Method for quantitative evaluation of kinetic constants in olefin polymerizations. II: Kinetic study of a high-activity Ziegler-Natta catalyst used for bulk propylene polymerizations

Journal of Applied Polymer Science

Volumn 86, Issue 13, 2002, Pages 3226-3245

  Matos, Vlter ^a   Mattos Neto, Antio G ^a   Nele, Mrcio ^b   Pinto, Jos Carlos ^b  

^a Polibrasil Resinas SA   (Brazil)

^b FEDERAL UNIVERSITY OF RIO DE JANEIRO   (Brazil)

Author keywords

Catalyst; Estimation; Kinetic constant; Kinetic parameter; Polymerization; Propylene; Ziegler Natta

Indexed keywords

CATALYSTS; GEL PERMEATION CHROMATOGRAPHY; NUCLEAR MAGNETIC RESONANCE; POLYMERIZATION; RATE CONSTANTS;

KINETIC PARAMETERS;

POLYPROPYLENES;

CATALYST; KINETICS; POLYMERIZATION; POLYOLEFIN; QUANTITATIVE ANALYSIS;

EID: 0037146640     PISSN: 00218995     EISSN: None     Source Type: Journal    
DOI: 10.1002/app.11055     Document Type: Article

References (28)

1. Moore, E.P., Jr. (Ed.). Polypropylene Handbook: Polymerization Characterization, Properties, Processing Applications; Hanser Gardner Publications: New York, 1996.
2. Chemical and Engineering News 2000, 78, 20.
3. Pinto, J.C.; SIMULPOL 3.0-Software for Simulation of Slurry and Bulk Propylene Polymerizations; The User's Guide, Internal Report, Polibrasil Resinas SA, Camaçari-BA, 1999.
4. Zabisky, R.C.M.; Chan, W.-M.; Gloor, P.E.; Hamielec, A.E. Polymer 1992, 33, 2243.
5. Soares, J.B.P.; Hamielec, A.E. Polym React Eng 1996, 4, 153.
6. Xie, T.; McAuley, K.B.; Hsu, J.C.C.; Bacon, D.W.; Ind Eng Chem Res 1994, 33, 449-479.
7. Zacca, J.J.; Debling, J.A.; Ray, W.H. Chem Eng Sci 1996, 51, 4859-4886.
8. Nele, M.; Pinto, J.C. J Appl Polym Sci 1997, 35, 1403-1413.
9. der Ven, S.V. Polypropylene and Other Polyolefins: Polymerization and Characterization; Elsevier Science: Amsterdam, 1990.
10. Matos, V.; Mattos Neto, A.G.; Pinto, J.C. J Appl Polym Sci 2001, 79, 2076.
11. Zacca, J.J.; Ray, W.H. Chem Eng Sci 1993, 48, 3743-3765.
12. Sarkar, P.; Gupta, S.K. Polym Eng Sci 1992, 32, 732-742.
13. Samson, J.J.C.; Weickert, G.; Heerze, A.E.; Westerterp, K.R. AICHE J 1998, 44, 1424-1437.
14. Samson, J.J.C.; Bosman, P.J.; Weickert, G.; Westerterp, K.R. J polym Sci, Part A: Polym Chem 1999, 37, 219-232.
15. Guinot, P.; Othman, N.; Fevotte, G.; McKenna, T.F. Polym React Eng 2000, 8, 115-134.
16. Tonelli, A.E. NMR Spectroscopy and Polymer Microstructure: The Conformational Connection; VCH: New York, 1991.
17. Phan, Q.; Petiaud, R.; Waton, H.; Darricades, M.F.L. Proton and Carbon NMR Spectra of Polymers; Penton Press: London, 1991.
18. Mori, H.; Endo, M.; Tashino, K.; Terano, M.J. Mol Catal A Chem 1999, 145, 153-158.
19. Soares, J.B.P.; Hamielec, A.E. Polymer 1996, 37, 4599-4605.
20. Keii, T. Kinetics of Ziegler-Natta Polymerization; Kodansha Scientific Books: Tokyo, 1972.
21. Kim, I.; Choi, H.K.; Kim, J.H., Woo, S.I. J Polym Sci, Part A: Polym Chem 1994, 32, 971-977.
22. Ross, P.J. Taguchi Techniques for Quality Engineering, 2nd ed.; McGraw-Hill: New York, 1996.
23. Shaffer, W.K.A.; Ray, W.H. J Appl Polym Sci 1997, 65, 1053-1080.
24. Froment, G.F.; Bischoff, K.B. Chemical Reactor Analysis and Design, 2nd ed., Wiley: New York, 1990.
25. Pinto, J.C. ESTIMA-A Software for Parameter Estimation and Experimental Design, User's Guide; PEQ/COPPE/UFRJ: Rio de Janeiro, 1999.
26. Box, W.; Hunter, J.S.; Hunter, W.G. Statistics for Experimenters: An Introduction to Design, Data Analysis, and Model Building; Wiley: New York, 1978.
27. Alman, E.J.; Cossee, P. J Catal 1960, 3, 99.
28. Mattos Neto, A.G.; Pinto, J.C. Chem Eng Sci 2001, 56, 4043-4057.