Polycubane clusters: Synthesis of [Fe4S4(PR3)4]1+,0 (R = Bu(t), Cy, Pr(i)) and [Fe4S4]0 core aggregation upon loss of phosphine

Journal of the American Chemical Society

Volumn 118, Issue 47, 1996, Pages 11844-11853

  Goh, Christopher ^a   Segal, Brent M ^a   Huang, Jiesheng ^a   Long, Jeffrey R ^a   Holm, R H ^a  

^a HARVARD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

IRON COMPLEX; METAL COMPLEX;

ARTICLE; COMPLEX FORMATION; DRUG STRUCTURE; MASS SPECTROMETRY; MOSSBAUER SPECTROSCOPY; REACTION ANALYSIS;

EID: 0029853710     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9620200     Document Type: Article

References (64)

1. (a) Chan, M. K.; Kim, J.; Rees, D. C. Science 1993, 260, 792.
2. (b) Kim, J.; Woo, D.; Rees, D. C. Biochemistry 1993, 32, 7104.
3. (a) Power, P. P.; Shoner, S. C. Angew. Chem., Int. Ed. Engl. 1991, 30, 330.
4. (b) Ruhlandt-Senge, K.; Power, P. P. Bull. Soc. Chim. Fr. 1992, 129, 594.
5. (c) MacDonnell, F. M.; Ruhlandt-Senge, K.; Ellison, J. J.; Holm, R. H.; Power, P. P. Inorg. Chem. 1995, 34, 1815.
6. This mean distance was calculated using the latest set of crystallographic coordinates for the Azotobacter vinelandii MoFe protein structure; Rees, D. C., private communication.
7. (a) Scott, M. J.; Holm. R. H. Angew. Chem., Int. Ed. Engl. 1993, 32, 564.
8. (b) Goh, C.: Holm, R. H., unpublished results.
9. (a) Nordlander, E.; Lee, S. C.; Cen, W.; Wu, Z. Y.; Natoli, C. R.: Di Cicco, A.; Filipponi, A.; Hedman, B.; Hodgson, K. O.; Holm, R. H. J. Am. Chem. Soc. 1993, 115, 5549.
10. (b) Cen, W.; MacDonnell, F. M.; Scott, M. J.; Holm, R. H. Inorg. Chem. 1994, 33, 5809.
11. (a) Synder, B. S.; Reynolds, M. S.; Noda, I.; Holm. R. H. Inorg. Chem. 1988, 27, 595.
12. (b) Snyder, B. S.; Holm, R. H. Inorg. Chem. 1988, 27, 2339.
13. Reynolds, M. S.; Holm, R. H. Inorg. Chem. 1988, 27, 4494.
14. Snvder, B. S.; Holm, R. H. Inorg. Chem. 1990, 29, 274.
15. No'da, I.; Snyder, B. S.; Holm, R. H. Inorg. Chem. 1986, 25, 3851.
16. 8: Eaton, P. E.; Cole, T. W., Jr. J. Am. Chem. Soc. 1964, 86, 3158.
17. Nelson, L. L.; Lo, F. Y.-K.; Rae, A. D.; Dahl, L. F. J. Organomet. Chem. 1982, 225, 309.
18. (a) Iron - Sulfur Proteins; Spiro, T. G., Ed.; Wiley-Interscience: New York, 1982.
19. (b) Cammack, R. Adv. Inorg. Chem. 1992, 38, 281.
20. (a) Berg, J. M.; Holm, R. H. In Iron - Sulfur Proteins; Spiro, T. G., Ed.; Wiley-Interscience: New York, 1982, Chapter 1.
21. (b) Carney, M. J.; Papaefthymiou, G. C.; Spartalian, K.; Frankel, R. B.; Holm, R. H. J. Am. Chem. Soc. 1988, 110, 6084 and references therein.
22. (c) O'Sullivan, T.; Millar, M. M. J. Am. Chem. Soc. 1985, 107, 4096.
23. Wong, G. B.; Bobrik, M. A.; Holm, R. H. Inorg. Chem. 1978, 17, 578.
24. (a) Müller, A.; Schladerbeck, N. H.; Bögge, H. J. Chem. Soc., Chem. Commun. 1987, 35.
25. (b) Cleland, W. E.; Holtman, D. A.; Sabat, M.; Ibers, J. A.; DeFotis, G. C.; Averill, B. A. J. Am. Chem. Soc. 1983, 105, 6021.
26. Chu, C. T.-W.; Lo, F. Y.-K.; Dahl, L. F. J. Am. Chem. Soc. 1982, 104, 3409.
27. (a) Stack, T. D. P.; Weigel, J. A.; Holm, R. H. Inorg. Chem. 1990, 29, 3745.
28. (b) Holm, R. H.; Ciurli, S.; Weigel, J. A. Prog. Inorg. Chem. 1990, 38, 1.
29. Tyson, M. A.; Demadis, K. D.; Coucouvanis, D. Inorg. Chem. 1995, 34, 4519.
30. 9
31. 1 (182°).
32. Booth, G.; Chatt, J. J. Chem. Soc. 1962, 2009.
33. Cai, L.; Segal, B. M.; Long. J. R.; Scott, M. J.; Holm, R. H. J. Am. Chem. Soc. 1995, 117, 8863.
34. See paragraph at the end of this article concerning Supporting Information.
35. (a) Laskowski, E. J.; Frankel, R. B.; Gillum, W. O.; Papaethymiou, G. C.; Renaud, J.; Ibers, J. A.; Holm, R. H. J. Am. Chem. Soc. 1978, 100, 5322.
36. (b) Laskowski, E. J.; Reynolds, J. G.; Frankel, R. B.; Foner, S.; Papaefthymiou, G. C.; Holm, R. H. J. Am. Chem. Soc. 1979, 101, 6562.
37. (c) Carney, M. J.; Papaefthymiou, G. C.; Whitener, M. A.; Spartalian, K.; Frankel, R. B.; Holm, R. H. Inorg. Chem. 1988, 27, 346.
