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29
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2142843960
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note
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Replacing methyl ester on 2a by the more crowed ethyl ester affects the stereochemical outcome of the reduction (de = 66%). This result could be explained by considering that for the intermediate 2a′ (Figure 1) the conformer A should be relatively more stable then in the case where a methyl ester is present such as in compound 2a. This effect should affect the diasteroselectivity of the reduction.
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0004147792
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Lapuyade, G.; Schlewer, G.; Wermuth, C. G. Bull. Chem. Soc. Fr. 1986, 663. Blaser, H. U.; Honig, H.; Studer, M.; Wedemeyer-Exl, C. J. Mol. Catal. A: Chem. 1999, 253.
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0345561665
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Lapuyade, G.; Schlewer, G.; Wermuth, C. G. Bull. Chem. Soc. Fr. 1986, 663. Blaser, H. U.; Honig, H.; Studer, M.; Wedemeyer-Exl, C. J. Mol. Catal. A: Chem. 1999, 253.
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Blaser, H.U.1
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Wedemeyer-Exl, C.4
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