Bifurcation analysis of reactive distillation systems with liquid-phase splitting

Computers and Chemical Engineering

Volumn 26, Issue 10, 2002, Pages 1459-1471

  Qi, Zhiwen ^a   Sundmacher, Kai ^a,b  

^a MAX PLANCK INSTITUTE FOR DYNAMICS OF COMPLEX TECHNICAL SYSTEMS   (Germany)

^b OTTO VON GUERICKE UNIVERSITY   (Germany)

Author keywords

Bifurcation; Phase splitting; Pinch point; Reactive azeotrope; Reactive distillation; Singular point

Indexed keywords

BIFURCATION (MATHEMATICS); DISTILLATION; REACTION KINETICS;

CHEMICAL EQUILIBRIUM;

CHEMICAL ENGINEERING;

AZEOTROPIC MIXTURE; BIFURCATION; CHEMICAL REACTION; DISTILLATION; LIQUID-LIQUID SEPARATION;

ARTICLE; CHEMICAL PROCEDURES; CHEMICAL REACTION; DISTILLATION; EQUILIBRIUM CONSTANT; LIQUID; MATHEMATICAL ANALYSIS; MATHEMATICAL PARAMETERS; PHASE TRANSITION;

EID: 0037108410     PISSN: 00981354     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0098-1354(02)00124-2     Document Type: Article

References (22)

1. Barbosa, D., & Doherty, M. F. (1988). The simple distillation of homogeneous reactive mixtures. Chemical Engineering Science, 43, 541.
2. Chadda, N., Malone, M. F., & Doherty, M. F. (2001). Effect of chemical kinetics on feasible splits for reactive distillation. American Institute of Chemical Engineering Journal, 47, 590.
3. Fien, G. A. F., & Liu, Y. A. (1994). Heuristic synthesis and shortcut design of separation processes using residue curve maps: review. Industrial Engineering and Chemical Research, 33, 2505.
4. Jiménez, L., Wahnschafft, O. M., & Julka, V. (2001). Analysis of residue curve maps of reactive and extractive distillation units. Computer and Chemical Engineering, 25, 635.
5. Löning, S., Horst, C., & Hoffmann, U. (2000). Theoretical investigation on the quaternary system n-butanol, butyl acetate, acetic acid and water. Chemical Engineering Technology, 23, 789.
6. Mangold, M., Kienle, A., Gilles, E. D., & Mohl, K. D. (2000). Nonlinear computation in DIVA - methods and applications. Chemical Engineering Science, 55, 441.
7. Okasinski, M. J., & Doherty, M. F. (1997). Thermodynamic behaviour of reactive azeotropes. American Institute of Chemical Engineering Journal, 43, 2227.
8. Okasinski, M. J., & Doherty, M. F. (2000). Prediction of heterogeneous reactive azeotropes in esterification systems. Chemical Engineering Science, 55, 5263.
9. Prausnitz, J., Anderson, T., Grens, E., Eckert, C., Hsieh, R., & O'Connell, J. (1980). Computer calculations for multicomponent vapor-liquid and liquid-liquid equilibria. New Jersey: Prentice-Hall Appendix G.
10. Qi, Z., Kolah, A., & Sundmacher, K. (2002). Residue curve maps for reactive distillation systems with liquid phase splitting. Chemical Engineering Science, 57, 163.
11. Solokhin, A. V., Blagov, S. A., Serafimov, L. A., & Timofeev, V. S. (1990a). Open evaporation processes accompanied by chemical reaction in the liquid phase. Theoretical Foundation of Chemical Engineering, 24, 103.
12. Solokhin, A. V., Blagov, S. A., Serafimov, L. A., & Timofeev, V. S. (1990b). Dynamical system for open evaporation process in presence of A⇔B chemical reaction. Theoretical Foundation of Chemical Engineering, 24, 377.
13. Steyer, F., Qi, Z., & Sundmacher, K. (2002). Synthesis of cyclohexanol by three-phase reactive distillation: influence of kinetics on phase equilibria. Chemical Engineering Science, 57, 1511.
14. Thiel, C., Sundmacher, K., & Hoffmann, U. (1997). Residue curve maps for heterogeneously catalysed reactive distillation of fuel ethers MTBE and TAME. Chemical Engineering Science, 52, 993.
15. Ung, S., & Doherty, M. F. (1995a). Calculation of residue curve maps for mixture with multiple equilibrium chemical reactions. Industrial Engineering and Chemical Research, 34, 3195.
16. Ung, S., & Doherty, M. F. (1995b). Theory of phase equilibria in multiple reaction systems. Chemical Engineering Science, 50, 3201.
17. Ung, S., & Doherty, M. F. (1995c). Vapor-liquid phase equilibrium in systems with multiple chemical reactions. Chemical Engineering Science, 50, 23.
18. Ung, S., & Doherty, M. F. (1995d). Necessary and sufficient conditions for reactive azeotropes in multireaction mixtures. American Institute of Chemical Engineering Journal, 41, 2382.
19. Venimadhavan, G., Buzad, G., Doherty, M. F., & Malone, M. F. (1994). Effect of kinetics on residue curve maps for reactive distillation. American Institute of Chemical Engineering Journal, 40, 1814.
20. Venimadhavan, G., Malone, M. F., & Doherty, M. F. (1999a). A novel distillate policy for batch reactive distillation with application to the production of butyl acetate. Industrial Engineering and Chemical Research, 38, 714.
21. Venimadhavan, G., Doherty, M. F., & Malone, M. F. (1999b). Bifurcation study of kinetic effects in reactive distillation. American Institute of Chemical Engineering Journal, 45, 546.
22. Yang, Z., Cui, X., & Gao, J. (1998). Esterification-distillation of butanol and acetic acid. Chemical Engineering Science, 53, 2081.