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Volumn 124, Issue 50, 2002, Pages 14842-14843

Cluster synthesis via ligand-arrested solid growth: Triethylphosphine-capped fragments of binary metal chalcogenides

Author keywords

[No Author keywords available]

Indexed keywords

LIGAND; METAL;

EID: 0037132614     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja027862f     Document Type: Article
Times cited : (9)

References (26)
  • 16
    • 0012145237 scopus 로고    scopus 로고
    • note
    • Narrow ribbon, wide ribbon, and trough-shaped tungsten heating boats were purchased from R. D. Mathis, as parts ME 5-0.005 W, ME 8-0.005 W. and S 16-0.005 W. respectively. The type of boat that is most suitable depends on the nature of the solid, with more refractory chalcogenides requiring use of boats having a narrower cross-section.
  • 17
    • 0012181998 scopus 로고    scopus 로고
    • note
    • 31P NMR spectroscopy, which in most instances indicated the presence of a mixture of clusters. On the basis of comparisons of peak intensities, the species in Table 1 are estimated to represent 60-100% of the obeservable products.
  • 22
    • 0012146998 scopus 로고    scopus 로고
    • note
    • 13: C. 23.29; H. 4.89. Found: C, 23.38; H. 4.92.
  • 23
    • 0012146999 scopus 로고    scopus 로고
    • note
    • 2 = 0.3400. Data were collected on a Siemens SMART diffractometer using graphite monochromated Mo Kα (λ = 0.71073 Å) radiation. Structures were solved by direct methods and refined against all data using SHELXTL 5.0. In both cases, ethyl groups on several of the PEt3 ligands are severely disordered, leading to poor data quality and high final agreement factors.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.