Classical metallocenes as photoinitiators for the anionic polymerization of an alkyl 2-cyanoacrylate

Macromolecules

Volumn 35, Issue 26, 2002, Pages 9648-9652

  Sanderson, Cynthia T ^a   Palmer, Bentley J ^a,b   Morgan, Alan ^a   Murphy, Michael ^a   Dluhy, Richard A ^a   Mize, Todd ^a   Amster, I Jonathan ^a   Kutal, Charles ^a  

^a UNIVERSITY OF GEORGIA   (United States)

^b Supercritical Systems Inc   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION; ANIONIC POLYMERIZATION; CHARGE TRANSFER; INFRARED SPECTROSCOPY; INITIATORS (CHEMICAL); MONOMERS; ORGANIC COMPOUNDS; ORGANOMETALLICS; OXIDATION; REFLECTION;

ALKYL CYANOACRYLATE; ELECTROPHILIC MONOMER; METALLOCENES; PHOTOINITIATORS;

INITIATORS (CHEMICAL);

EID: 0037126757     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma0212238     Document Type: Article

References (33)

1. Kutal, C.; Grutsch, P. A.; Yang, D. B. Macromolecules 1991, 24, 6872-6873.
2. Palmer, B. J.; Kutal, C.; Billing, R.; Hennig, H. Macromolecules 1995, 28, 1328-1329.
3. Lavallee, R. J.; Palmer, B. J.; Billing, R.; Hennig, H.; Ferraudi, G.; Kutal, C. Inorg. Chem. 1997, 36, 5552-5558.
4. Yamaguchi, Y.; Palmer, B. J.; Kutal, C.; Wakamatsu, T.; Yang, D. B. Macromolecules 1998, 31, 5515-5517.
5. Yamaguchi, Y.; Kutal, C. Inorg. Chem. 1999, 38, 4861-4867.
6. Yamaguchi, Y.; Kutal, C. Macromolecules 2000, 33, 1152-1156.
7. Paul, R. B.; Kelly, J. M.; Pepper, D. C. Polymer 1997, 38, 2011-2014.
8. Aida, T.; Inoue, S. Acc. Chem. Res. 1996, 29, 39-48.
9. Sugimoto, H.; Inoue, S. Adv. Polym. Sci. 1999, 146, 41-119.
10. Arsu, N.; Onen, A.; Yagci, Y. Macromolecules 1996, 29, 8973-8974.
11. Onen, A.; Arsu, N.; Yagci, Y. Angew. Makromol. Chem. 1999, 264, 56-59.
12. Jarikov, V. V.; Neckers, D. C. Macromolecules 2000, 33, 7761-7764.
13. An interesting variation on this mechanistic theme involves the generation of p-chlorophenol by photolysis of p-chlorophenyl-o-nitrobenzyl ether. Reaction of the released phenol with titanium tetraisopropoxide yields an active thermal catalyst for the anionic coordination polymerization of epoxides. Fukuchi, Y.; Takahashi, T.; Noguchi, H.; Saburi, M.; Uchida, Y. Macromolecules 1987, 20, 2317-2318.
14. Geoffroy, G. L.; Wrighton, M. S. Organometallic Photochemistry; Academic Press: New York, 1979; Chapter 5.
15. Traverso, O.; Scandola, F. Inorg. Chim. Acta 1970, 4, 493-498.
16. Akiyama, T.; Hoshi, Y.; Goto, S.; Sugimori, A. Bull. Chem. Soc. Jpn. 1973, 46, 1851-1855.
17. Traverso, O.; Sostero, S.; Mazzochin, G. A. Inorg. Chim. Acta 1974, 11, 237-241.
18. Borrell, P.; Henderson, E. J. Chem. Soc., Dalton Trans. 1975, 432-438.
19. Granifo, J.; Ferraudi, G. Inorg. Chem. 1984, 23, 2210-2212.
20. Bergamini, P.; Di Martino, S.; Maldotti, A.; Sostero, S.; Traverso, O. J. Organomet. Chem. 1989, 365, 341-346.
21. Hatchard, C. G.; Parker, C. A. Proc. R. Soc. London, Ser. A 1956, 235, 518-536.
22. Harrick, N. J. Internal Reflection Spectroscopy; Harrick Scientific Corp.: Ossining, NY, 1979; p 30.
23. Cameron, D. G.; Moffat, D. J.; Mantsch, H. H. Appl. Spectrosc. 1983, 36, 245-249.
24. Easterling, M. L.; Pitsenberger, C. C.; Kulkarni, S. S.; Taylor, P. K.; Amster, I. J. Int. J. Mass Spectrom. Ion Processes 1996, 158, 97-113.
25. Montaudo, G.; Montaudo, M. S.; Puglisi, C.; Samperi, F. Anal. Chem. 1994, 66, 4366-4369.
26. Montaudo, G.; Scamporrino, E.; Vitalini, D.; Mineo, P. Rapid Commun. Mass Spectrom. 1996, 10, 1551-1559.
27. Gordon, K. R.; Warren, K. D. Inorg. Chem. 1978, 17, 987-994.
28. Hill, M. G.; Lamanna, W. M.; Mann, K. R. Inorg. Chem. 1991, 30, 4690-4692.
29. Recently reported density functional theory calculations reveal that the adiabatic electron affinity of CA (1.1 ± 0.1 eV) is comparable to that of carbon tetrachloride (1.4 ± 0.1 eV); Brinkmann, N. R.; Schaefer, H. F., III.; Sanderson, C. T.; Kutal, C. J. Phys. Chem. A 2002, 106, 847-853.
30. Sohn, Y. S.; Hendrickson, D. N.; Gray, H. B. J. Am. Chem. Soc. 1971, 93, 3603-3612.
31. 5- and thereby prevent its recombination with the metal.
32. Robello, D. R.; Eldridge, T. D.; Swanson, M. T. J. Polym. Sci., Polym. Chem. Ed. 1999, 37, 4570-4581.
33. Irie, M.; Tomimoto, S.; Hayashi, K. Polym. Lett. 1972, 10, 699-701.