Electron solvation in two dimensions

Science

Volumn 297, Issue 5584, 2002, Pages 1163-1166

  Miller, A D ^a   Bezel, I ^b   Gaffney, K J ^a,c   Garrett Roe, S ^a   Liu, S H ^a   Szymanski, P ^a   Harris, C B ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b Miller Institute for Basic Research in Science   (United States)

^c STANFORD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRONS; INTERFACES (MATERIALS); MOLECULES; PHOTOEMISSION;

ELECTRON SOLVATION;

HIGH ENERGY PHYSICS;

ACETONITRILE; BUTYRONITRILE; GOLD; SILVER;

ELECTRON;

ARTICLE; DIPOLE; ELECTRIC POTENTIAL; ELECTROCHEMISTRY; ELECTRON; ELECTRON DIFFRACTION; FOURIER TRANSFORMATION; MATHEMATICAL MODEL; MOLECULAR INTERACTION; PHOTON; PRIORITY JOURNAL; SOLVATION;

EID: 0037119604     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.1073571     Document Type: Article

References (33)

1. D. G. Busch, S. Gao, R. A. Pelak, M. F. Booth, W. Ho, Phys. Rev. Lett. 75, 673 (1995).
2. T. Kugler, M. Logdlund, W. R. Salaneck, Acc. Chem. Res. 32, 225 (1999).
3. R. M. Stratt, M. Maroncelli, J. Phys. Chem. 100, 12981 (1996).
4. G. R. Fleming, M. H. Cho, Annu. Rev. Phys. Chem. 47, 109 (1996).
5. P. J. Rossky, J. D. Simon, Nature 370, 263 (1994).
6. P. K. Walhout et al., Chem. Phys. Lett. 232, 135 (1995).
7. J. A. Kloepfer, V. H. Vilchiz, V. A. Lenchenkov, S. E. Bradforth, Chem. Phys. Lett. 298, 120 (1998).
8. B. J. Loughnane, R. A. Farrer, A. Scodinu, T. Reilly, J. T. Fourkas, J. Phys. Chem. B 104, 5421 (2000).
9. D. M. Willard, R. E. Riter, N. E. Levinger, J. Am. Chem. Soc. 120, 4151 (1998).
10. D. Zimdars, K. B. Eisenthal, J. Phys. Chem. A 103, 10567 (1999).
11. I. Benjamin, Chem. Rev. 96, 1449 (1996).
12. C. B. Harris, N.-H. Ge, R. L. Lingle, J. D. McNeill, C. M. Wong, Annu. Rev. Phys. Chem. 48, 711 (1997).
13. T. Fauster, W. Steinmann, in Photonic Probes of Surfaces, P. Halevi, Ed. (Elsevier, Amsterdam, 1995), pp. 347-411.
14. U. Höfer et al., Science 277, 1480 (1997).
15. H. Petek, M. J. Weida, H. Nagano, S. Ogawa, Science 288, 1402 (2000).
16. Q. Zhong, C. Gahl, M. Wolf, Surf. Sci. 496, 21 (2002).
17. D. R. Lide. Ed., CRC Handbook of Chemistry and Physics (CRC Press, Boca Raton, FL, ed. 81, 2000).
18. Value is for the anti conformer; the gauche conformer has a dipole moment of 3.9 debyes.
19. M. Ogasawara, in Excess Electrons in Dielectric Media, C. Ferradini, J.-P. Jay-Gerin, Eds. (CRC Press, Boca Raton, FL, 1991), pp. 287-314.
20. P. A. Stevens, R. J. Madix, J. Stohr, J. Chem. Phys. 91, 4338 (1989).
21. T. Soloman, H. Christmann, A. Neumann, J. Baumgärtel, J. Electroanal. Chem. 309, 355 (1991).
22. T. Soloman, H. Christmann, J. Baumgärtel, J. Phys. Chem. 93, 7199 (1989).
23. R. Hashemi, E. Illenberger, J. Phys. Chem. 95, 6402 (1991).
24. P. M. Echenique, J. B. Pendry, J. Phys. C 11, 2065 (1978).
25. N. Memmel, Surf. Sci. Rep. 32, 91 (1998).
26. K. Wandelt, in Thin Metal Films and Gas Chemisorption, P. Wissman, Ed. (Elsevier, Amsterdam, 1987), pp. 280-368.
27. S. Baldelli, G. Mailhot, P. Ross, Y. R. Shen, G. A. Somarjai, J. Phys. Chem. B 105, 654 (2001).
28. T. Holstein, Ann. Phys. 8, 343 (1959).
29. D. Emin, T. Holstein, Phys. Rev. Lett. 36, 323 (1976).
30. V. V. Kabanov, O. Y. Mashtakov, Phys. Rev. B 47, 6060 (1993).
31. H. Sumi, A. Sumi, J. Phys. Soc. Jpn. 63, 637 (1994).
32. G. Katosakas, S. Aubry, G. P. Tsironis, Phys. Rev. B 58, 3094 (1998).
33. We thank C. Wittig for valuable discussions. Supported by the director, Office of Energy Research, Office of Basic Energy Sciences, Chemical Sciences Division of the U.S. Department of Energy, under contract DE-AC03-76SF00098. We acknowledge NSF support for specialized equipment used in these experiments.