Benzoyl-substituted ferrocenes: an attractive new class of anionic photoinitiators

Macromolecules

Volumn 33, Issue 4, 2000, Pages 1152-1156

  Yamaguchi, Yoshikazu ^a,b   Kutal, Charles ^a  

^a UNIVERSITY OF GEORGIA   (United States)

^b JSR CORPORATION   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION; ANIONIC POLYMERIZATION; CHARGE TRANSFER; ELECTRON TRANSITIONS; GROWTH (MATERIALS); INITIATORS (CHEMICAL); PHOTOCHEMICAL REACTIONS; QUANTUM EFFICIENCY; SPECTROSCOPY;

ANIONIC PHOTOINITIATORS; BENZOYL SUBSTITUTED FERROCENE;

METALLORGANIC POLYMERS;

EID: 0033906417     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9915982     Document Type: Article

References (25)

1. Photopolymerization and Photoimaging Science and Technology; Allen, N. S., Ed.; Elsevier Applied Science: London, 1989.
2. Radiation Curing: Science and Technology; Pappas, S. P., Ed.; Plenum Press: New York, 1992.
3. Photopolymerization: Fundamentals and Applications; Scranton, A. B., Bowman, C. N., Peiffer, R. W., Eds.; ACS Symposium Series No. 673; American Chemical Society: Washington, DC, 1997.
4. Reichmanis, E.; Houlihan, F. M.; Nalamasu, O.; Neenan, T. X. Chem. Mater. 1991, 3, 394-407.
5. Yang, D. B.; Kutal, C. In Radiation Curing: Science and Technology; Pappas, S. P., Ed.; Plenum Press: New York, 1992; Chapter 2.
6. Monroe, B. M.; Weed, G. C. Chem. Rev. 1993, 93, 435-448.
7. Davidson, R. S. J. Photochem. Photobiol. A: Chem. 1993, 73, 81-96.
8. Kutal, C.; Grutsch, P. A.; Yang, D. B. Macromolecules 1991, 24, 6872-6873.
9. Wegner, E. E.; Adamson, A. W. J. Am. Chem. Soc. 1966, 88, 394-403.
10. For examples of CA polymerization initiated by photogenerated nitrogen and phosphorus bases, see: (a) Arsu, N. ; Onen, A.; Yagci, Y. Macromolecules 1996, 29, 8973-8974.
11. (b) Paul, R. B.; Kelly, J. M.; Pepper, D. C.; Long, C. Polymer 1997, 38, 2011-2014.
12. Onen, A.; Arsu, N.; Yagci, Y. Angew. Makromol. Chem. 1999, 264, 56-59.
13. Yamaguchi, Y.; Palmer, B. J.; Kutal, C.; Wakamatsu, T.; Yang, D. B. Macromolecules 1998, 31, 5155-5157.
14. Yamaguchi, Y.; Kutal, C. Inorg. Chem. 1999, 38, 4861-4867.
15. Jones, S. S.; Rausch, M. D.; Bitterwolf, T. E. J. Organomet. Chem. 1993, 450, 27-31.
16. Warren, K. D. Struct. Bonding (Berlin) 1976, 8, 45-159.
17. Sohn, Y. S.; Hendrickson, D. N.; Gray, H. B. J. Am. Chem. Soc. 1971, 93, 3603-3612.
18. For a discussion of this effect, see: Treadway, J. A.; Loeb, B.; Lopez, R.; Anderson, P. A.; Keene, F. R.; Meyer, T. J. Inorg. Chem. 1996, 35, 2242-2246.
19. Tarr, A. M.; Wiles, D. M. Can. J. Chem. 1968, 46, 2725-2731.
20. 11
21. Traverso, O.; Scandola, F. Inorg. Chim. Acta 1970, 4, 493-498.
22. Akiyama, T.; Hoshi, Y.; Goto, S.; Sugimori, A. Bull. Chem. Soc. Jpn. 1973, 46, 1851-1855.
23. Akiyama, T.; Sugimori, A.; Hermann, H. Bull. Chem. Soc. Jpn. 1973, 46, 1855-1859.
24. Photolysis of III in ethyl a-cyanopropionate induces spectral changes very similar to those observed in methanol (Figure 4), thus suggesting that the ferrocene complex undergoes similar substitutional photochemistry (e.g., eq 5) in the two solvents.
25. For a discussion of protonation of ferrocenes, see: Long, N. J. Metallocenes: An Introduction to Sandwich Complexes; Blackwell Science: London, 1998; Chapter 4.