38. (d) Carney, M. J.; Papaefthymiou, G. C.; Frankel, R. B.; Holm, R. H. Inorg. Chem. 1989, 28, 1497. Note that the isomer shifts in certain of these works are converted to values relative to Fe metal at room temperature by addition of 0.12 mm/ s.
39. Cambray, J.; Lane, R. W.; Wedd, A. G.; Johnson, R. W.; Holm, R. H. Inorg. Chem. 1977, 16, 2565.
40. Pickett, C. J. J. Chem. Soc., Chem. Commun. 1985, 323.
41. (a) Agresti, A.; Bacci, M.; Ceceoni, F.; Ghilardi, C.; Midollini, S. Inorg. Chem. 1985, 24, 689.
42. (b) Ceceoni, F.; Ghilardi, C; Midollini, S.; Orlandini, A. J. Chem. Soc., Dalton Trans. 1987, 831.
43. Goddard, C. A.; Long, J. R.; Holm, R. H. Inorg. Chem. In press.
44. (a) Fenske, D.; Ohmer, J.; Hachgenei, J. Angew. Chem., Int. Ed. Engl. 1985, 24, 993.
45. (b) Fenske, D.; Ohmer, J.; Hachgenei, J.; Merzweiler, K. Angew. Chem., Int. Ed. Engl. 1988, 27, 1277.
46. Steigerwald, M. D.; Siegrist, T.; Gyorgy, E. M.; Hessen, B.; Kwon, Y.-U.; Tanzler, S. M. Inorg. Chem. 1994, 33, 3389.
47. 1+ above.
48. Ceceoni, F.; Ghilardi, C. A.; Midollini, S.; Orlandini, J. Chem. Soc., Chem. Commun. 1992, 910.
49. Steigerwald, M. D.; Siegrist, T.; Stuczynski, S. M.; Kwon, Y.-U. J. Am. Chem. Soc. 1992, 114, 3155.
50. For a recent example in Re-S/Se cluster chemistry, cf.: Long, J. R.; McCarty, L. S.; Holm, R. H. J. Am. Chem. Soc. 1996, 118, 4603 and references therein.
51. 2+: Cecconi, F.; Ghilardi, C. A.; Midollini, S.; Orlandini, A. Inorg. Chim. Acta 1993, 214, 13.
52. 2+: Cecconi, F.; Ghilardi, C. A.; Midollini, S.; Orlandini, A. Inorg. Chim. Acta 1993, 214, 13.
53. 2+: Cecconi, F.; Ghilardi, C. A.; Midollini, S.; Orlandini, A. Inorg. Chim. Acta 1993, 214, 13.
54. 2+: Cecconi, F.; Ghilardi, C. A.; Midollini, S.; Orlandini, A. Inorg. Chim. Acta 1993, 214, 13.
55. 2+: Cecconi, F.; Ghilardi, C. A.; Midollini, S.; Orlandini, A. Inorg. Chim. Acta 1993, 214, 13.
56. 2]: Demadis, K. D.; Campana, C. F.: Coucouvanis, D. J. Am. Chem. Soc. 1995, 117, 7832.
57. (a) Pohl, S.; Saak, W. Angew. Chem., Int. Ed. Engl. 1984, 23, 907.
58. (b) Pohl, S.; Opitz, U. Angew. Chem., Int. Ed. Engl. 1993, 32, 863.
59. p].
60. Owing to the multitude of possible connection pathways, the enumeration of polycubanes reduces to a nontrivial problem in graph theory, a field in which enumeration of even the simplest lattice-bound graphs relies upon such brutish iterative techniques: (a) Soteros, C. E.; Whittington, S. G. J. Math. Chem. 1990, 5, 307. (b) Long, J. R.; Holm, R. H. J. Am. Chem. Soc. 1994, 116, 9987.
61. Owing to the multitude of possible connection pathways, the enumeration of polycubanes reduces to a nontrivial problem in graph theory, a field in which enumeration of even the simplest lattice-bound graphs relies upon such brutish iterative techniques: (a) Soteros, C. E.; Whittington, S. G. J. Math. Chem. 1990, 5, 307. (b) Long, J. R.; Holm, R. H. J. Am. Chem. Soc. 1994, 116, 9987.
62. Only one enantiomer is counted (and displayed) for chiral polycubanes.
63. To our knowledge, there are no relevant examples of cluster assemblies in which chemically identical cluster cores adopt more than one coordination environment. However, frameworks composed of two different cluster cores have been uncovered among the Chevrel phases: (a) Chevrel, R.; Sergent, M.; Seeber, B.; Fischer. Ø.; Grüttner, A.; Yvon, K. Mater. Res. Bull. 1979, 14, 567. (b) Chevrel, R.: Potel, M.; Sergent, M.: Decroux, M.; Fischer, Ø. J. Solid State Chem. 1980, 34, 247.
64. To our knowledge, there are no relevant examples of cluster assemblies in which chemically identical cluster cores adopt more than one coordination environment. However, frameworks composed of two different cluster cores have been uncovered among the Chevrel phases: (a) Chevrel, R.; Sergent, M.; Seeber, B.; Fischer. Ø.; Grüttner, A.; Yvon, K. Mater. Res. Bull. 1979, 14, 567. (b) Chevrel, R.: Potel, M.; Sergent, M.: Decroux, M.; Fischer, Ø. J. Solid State Chem. 1980, 34, 247.