Liquid-phase polymerization of propylene with a highly active catalyst

AIChE Journal

Volumn 44, Issue 6, 1998, Pages 1424-1437

  Samson, Job Jan C ^a   Weickert, Günter ^a   Heerze, Annelies E ^a   Roel Westerterp, K ^a  

^a UNIVERSITY OF TWENTE   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; MONOMERS; POLYMERIZATION; PURIFICATION; REACTION KINETICS; TEMPERATURE CONTROL; THERMAL EFFECTS;

LIQUID PHASE POLYMERIZATION;

POLYPROPYLENES;

EID: 0032097214     PISSN: 00011541     EISSN: None     Source Type: Journal    
DOI: 10.1002/aic.690440620     Document Type: Article

References (18)

1. Aminabhavi, T. M., H. T. S. Phayde, and J. D. Ortego, "A Study of Sorption/Desorption and Diffusion of n-Alkanes and Aliphatic Hydrocarbons into Polymeric Blends of Ethylene-Propylene Random Co-Polymer and Isotactic Polypropylene in the Temperature Interval of 25 to 70°C," J. Poly. Eng., 16, 121 (1996).
2. Barton, A. F. M., CRC Handbook of Polymer-Liquid Interaction Parameters and Solubility Parameters, CRC Press, Boca Raton, FL, p. 284 (1990).
3. Böhm, L. L., "Reaction Rate Model for Ziegler-Natta Polymerization Processes," Polymer, 19, 545 (1978).
4. Bradford, M. L., and G. Thodos, "Solubility Parameters of Hydrocarbons," Can. J. Chem. Eng., 44, 345 (1966).
5. Brockmeier, N. F., and J. B. Rogan, "Propylene Polymerization Kinetics in a Semi-Batch Reactor by Use of a Supported Catalyst," Ind. Eng. Chem. Prod. Res. Dev., 24, 278 (1985).
6. Doi, Y., T. Keii, E. Suzuki, and M. Tamura, "Propene Polymerization with a Magnesium Chloride Supported Ziegler Catalyst 1," Macromol. Chem., 183, 2285 (1982).
7. Gunn, D. J., "Transfer of Heat or Mass to Particles in Fixed and Fluidised Beds," Int. J. Heat Mass Transfer, 21, 467 (1978).
8. 2 Catalyst I. Effect of Polymerization Conditions," J. Poly. Sci. Part A Poly. Chem., 35, 2063 (1997).
9. Hutchinson, R. A., and W. H. Ray, "Polymerization of Olefins through Heterogeneous Catalysis," J. Appl. Polym. Sci., 41, 51 (1990).
10. 4," Poly. Bull., 23, 35 (1990).
11. Kim, J. H., I. Kim, and S. I. Woo, "Computer Simulation Study of Ethylene Polymerization Rate Profile Catalyzed Over Highly Active Ziegler-Natta Catalysts," Ind. Eng. Chem. Res., 30, 2074 (1991).
12. Kim, I., H. K. Choi, J. H. Kim, and S. I. Woo, "Kinetics of Propylene Polymerization in the Initial Acceleration Stage," J. Poly. Sci. Part A Poly. Chem., 32, 971 (1994).
13. Perry, R. J., "Introducing Catalyst into a Reactor," U.S. Patent No. 3,780,135 (1973).
14. Samson, J. J. C., G. Weickert, and K. R. Westerterp, "Gas Phase Polymerization of Propylene with a Highly Active Catalyst," submitted (1998a).
15. 4/EB Catalyst: The Influence of Hydrogen, Cocatalyst and Electron Donor on Reaction Kinetics," in press (1998b).
16. Tait, P. T. J., D. R. Burfield, and I. D. McKenzie, "Ziegler-Natta Catalysis: 1. A General Kinetic Scheme," Polymer, 13, 302 (1972).
17. Yuan, H. G., and W. H. Ray, "Polymerization of Olefins through Heterogeneous Catalysis 1," J. Appl. Poly. Sci., 27, 1691 (1982).
18. Zakharov, V. A., G. D. Bukatov, and Y. I. Yermakov, "On the Mechanism of Olefin Polymerization by Ziegler-Natta Catalysts," Adv. Poly. Sci., 51, 61 (1983).