; MACROLIDES; MAGNETIC RESONANCE SPECTROSCOPY; MASS SPECTROMETRY; PORIFERA;

EID: 0037149007     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol017271e     Document Type: Article

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16. 1H (500 and 600 MHz) NMR spectra were identical. (b) Optical rotation data for natural (+)-1 = +30.0° (c 1.0, MeOH); optical rotation for synthetic (+)-1 = +235° (c 0.52, MeOH).